Enhancing selectivity in acidic CO_(2) electrolysis:Cation effects and catalyst innovation

The electrochemical reduction of CO_(2)(eCO_(2)R)under ambient conditions is crucial for reducing carbon emissions and achieving carbon neutrality.Despite progress with alkaline and neutral electrolytes,their efficiency is limited by(bi)carbonates formation.Acidic media have emerged as a solution,addressing the(bi)carbonates challenge but introducing the issue of the hydrogen evolu-tion reaction(HER),which reduces CO_(2) conversion efficiency in acidic environments.This review focuses on enhancing the selectivity of acidic CO_(2) electrolysis.It commences with an overview of the latest advancements in acidic CO_(2) electrolysis,focusing on product selectivity and electrocatalytic activity enhancements.It then delves into the critical factors shaping selectivity in acidic CO_(2) electrolysis,with a special emphasis on the influence of cations and catalyst design.Finally,the research challenges and personal perspectives of acidic CO_(2) electrolysis are suggested.

Durability design of prestressed concrete structures

Based on the durability characteristics of prestressed concrete structures,the durability limit states of carbonation and chloride ion attack are defined, respectively.Durability predicting models on the basis of reliability mathematics and stochastic processes areconstructed, and the pure theoretical formulae of failure probability of prestressed concretestructures are analyzed. In addition, a simple durability design method for carbonation ofstructures is put forward. According to the analysis, the durability of prestressed concretestructures is superior to that of traditional structures. The research also indicates that theconcrete cover prescribed in the current code (GB 50010-2002) is not adequate. The rational coverthickness should notbe less than 35 or 45 mm according to carbonation or chloride ion attack,respectively.

微视频助力小学足球有效性训练提升策略

微视频在教学中的应用,有助于提高小学生的学习兴趣,提升教学工作成效。随着时代的发展,人们对身体素质的要求越来越高,喜欢足球运动的人也越来越多,足球的训练不仅能够帮助小学生提高其身体素质,还能使小学生在团队中真切地感受到团队协作的重要性。所以,学生对足球的感知应从小培养,如何提升小学生的足球训练效率,成为小学体育老师需要解决的重点难题之一。

Hybrid enzyme catalysts synthesized by a de novo approach for expanding biocatalysis

The two major challenges in industrial enzymatic catalysis are the limited number of chemical reaction types that are catalyzed by enzymes and the instability of enzymes under harsh conditions in industrial catalysis.Expanding enzyme catalysis to a larger substrate scope and greater variety of chemical reactions and tuning the microenvironment surrounding enzyme molecules to achieve high enzyme performance are urgently needed.In this account,we focus on our efforts using the de novo approach to synthesis hybrid enzyme catalysts that can address these two challenges and the structure-function relationship is discussed to reveal the principles of designing hybrid enzyme catalysts.We hope that this account will promote further efforts toward fundamental research and wide applications of designed enzyme hybrid catalysts for expanding biocatalysis.

Layout problem of multi-component systems arising for improving maintainability

To improve the mainlainability design efficiency and quality, a layout optimization method for maintainability of multi-component systems was proposed. The impact of the component layout design on system maintainability was analyzed, and the layout problem for maintainability was presented. It was formulated as an optimization problem, where maintainability, layout space and distance requirement were formulated as objective functions. A multi-objective particle swarm optimization algorithm, in which the constrained-domination relationship and the update strategy of the global best were simply modified, was then used to obtain Pareto optimal solutions for the maintainability layout design problem. Finally, application in oxygen generation system of a spacecraft was studied in detail to illustrate the effectiveness and usefulness of the proposed method. The results show that the concurrent maintainability design can be carried out during the layout design process by solving the layout optimization problem for maintainability.

