Based on current research, the characteristics and action mechanism of biological nitrification inhibitors at home and abroad were reviewed by combining with the latest research progress. The application effects of bi...Based on current research, the characteristics and action mechanism of biological nitrification inhibitors at home and abroad were reviewed by combining with the latest research progress. The application effects of biological nitrification inhibitors on agricultural production were summarized. Research hotspot and achievements of biological nitrification inhibitors at home and abroad were summarized. The research direction in future was forecasted.展开更多
Cu-based catalysts are the most promising candidates for electrochemical CO_(2)reduction(CO_(2)RR)to multi-carbon(C_(2))products.Optimizing the C-C coupling process,the rate-determining step for C_(2)product generatio...Cu-based catalysts are the most promising candidates for electrochemical CO_(2)reduction(CO_(2)RR)to multi-carbon(C_(2))products.Optimizing the C-C coupling process,the rate-determining step for C_(2)product generation,is an important strategy to improve the production and selectivity of the C_(2)products.In this study,we determined that the local electric field can promote the C-C coupling reaction and enhance CO_(2)electroreduction to C_(2)products.First,finite-element simulations indicated that the high curvature of the Cu nanoneedles results in a large local electric field on their tips.Density functional theory(DFT)calculations proved that a large electric field can promote C-C coupling.Motivated by this prediction,we prepared a series of Cu catalysts with different curvatures.The Cu nanoneedles(NNs)exhibited the largest number of curvatures,followed by the Cu nanorods(NRs),and Cu nanoparticles(NPs).The Cu NNs contained the highest concentration of adsorbed K+,which resulted in the highest local electric field on the needles.CO adsorption sensor tests indicated that the Cu NNs exhibited the strongest CO adsorption ability,and in-situ Fourier-transform infrared spectroscopy(FTIR)showed the strongest*COCO and*CO signals for the Cu NNs.These experimental results demonstrate that high-curvature nanoneedles can induce a large local electric field,thus promoting C-C coupling.As a result,the Cu NNs show a maximum FEC_(2)of 44%for CO_(2)RR at a low potential(-0.6 V vs.RHE),which is approximately 2.2 times that of the Cu NPs.This work provides an effective strategy for enhancing the production of multi-carbon products during CO_(2)RR.展开更多
In the delicate normative balance, at European Union （EU） level of the borderline products （i.e., between plant protectants and bio-fertilizers/bio-effectors） containing microbial consortia （MC） instead of singl...In the delicate normative balance, at European Union （EU） level of the borderline products （i.e., between plant protectants and bio-fertilizers/bio-effectors） containing microbial consortia （MC） instead of single microbial strains, the most relevant factors influencing the categorization of the products are the intention of use, the cell density and the mode of action. For the latter, the basic difference between the two types of products is that a plant protectant has a targeted activity on plant pathogens, while a bio-fertilizer acts indirectly by nourishing and fortifying the host plant （healthier plant）, thus inducing a generalized resistance to the onset of pathological status, irrespective of its origin and nature. Case-studies are presented on the effectiveness of MC as bio-fertilizers/bio-effectors on different crops. Bio-fertilizers exhibit a double effect--biotic and abiotic, leading to the fortification of the crop plant linked to its more effective water and nutrient uptakes as well asto a generalized healthier status. This in turn leads to a higher resistance to diseases. In addition, bio-fertilizers play a relevant role on the reduction of environmental impacts due to chemical fertilizers, e.g., by facilitating the uptake of phosphorus （P）, thus reducing the need of P fertilization. Although finding a scientifically-based balance between regulatory need and marketing constraint is not always an easy task, the availability of scientific advancements combined to common sense should help in describing positive effects and risk profiles of MC in agriculture.展开更多
Electrochemical conversion of CO2 into fuels is a promising means to solve greenhouse effect and recycle chemical energy. However, the CO2 reduction reaction(CO2 RR) is limited by the high overpotential, slow kinetics...Electrochemical conversion of CO2 into fuels is a promising means to solve greenhouse effect and recycle chemical energy. However, the CO2 reduction reaction(CO2 RR) is limited by the high overpotential, slow kinetics and the accompanied side reaction of hydrogen evolution reaction. Au nanocatalysts exhibit high activity and selectivity toward the reduction of CO2 into CO. Here, we explore the Faradaic efficiency(FE)of CO2 RR catalyzed by 50 nm gold colloid and trisoctahedron. It is found that the maximum FE for CO formation on Au trisoctahedron reaches 88.80% at -0.6 V, which is 1.5 times as high as that on Au colloids(59.04% at -0.7 V). The particle-size effect of Au trisoctahedron has also been investigated, showing that the FE for CO decreases almost linearly to 62.13% when the particle diameter increases to 100 nm. The Xray diffraction characterizations together with the computational hydrogen electrode(CHE) analyses reveal that the(2 2 1) facets on Au trisoctahedron are more feasible than the(1 1 1) facets on Au colloids in stabilizing the critical intermediate COOH*, which are responsible for the higher FE and lower overpotential observed on Au trisoctahedron.展开更多
基金Supported by Tibet Natural Science Foundation(ZJ2014068)School-level Key Project of Tibet Vocational Technical College(2012L07)~~
文摘Based on current research, the characteristics and action mechanism of biological nitrification inhibitors at home and abroad were reviewed by combining with the latest research progress. The application effects of biological nitrification inhibitors on agricultural production were summarized. Research hotspot and achievements of biological nitrification inhibitors at home and abroad were summarized. The research direction in future was forecasted.
