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企业集团财务资源协同管理效应的度量 被引量:11
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作者 傅元略 《中国工业经济》 CSSCI 北大核心 2003年第9期66-72,共7页
本文以集团企业的现金流量表及其特性为基础 ,揭示了集团资产、负债和权益协同管理与集团现金流协同效应的关系 ,建立了度量经营活动现金流协同效应的模型 ,分析了模型中效应参数之间的关系。同时 ,提出了企业集团的投资现金流和融资现... 本文以集团企业的现金流量表及其特性为基础 ,揭示了集团资产、负债和权益协同管理与集团现金流协同效应的关系 ,建立了度量经营活动现金流协同效应的模型 ,分析了模型中效应参数之间的关系。同时 ,提出了企业集团的投资现金流和融资现金流协同效应度量的命题。最后 ,对企业集团智力资产对经营活动现金流协同效应的贡献进行探讨。这些模型和命题的创立为企业集团度量和分析协同管理效应提供了一套便利的方法。 展开更多
关键词 企业集团 财务资源 协同管理效应 效应度量模型 现金流量表 智力资产 经营活动现金流
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An Analytical Model of Drain Current for Ultra-Thin Body and Double-Gate Schottky Source/Drain MOSFETs Accounting for Quantum Effects 被引量:2
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作者 栾苏珍 刘红侠 +3 位作者 贾仁需 蔡乃琼 王瑾 匡潜玮 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第5期869-874,共6页
A compact drain current including the variation of barrier heights and carrier quantization in ultrathin-body and double-gate Schottky barrier MOSFETs (UTBDG SBFETs) is developed. In this model, Schrodinger's equat... A compact drain current including the variation of barrier heights and carrier quantization in ultrathin-body and double-gate Schottky barrier MOSFETs (UTBDG SBFETs) is developed. In this model, Schrodinger's equation is solved using the triangular potential well approximation. The carrier density thus obtained is included in the space charge density to obtain quantum carrier confinement effects in the modeling of thin-body devices. Due to the quantum effects, the first subband is higher than the conduction band edge, which is equivalent to the band gap widening. Thus, the barrier heights at the source and drain increase and the carrier concentration decreases as the drain current decreases. The drawback of the existing models,which cannot present an accurate prediction of the drain current because they mainly consider the effects of Schottky barrier lowering (SBL) due to image forces,is eliminated. Our research results suggest that for small nonnegative Schottky barrier (SB) heights,even for zero barrier height, the tunneling current also plays a role in the total on-state currents. Verification of the present model was carried out by the device numerical simulator-Silvaco and showed good agreement. 展开更多
关键词 Schottky barrier quantum effects the effective mass electron density
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Influence of Chemical Effect on the Kβ/Kα Intensity Ratios and Kβ Energy Shift of Co, Ni, Cu, and Zn Complexes 被引量:1
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作者 G. Apaydin V. Aylikci +2 位作者 Z. Biyiklioglu E. Tirasoglu H. Kantekin 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2008年第6期591-595,共5页
Chemical effects on the Kβ/Kα intensity ratios and △E energy differences for Co, Ni, Cu, and Zn complexes were investigated. The samples were excited by 59.5 keV γ-rays from a ^241Am annular radioactive source. K ... Chemical effects on the Kβ/Kα intensity ratios and △E energy differences for Co, Ni, Cu, and Zn complexes were investigated. The samples were excited by 59.5 keV γ-rays from a ^241Am annular radioactive source. K X-rays emitted by samples were counted by an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. We observed the effects of different ligands on the Kβ/Kα intensity ratios and △E energy differences for Co, Ni, Cu, and Zn complexes. We tried to investigate chemical effects on central atoms using the behaviors of different ligands in these complexes. The experimental values of Kβ/Kα were compared with the theoretical and other experimental values of pure Co, Ni, Cu, and Zn. 展开更多
关键词 Chemical effect K intensity ratio △E energy difference Ultra-LEGe detector 241Am annular radioactive source
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Seismic physical modeling and quality factor 被引量:1
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作者 Gao Feng Wei Jian-Xin and Di Bang-Rang 《Applied Geophysics》 SCIE CSCD 2018年第1期46-56,148,共12页
Accurate Q parameter is hard to be obtained, but there is great difference between Q measurements from different measurement methods in seismic physical modelling. The influence factors, stability and accuracy of diff... Accurate Q parameter is hard to be obtained, but there is great difference between Q measurements from different measurement methods in seismic physical modelling. The influence factors, stability and accuracy of different methods are analyzed through standard sample experiment and the seismic physical modelling. Based on this, we proposed an improved method for improving accuracy of pulse transmission method, in which the samples with similar acoustic properties to the test sample are selected as the reference samples. We assess the stability and accuracy of the pulse transmission, pulse transmission insertion, and reflection wave methods for obtaining the quality factor Q using standard and reference samples and seismic physical modeling. The results suggest that the Q-values obtained by the pulse transmission method are strongly affected by diffraction and the error is 50% or greater, whereas the relative error of the improved pulse transmission method is about 10%. By using a theoretical diffraction correction method and the improved measurement method, the differences among the Q-measuring methods can be limited to within 10%. 展开更多
关键词 Seismic physical modeling Q-VALUE diffraction effect.