Design strategies and structure‐performance relationships of heterogeneous catalysts for selective hydrogenation of 1,3‐butadiene

Selective hydrogenation of 1,3‐butadiene is an essential process in the upgrading of the crude C4 cut from the petroleum chemical sector.Catalyst design is crucial to achieve a virtually alkadiene‐free product while avoiding over‐hydrogenating valuable olefins.In addition to the great industrial relevance,this demanding selectivity pattern renders 1,3‐butadiene hydrogenation a widely used model reaction to discriminate selective hydrogenation catalysts in academia.Nonetheless,critical reviews on the catalyst development are extremely lacking in literature.In this review,we aim to provide the reader an in‐depth overview of different catalyst families,particularly the precious metal‐based monometallic catalysts(Pd,Pt,and Au),developed in the last half century.The emphasis is placed on the development of new strategies to design high‐performance architectures,the establishment of structure‐performance relationships,and the reaction and deactivation mechanisms.Thrilling directions for future optimization of catalyst formulations and engineering aspect are also provided.

A Comprehensive Mixed Media Model for Boosting Automobile Dealer Visits

This paper validates the effectiveness of a comprehensive mixed media model for effective advertising designed to bring customers into auto dealerships by use of their AIDA （attention, interest, desire, action） model and statistical science to quantitatively assess the effectiveness of various advertising methods using television, newspapers, flyers, direct mail, public transportation, and the internet. This model is applied to a dealership representing a well-known automaker, where its effectiveness is verified.

COST:Coding over Spatial-Temporal Diversity for Low-Duty-Cycle WSNs

In low-duty-cycle wireless sensor networks,designers have to cope with unreliable links and limited communication capacity.In this work,we propose COST,a coding scheme that leverages spatial-temporal diversity to achieve higher energy efficiency and lower delay of packet transmissions.We particularly address long sleeping intervals in low-duty-cycle networks by exploiting multi-path diversity.Specifically,we propose to employ an erasure-coding scheme to improve reliability.With respect to energy efficiency and delivery timeliness,we formulate the problem in optimal allocation of coded blocks over multiple paths,which is then proved to be NP-hard.We further propose a near-optimal algorithm to solve the allocation problem.Through extensive simulations,we evaluate the impact of network parameters and demonstrate the effectiveness of our proposal.

Construction of a growth model in the green alga Tetraselmis subcordiformis using a response surface approach

The green alga Tetraselmis subcordiformis has been widely used as a quality live food for aquaculture species, and also has been studied as a model organism for the photo-biological production of hydrogen. We attempted to quantify the relationship between T. subcordiformis specific growth rate （SGR） and three important environmental factors （temperature, salinity, and pH） using the central composite design and response surface method under laboratory conditions. The results showed that the linear effects of temperature and salinity were significant （P〈0.05）, and they were equally important in impacting T. subcordiformis specific growth; the linear effect of pH was not significant （P〉0.05）; the interactive effect of temperature and pH was significant （P〈0.05）, whereas the temperature ~ salinity and salinity x pH interactions were not significant （P〉0.05）; all of the quadratic effects of the three factors were significant （P〈0.05）. A model equation for specific growth rate with the three factors was established, with the unadjusted and predictive R2 as high as 0.990 and 0.921, respectively, suggesting that the model was a very good fit and that it could be used to predict SGR. Through optimizing the reliable model, an optimal 3-factor combination of 25~C/35 of salinity/pH 7.9 was obtained, at which the maximum specific growth rate （0.65） was recorded, with a desirability value of 93.8%. These experimental results could serve as guidelines for increasing T. subcordiformis production efficiency.

Assessment of Durability and Long Term Performance of High Density Polyethylene Drainboards in the Gotthard Railway Tunnels

Drainage layers provide permanent relief of hydrostatic water pressure, while the waterproof liner prevents any ingress of water into the tunnel. The durability and aging resistance of drainage membranes are of primary concern. This paper describes advantages and concerns related to the usage of, and the design with, polymeric drainboards in tunnel construction. Common degradation mechanisms associated with HDPE （high density polyethylene） sheets are described. The stringent requirements for the Gotthard Alpine Railway Tunnel through the Swiss Alps, e.g., high ambient temperatures of up to 45 ℃ and an expected service life of up to 100 years require outstanding aging resistance of polymeric drainage materials. The paper describes the methods deployed to investigate the long-term performance of HDPE drainboards, focusing on aging mechanisms. Details associated with the test procedures developed to reflect the specific properties of drainboards, as well as the results obtained, are presented. A summary table shows recommended product specifications needed to confine the aging properties of drainboards and to design a system performing adequately during the entire lifetime of the structure.