文摘Cu-based catalysts are the most promising candidates for electrochemical CO_(2)reduction(CO_(2)RR)to multi-carbon(C_(2))products.Optimizing the C-C coupling process,the rate-determining step for C_(2)product generation,is an important strategy to improve the production and selectivity of the C_(2)products.In this study,we determined that the local electric field can promote the C-C coupling reaction and enhance CO_(2)electroreduction to C_(2)products.First,finite-element simulations indicated that the high curvature of the Cu nanoneedles results in a large local electric field on their tips.Density functional theory(DFT)calculations proved that a large electric field can promote C-C coupling.Motivated by this prediction,we prepared a series of Cu catalysts with different curvatures.The Cu nanoneedles(NNs)exhibited the largest number of curvatures,followed by the Cu nanorods(NRs),and Cu nanoparticles(NPs).The Cu NNs contained the highest concentration of adsorbed K+,which resulted in the highest local electric field on the needles.CO adsorption sensor tests indicated that the Cu NNs exhibited the strongest CO adsorption ability,and in-situ Fourier-transform infrared spectroscopy(FTIR)showed the strongest*COCO and*CO signals for the Cu NNs.These experimental results demonstrate that high-curvature nanoneedles can induce a large local electric field,thus promoting C-C coupling.As a result,the Cu NNs show a maximum FEC_(2)of 44%for CO_(2)RR at a low potential(-0.6 V vs.RHE),which is approximately 2.2 times that of the Cu NPs.This work provides an effective strategy for enhancing the production of multi-carbon products during CO_(2)RR.
文摘In the delicate normative balance, at European Union （EU） level of the borderline products （i.e., between plant protectants and bio-fertilizers/bio-effectors） containing microbial consortia （MC） instead of single microbial strains, the most relevant factors influencing the categorization of the products are the intention of use, the cell density and the mode of action. For the latter, the basic difference between the two types of products is that a plant protectant has a targeted activity on plant pathogens, while a bio-fertilizer acts indirectly by nourishing and fortifying the host plant （healthier plant）, thus inducing a generalized resistance to the onset of pathological status, irrespective of its origin and nature. Case-studies are presented on the effectiveness of MC as bio-fertilizers/bio-effectors on different crops. Bio-fertilizers exhibit a double effect--biotic and abiotic, leading to the fortification of the crop plant linked to its more effective water and nutrient uptakes as well asto a generalized healthier status. This in turn leads to a higher resistance to diseases. In addition, bio-fertilizers play a relevant role on the reduction of environmental impacts due to chemical fertilizers, e.g., by facilitating the uptake of phosphorus （P）, thus reducing the need of P fertilization. Although finding a scientifically-based balance between regulatory need and marketing constraint is not always an easy task, the availability of scientific advancements combined to common sense should help in describing positive effects and risk profiles of MC in agriculture.
基金This work was supported by the National Key Research and Development Program of China(2017YFA0206500)the National Natural Science Foundation of China(21635004 and 21675079)Part of the numerical calculations were carried out in the High Performance Computing Center(HPCC)of Nanjing University.
文摘Electrochemical conversion of CO2 into fuels is a promising means to solve greenhouse effect and recycle chemical energy. However, the CO2 reduction reaction(CO2 RR) is limited by the high overpotential, slow kinetics and the accompanied side reaction of hydrogen evolution reaction. Au nanocatalysts exhibit high activity and selectivity toward the reduction of CO2 into CO. Here, we explore the Faradaic efficiency(FE)of CO2 RR catalyzed by 50 nm gold colloid and trisoctahedron. It is found that the maximum FE for CO formation on Au trisoctahedron reaches 88.80% at -0.6 V, which is 1.5 times as high as that on Au colloids(59.04% at -0.7 V). The particle-size effect of Au trisoctahedron has also been investigated, showing that the FE for CO decreases almost linearly to 62.13% when the particle diameter increases to 100 nm. The Xray diffraction characterizations together with the computational hydrogen electrode(CHE) analyses reveal that the(2 2 1) facets on Au trisoctahedron are more feasible than the(1 1 1) facets on Au colloids in stabilizing the critical intermediate COOH*, which are responsible for the higher FE and lower overpotential observed on Au trisoctahedron.