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Effect of Graft Yield on the Thermo-Responsive Permeability Through Porous Membranes with Plasma-Grafted Poly(N-isopropylacrylamide)Gates 被引量:6
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作者 褚良银 朱家骅 +3 位作者 陈文梅 NIITSUMA Takuya YAMAGUCHI Takeo NAKAO Shin-ichi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2003年第3期269-275,共7页
The effect of graft yield on both the thermo-responsive hydraulicpermeability and the therrno-responsive diffusional permeability through porous membranes withplasma-grafted poly(N-isopropylacrylamide) (PNIPAM) gates ... The effect of graft yield on both the thermo-responsive hydraulicpermeability and the therrno-responsive diffusional permeability through porous membranes withplasma-grafted poly(N-isopropylacrylamide) (PNIPAM) gates was investigated. Both thermo-responsiveflat membranes and core-shell microcapsule membranes with a wide range of graft yield of PNIPAM wereprepared using a plasma-graft pore-filling polymerization method. The grafted PNIPAM was formedhomogeneously throughout the entire thickness of both the flat polyethylene membranes and themicrocapsule polyamide membranes. Both the hydraulic permeability and the diffusional permeabilitywere heavily dependent on the PNIPAM graft yield. With increasing the graft yield, the hydraulicpermeability (water flux) decreases rapidly at 25℃ because of the decrease of the pore size;however, the water flux at 40℃ increases firstly to a peak because of the increase ofhydrophobicity of the pore surface, and then decreases and finally tends to zero because of the poresize becoming smaller and smaller. For the diffusional permeability, the temperature showsdifferent effects on the diffusional permeability coefficients of solutes across the membranes. Whenthe graft yield was low, the diffusional coefficient of solute across the membrane was higher attemperature above the lower critical solution temperature (LCST) than that below the LCST; however,when the graft yield was high, the diffusional coefficient was lower at temperature above the LCSTthan that below the LCST. It is very important to choose or design a proper graft yield of PNIPAMfor obtaining a desired thermo-responsive 'on/off' hydraulic or diffusional permeability. 展开更多
关键词 thermo-responsive membrane poly(N-isopropylacrylamide) plasma-graftpore-filling polymerization graft yield hydraulic permeability diffusional permeability
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Quantum Gravitational Effects on Tunneling Rate of Reissner-Nordstroum Black Hole Emission and Generalized Second Law 被引量:1
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作者 A.Farmany H.Noorizadeh S.S.Mortazavi 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第8期289-292,共4页
The semi-classical black hole tunneling radiation (Parikh-Wilczek tunneling proposal) is calculated undera minimal length uncertainty analysis.It is shown that,the generalized second law of thermodynamics may bound th... The semi-classical black hole tunneling radiation (Parikh-Wilczek tunneling proposal) is calculated undera minimal length uncertainty analysis.It is shown that,the generalized second law of thermodynamics may bound thetunneling probability radiation of a Reissner-Nordstrom black hole radiation. 展开更多
关键词 generalized uncertainty principle black hole tunneling radiation Reissner-NordstrSm black hole generlized second law
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No-reference blur assessment method based on gradient and saliency 被引量:2
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作者 Jia Huizhen Lei Chucong +5 位作者 Wang Tonghan Li Tan Wu Jiasong Li Guang He Jianfeng Shu Huazhong 《Journal of Southeast University(English Edition)》 EI CAS 2021年第2期184-191,共8页