Construction of column-orthogonal designs for computer experiments

Latin hypercube design and uniform design are two kinds of most popular space-filling designs for computer experiments. The fact that the run size equals the number of factor levels in a Latin hypercube design makes it difficult to be orthogonal. While for a uniform design, it usually has good space-filling properties, but does not necessarily have small or zero correlations between factors. In this paper, we construct a class of column-orthogonal and nearly column-orthogonal designs for computer experiments by rotating groups of factors of orthogonal arrays, which supplement the designs for computer experiments in terms of various run sizes and numbers of factor levels and are flexible in accommodating various combinations of factors with different numbers of levels. The resulting column-orthogonal designs not only have uniformly spaced levels for each factor but also have uncorrelated estimates of the linear effects in first order models. Further, they are 3-orthogonal if the corresponding orthogonal arrays have strength equal to or greater than three. Along with a large factor-to-run ratio, these newly constructed designs are economical and suitable for screening factors for physical experiments.

Rational design of geranylgeranyl diphosphate synthase enhances carotenoid production and improves photosynthetic efficiency in Nicotiana tabacum

Restricted genetic diversity can supply only a limited number of elite genes for modern plant cultivation and transgenesis.In this study,we demonstrate that rational design enables the engineering of geranyl-geranyl diphosphate synthase(NtGGPPS),an enzyme of the methylerythritol phosphate pathway(MEP)in the model plant Nicotiana tabacum.As the crucial bottleneck in carotenoid biosynthesis,NtGGPPS1 interacts with phytoene synthase(NtPSY1)to channel GGPP into the production of carotenoids.Loss of this enzyme in the ntggpps1 mutant leads to decreased carotenoid accumulation.With the aim of enhanc-ing NtGGPPS1 activity,we undertook structure-guided rational redesign of its substrate binding pocket in combination with sequence alignment.The activity of the designed NtGGPPS1(a pentuple mutant of five sites V154A/I161L/F218Y/I209S/V233E,d-NtGGPPS1)was measured by a high-throughput colorimetric assay.d-NtGGPPS1 exhibited significantly higher conversion of IPP and each co-substrate(DMAPP~1995.5-fold,GPP~25.9-fold,and FPP~16.7-fold)for GGPP synthesis compared with wild-type NtGGPPS1.Importantly,the transient and stable expression of d-NtGGPPS1 in the ntggpps1 mutant increased carotenoid levels in leaves,improved photosynthetic efficiency,and increased biomass relative to NtGGPPS1.These findings provide a firm basis for the engineering of GGPPS and will facilitate the development of quality and yield traits.Our results open the door for the structure-guided rational design of elite genes in higher plants。

Uniform design ray in the assessment of combined toxicities of multi-component mixtures

Multi-component mixture(MCM) is a complicated chemical system that contains a great deal of mixture rays with various mixture ratios, and each ray includes many mixtures with different concentration levels.Currently, in combined toxicity field, almost all studies on MCM focus on the mixtures designed by the equivalenteffect concentration ratio(EECR) procedure. However, the EECR mixtures cannot represent the whole mixture system because the EECR mixtures are located on one mixture ray in concentration space formed by multiple components. In our view, some optimal experimental design such as the uniform design(UD) should be used to effectively select many representative mixture rays from the MCM system,instead of single EECR ray. The uniform design ray(UDray) integrating UD idea with fixed-ratio ray design can systematically and comprehensively measure the combined toxicity changes in the MCM system. This review introduces the operation method, construction of uniform table and corresponding usable table, and some cases of application of the UD-ray to help readers easily use UD-ray in their MCM toxicity assessment.