To evaluate the quality of blurred images effectively,this study proposes a no-reference blur assessment method based on gradient distortion measurement and salient region maps.First,a Gaussian low-pass filter is used... To evaluate the quality of blurred images effectively,this study proposes a no-reference blur assessment method based on gradient distortion measurement and salient region maps.First,a Gaussian low-pass filter is used to construct a reference image by blurring a given image.Gradient similarity is included to obtain the gradient distortion measurement map,which can finely reflect the smallest possible changes in textures and details.Second,a saliency model is utilized to calculate image saliency.Specifically,an adaptive method is used to calculate the specific salient threshold of the blurred image,and the blurred image is binarized to yield the salient region map.Block-wise visual saliency serves as the weight to obtain the final image quality.Experimental results based on the image and video engineering database,categorial image quality database,and camera image database demonstrate that the proposed method correlates well with human judgment.Its computational complexity is also relatively low. 展开更多
关键词 no-reference image quality assessment reblurring effect gradient similarity SALIENCY
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Specific Heat of Hollow Nanosphere Coupled to Substrate: Quantum Size Effects
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作者 YIN Xue-Ai LUO Bo LIU Fei YI Lin 《Communications in Theoretical Physics》 SCIE CAS CSCD 2007年第4X期745-748,共4页
With the help of the elastic wave theory in the perturbed approximation the density-of-states for vibrational modes and the specific heat are studied for different hollow Si nanospheres, coupled with a semi-infinite ... With the help of the elastic wave theory in the perturbed approximation the density-of-states for vibrational modes and the specific heat are studied for different hollow Si nanospheres, coupled with a semi-infinite substrate. We find that the modes of such coupled hollow spheres are significantly broadened and shifted toward low frequencies. The specific heat of the coupled hollow nanosphere is bigger than an isolated one due to the coupling interaction and quantum size effects. The predicted coupling and size enhancements on specific heat are probed in thermal experiments. 展开更多
关键词 elastic wave size effect specific heat
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Effects of Preheat on the Thermodynamics of the ICF Hot Spot
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作者 Jeremy Melvin Hyunkyung Lim +4 位作者 Verinder Rana Baolian Cheng James Glimm David H. Sharp Doug C.Wilson 《Journal of Physical Science and Application》 2015年第1期24-28,共5页
We determine the dependence of key inertial confinement fusion (ICF) hot spot properties on the deuterium-tritium (DT) fuel adiabat accomplished by addition of heat to the cold shell. Our main result is to observe... We determine the dependence of key inertial confinement fusion (ICF) hot spot properties on the deuterium-tritium (DT) fuel adiabat accomplished by addition of heat to the cold shell. Our main result is to observe that variation of this parameter reduces the simulation to experiment discrepancy in several experimentally inferred quantities. Simulations are continued from capsule only l D simulations using the Lawrence Livermore National Laboratory ICF code, HYDRA. The continuations employ the high energy density physics (HEDP) University of Chicago code, FLASH, and a hydro only code, FronTier, modified with a radiation equation of state (EOS) model. Hot spot densities, burn-weighted ion temperatures and pressures show a decreasing trend, while the hot spot radius shows an increasing trend in response to added heat to the cold shell. Instantaneous quantities are assessed at the time of maximum neutron production within each simulation. 展开更多
关键词 ICF Rayleigh-Taylor instabilities hot spot deceleration phase adiabat.
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Short-Time Decoherence of Solid-State Qubit at Optimal Operation Points
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作者 ZHAO Xu LIANG Xian-Ting 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第5X期827-832,共6页
We investigate the short-time decoherence of a solid-state qubit under Ohmic noise at optimal operation points. The decoherence is analyzed by maximum norm of the deviation density operator. It is shown that at the te... We investigate the short-time decoherence of a solid-state qubit under Ohmic noise at optimal operation points. The decoherence is analyzed by maximum norm of the deviation density operator. It is shown that at the temperature T = 3 mK, the loss of the fidelity due to decoherence is much smaller than the DiVincenzo low decoherence criterion, which means that the mode/may be an optimal candidate of qubit for quantum computation. 展开更多
关键词 short-time decoherence Josephson junction qubit ohmic noise
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Shape of Compact Toroidal Dimensions T_θ~d and Casimir Effect on M^D×T_θ~d Spacetime
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作者 V.K.Oikonomou 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第1期101-110,共10页
We study the influence of the shape of compact a scalar field. We examine both the massive and the massless dimensions to the Casimir energy and Casimir force of scalar field. The total spacetime topology is M^D ×... We study the influence of the shape of compact a scalar field. We examine both the massive and the massless dimensions to the Casimir energy and Casimir force of scalar field. The total spacetime topology is M^D × Tθ2, where M^D) is the D-dimensional Minkowski spacetime and Tθ2 the twisted torus described by R1, R2, and 8. For the case R1 = R2 we found that the massive bulk scalar field Casimir energy is singular for D=even and this singularity is R-dependent and remains even when the force is calculated. Also the massless Casimir energy and force is regular only for D = 4 (!). This is very interesting phenomenologically. We examine the energy and force as a function of 8. Also we address the stabilization problem of the compact space. We also briefly discuss some phenomenological implications. 展开更多
关键词 Casimir energy Casimir force extra dimensions twisted torus shadowing effect zeta dimensions
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奢侈品品牌赝品效应与品牌传播浅析
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作者 郑怡 《才智》 2010年第24期295-295,共1页
奢侈品品牌赝品的存在对奢侈品企业构成了严峻的挑战。本文通过性能指标、知觉指标和财务指标三方面来度量品牌的赝品效应,并提出从赝品流通控制、正品质量优化、潜在需求分析和渠道控制管理四个方面来利用和控制赝品效应以达到奢侈品... 奢侈品品牌赝品的存在对奢侈品企业构成了严峻的挑战。本文通过性能指标、知觉指标和财务指标三方面来度量品牌的赝品效应,并提出从赝品流通控制、正品质量优化、潜在需求分析和渠道控制管理四个方面来利用和控制赝品效应以达到奢侈品品牌传播目的的独特观点。 展开更多
关键词 奢侈品品牌 赝品效应 效应度量模型 品牌传播控制
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引文内容视角下的引文网络知识流动网络分析 被引量:7
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作者 毕崇武 贠婕 +1 位作者 周静虹 叶光辉 《情报科学》 CSSCI 北大核心 2022年第1期79-87,共9页
【目的/意义】从引文内容视角探究引文网络的拓扑结构及其组成要素的知识属性与引文网络中知识流动效应间的关系。【方法/过程】首先,在阐述引文内容视角下引文网络知识流动主要特征的基础上,从静态特征属性和动态结构属性2个方面构建... 【目的/意义】从引文内容视角探究引文网络的拓扑结构及其组成要素的知识属性与引文网络中知识流动效应间的关系。【方法/过程】首先,在阐述引文内容视角下引文网络知识流动主要特征的基础上,从静态特征属性和动态结构属性2个方面构建了知识流动的演化动力模型;然后,依据影响引文网络中知识流动效应的主要因素,从知识吸收效应、知识叠加效应和知识成本效应3个方面构建了知识流动效应函数的数学模型;最后,借鉴描述知识溢出效应的蜂巢模型及其修正模型提出了知识流动效应系数的计算方法。【结果/结论】运用Netlogo设置演化动力模型的初始参数,并通过仿真实验剖析各因素对知识流动效应系数的影响机理。文中方法可为客观反映引文网络中的知识流动规律与模式,并揭示引文网络中的知识流动效应提供一套可参考的实证模型。【创新/局限】本文通过计算实验方法从理论上较为系统地分析了引文内容视角下引文网络的知识流动效应,得出了一系列结论,但并未结合实际题录数据的计算结果进行对比和优化。 展开更多
关键词 知识流动 引文内容 引文网络 效应度量 仿真实验
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中国上市公司会计信息价值相关性的动态分析与动因检验 被引量:8
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作者 赵振全 刘淼 于震 《财贸经济》 CSSCI 北大核心 2007年第6期45-49,10,共6页
本文基于价格模型对我国上市公司会计信息价值相关性在1994—2005年期间的变化情况进行了检验,针对其波动较大的特征,将可能影响价值相关性的因素归纳为两种效应:会计度量效应和投资者行为效应,并利用剩余收益定价模型检验了两种效应的... 本文基于价格模型对我国上市公司会计信息价值相关性在1994—2005年期间的变化情况进行了检验,针对其波动较大的特征,将可能影响价值相关性的因素归纳为两种效应:会计度量效应和投资者行为效应,并利用剩余收益定价模型检验了两种效应的存在性和影响力,结果表明这两种效应是影响我国上市公司会计信息价值相关性的重要因素,且均对会计信息价值相关性表现出负向影响;进一步检验发现如果剔除投资者行为因素的影响,会计信息价值相关性总体水平将显著提高。 展开更多
关键词 会计信息价值相关性 会计度量效应 投资者行为效应 剩余收益定价模型
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Lamella-like electrode with high Br_(2)-entrapping capability and activity enabled by adsorption and spatial confinement effects for brominebased flow battery 被引量:1
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作者 Luyin Tang Tianyu Li +1 位作者 Wenjing Lu Xianfeng Li 《Science Bulletin》 SCIE EI CSCD 2022年第13期1362-1371,M0004,共11页