Availability Equivalence Analysis of a Repairable Multi-State Series-Parallel System

The availability equivalence of different designs for a repairable multi-state series-parallel system(RMSPS) is discussed in this paper.The system components are assumed to be independent,and their failure and repair rates to be constant.The system availability is defined as the ability of the system to satisfy consumer demand.Factor improvement method and standby redundancy method are used to improve the system design.To evaluate availability of the both original and improved systems,a fast technique,based on universal generating function,is adopted.The availability equivalence factor is introduced to compare different system designs.Two types of availability equivalence factors of the system are derived.A numerical example is provided to illustrate how to utilize the obtained results.

Fairness of Extra-Gain Guilty in Performance of Supply Chain and Contract Design

Considering a one-supplier and two-retailer supply chain setting in which the supplier makes contacts with retailers in sequence based on FCFS(first–come–first-service) principle, the authors investigate the marginal effect of extra-gain guilty fairness concerns of supply chain members on the contract design, supply chain's profit and profit distribution. When the supplier considers distributional fairness of loss aversion and extra-gain guilty, extra-gain guilty concern reduces the optimal wholesale and retail price, and improves supply chain performance. When the first or the second retailer considers distributional fairness and peer-induced fairness, extra-gain guilty concerns decrease the optimal wholesale and retail price but increase the profit of all supply chain members only when the level of loss aversion is large enough and the level of extra-gain guilty is less than 1/2. However, when the level of loss aversion is small and the level of extra-gain guilty is less than 1/2, extra-gain guilty has no influence on supply chain performance. The analysis reveals that the supply chain performance can be further improved by considering fairness of extra-gain guilty.

Various Effective Resist Diffusion Lengths Methodology for OPC Model Calibration

A various effective resist diffusion lengths methodology for OPC model calibration is proposed,which considers the discrepancy of effective resist diffusion lengths between 1D and 2D patterns. An important step of this methodology is to set up a new calibration flow that lets 1D and 2D patterns have the same optical parameters but different effective diffusion lengths. Furthermore, a design for manufacturing （DFM） interaction is suggested in the calibration flow of the pro- posed model. From the CD errors of fitting results and the comparison between simulated contours and SEM images,it is found that the various effective resist diffusion lengths model calibration methodology results in a more accurate and stable model.

Design of large-core single-mode Yb^(3+)-doped photonic crystal fiber

The effective index of the cladding fundamental space-filling mode in photonic crystal fiber (PCF) is simulated by the effective index method. The variation of the effective index with the structure parameters of the fiber is achieved. For the first time, the relations of the V parameter of Yb3+-doped PCF with the refractive index of core and the structure parameters of the fiber are provided. the single-mode characteristics of large-core Yb3+-doped photonic crystal fibers with 7 and 19 missing air holes in the core are analyzed. The large-core single-mode Yb3+-doped photonic crystal fibers with core diameters of 50 μm, 100 μm and 150 μm are designed. The results provide theory instruction for the design and fabrication of fiber.

A series of dithienobenzodithiophene based small molecules for highly efficient organic solar cells

Three acceptor-donor-acceptor （A-D-A） small molecules DCAODTBDT, DRDTBDT and DTBDTBDT using dithieno[2,3-d：2＇,3＇-d＇]benzo[1,2-b：4,5-b＇]dithiophene as the central building block, octyl cyanoacetate, 3-octylrhodanine and thiobarbituric acid as the end groups were designed and synthesized as donor materials in solution-processed photovoltaic cells （OPVs）. The impacts of these different electron withdrawing end groups on the photophysical properties, energy levels, charge carrier mobility, morphologies of blend films, and their photovoltaic properties have been systematically investigated. OPVs device based on DRDTBDT gave the best power conversion efficiency （PCE） of 8.34%, which was significantly higher than that based on DCAODTBDT （4.83%） or DTBDTBDT （3.39%）. These results indicate that rather dedicated and balanced consideration of absorption, energy levels, morphology, mobility, etc. for the design of small-molecule-based OPVs （SM-OPVs） and systematic investigations are highly needed to achieve high performance for SM-OPVs.