Bromine-based flow batteries(Br-FBs)are well suitable for stationary energy storage owing to their high energy density and low cost.However,their power density and lifespan are limited by relatively low reaction kinet... Bromine-based flow batteries(Br-FBs)are well suitable for stationary energy storage owing to their high energy density and low cost.However,their power density and lifespan are limited by relatively low reaction kinetics of Br_(2)/Br-couple and serious self-discharge caused by bromine migration.Herein,lamella-like porous carbon nitride nanosheets(PCNS)with adsorption and spatial confinement effects are used to modify cathodes for Br-FBs.The large specific surface area and plentiful N-containing groups enable PCNS with excellent adsorption capacity,which captures bromine species into the pores on PCNS layers.The captured bromine species is subsequently confined in PCNS interlayers due to the strong interaction between bromine species and N-containing groups,thus effectively depressing bromine diffusion/migration.Moreover,the strong bromine adsorption capacity significantly improves the electrochemical activity of PCNS.Consequently,a zinc-bromine flow battery(ZBFB)employing PCNS-modified cathode achieves a high current density of 180 m A cm^(-2),with an ultra-high coulombic efficiency of 99.22%.It also exhibits better self-discharge performance and a long cycle life of 500 cycles.Furthermore,a complexing agent-free ZBFB is successfully realized based on the superior bromineentrapping/retaining capacity of the PCNS-modified cathode.Consequently,this work provides a promising strategy toward electrode modifications for high-performance and long-lifespan Br-FBs. 展开更多
关键词 Bromine-based flow battery Lamella-like electrode Bromine-entrapping capability Strong adsorption capacity Spatial confinement effect
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Effects of bleed hole size on supersonic boundary layer bleed mass flow rate 被引量:8
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作者 Bao-hu ZHANG Yu-xin ZHAO Jun LIU 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2020年第8期652-662,共11页
The bleed hole diameter,depth,and boundary layer thickness are key design parameters of a supersonic bleed system.The evolution trend of single-hole bleed flow coefficient with the ratio of boundary layer thickness to... The bleed hole diameter,depth,and boundary layer thickness are key design parameters of a supersonic bleed system.The evolution trend of single-hole bleed flow coefficient with the ratio of boundary layer thickness to bleed hole diameter and the ratio of bleed hole depth to diameter is investigated by numerical simulations under choking and non-choking conditions.The results show that the subsonic leading edge of the circular hole and the subsonic part of the boundary layer are the main factors causing lateral flow of the bleed hole.The effect of diameter on bleed mass flow rate is due to the viscous effect which reduces the effective diameter.The larger the ratio of displacement thickness to bleed hole diameter,the more obvious the viscous effect is.The depth affects bleed flow rate by changing the opening and closing states of the separation zone.When a certain depth is reached,the development of the boundary layer reduces the effective captured stream tube and thus reduces the bleed mass flow rate.The main objective of the study is to obtain the physical mechanism of the bleed hole size parameters affecting the bleed mass flow rate,and to provide theoretical guidance for the selection of the size of bleed holes in the design of a porous arrays bleed system in hypersonic inlets. 展开更多
关键词 INLET Supersonic bleed Scale effects CHOKING Bleed mass flow rate Lateral flow
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GENERALIZED p-VALUES AND GENERALIZED CONFIDENCE INTERVALS FOR VARIANCE COMPONENTS IN GENERAL RANDOM EFFECT MODEL WITH BALANCED DATA 被引量:9
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作者 Rendao YE Songgui WANG 《Journal of Systems Science & Complexity》 SCIE EI CSCD 2007年第4期572-584,共13页
Various random models with balanced data that are relevant for analyzing practical test data are described, along with several hypothesis testing and interval estimation problems concerning variance components. In thi... Various random models with balanced data that are relevant for analyzing practical test data are described, along with several hypothesis testing and interval estimation problems concerning variance components. In this paper, we mainly consider these problems in general random effect model with balanced data. Exact tests and confidence intervals for a single variance component corresponding to random effect are developed by using generalized p-values and generalized confidence intervals. The resulting procedures are easy to compute and are applicable to small samples. Exact tests and confidence intervals are also established for comparing the random-effects variance components and the sum of random-effects variance components in two independent general random effect models with balanced data. Furthermore, we investigate the statistical properties of the resulting tests. Finally, some simulation results on the type Ⅰ error probability and power of the proposed test are reported. The simulation results indicate that exact test is extremely satisfactory for controlling type Ⅰ error probability. 展开更多
关键词 Generalized confidence interval generalized p-value variance component.
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Mechanocaloric materials for solid-state cooling 被引量:5
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作者 Binfeng Lu Jian Liu 《Science Bulletin》 SCIE EI CAS CSCD 2015年第19期1638-1643,共6页
This article reviews the up-to-date progress in mechanocaloric effect and materials near ambient temperature. For elastocaloric materials, we focus on directly measured temperature change and its entropy origin in non... This article reviews the up-to-date progress in mechanocaloric effect and materials near ambient temperature. For elastocaloric materials, we focus on directly measured temperature change and its entropy origin in nonmagnetic and magnetic shape memory alloys. In terms of barocaloric materials, change in magnetic state, volume and shift of transition temperature due to hydrostatic pressure are systematically compared. We propose advantages and challenges of elastocaloric materials for solidstate cooling. Strategies to enhance elastocaloric and mechanical stability under long-term mechanical cycles are presented. Finally, we conclude with an outlook on the prospect of elastocaloric cooling application. 展开更多
关键词 Elastocaloric effect Barocaloric effect Shape memory alloy ENTROPY
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In situ Raman spectroscopy of topological insulator Bi2Te3 films with varying thickness 被引量:3
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作者 Chunxiao Wang Xiegang Zhu +7 位作者 Louis Nilsson Jing Wen GuangWang Xinyan Shan Qing Zhang Shulin Zhang Jinfeng Jia Qikun Xue 《Nano Research》 SCIE EI CAS CSCD 2013年第9期688-692,共5页
Topological insulators (TIs) are a new state of quantum matter with a band gap in bulk and conducting surface states. In this work, the Raman spectra of topological insulator Bi2Te3 films prepared by molecular beam ... Topological insulators (TIs) are a new state of quantum matter with a band gap in bulk and conducting surface states. In this work, the Raman spectra of topological insulator Bi2Te3 films prepared by molecular beam epitaxy (MBE) have been measured by an in situ ultrahigh vacuum (UHV)-MBE-Raman spectroscopy system. When the thickness of Bi2Te3 films decreases from 40 quintuple-layers (QL) to 1 QL, the spectral characteristics of some Raman modes appearing in bulk Bi2Te3 vary and a new vibrational mode appears, which has not been reported in previous studies and might be related to quantum size effects and symmetry breaking. In addition, an obvious change was observed at 3 QL when a Dirac cone formed. These results offer some new information about the novel quantum states of TIs. 展开更多
关键词 topological insulator in situ Raman spectroscop^surface phonon mode thin film
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Intrinsic viscosity of polymer solutions: fresh ideas to an old problem 被引量:2
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作者 Deyue Yan 《Science China Chemistry》 SCIE EI CAS CSCD 2015年第5期835-838,共4页
Intrinsic viscosity is one of the most fundamental properties of dilute polymer solutions; its study forms an integral part of the cornerstone of the modern macromolecular theory. However, a general theory applicable ... Intrinsic viscosity is one of the most fundamental properties of dilute polymer solutions; its study forms an integral part of the cornerstone of the modern macromolecular theory. However, a general theory applicable to any chain architectures and solvent conditions has remained elusive, due to the formidable challenges in the theoretical treatment of the long-range, many-body and accumulative hydrodynamic effects. Recently, Lijia An and coworkers at the Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, has developed a new approach that largely overcomes these challenges. Their new theory provides a simple and unified theoretical framework for describing the intrinsic viscosity of polymers with arbitrary architectures under any solvent conditions and forms the theoretical basis for inferring the polymer chain structure from intrinsic viscosity measurements. Comparisons with existing experimental data yield extensive, quantitative agreement. 展开更多
关键词 polymer solution intrinsic viscosity polymer chain structure hyperbranched polymers hydrodynamic effects
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