Thermophotovoltaic (TPV) system has been regarded as one promising means to alleviate current energy demand because it can directly generate electricity from radiation heat via photons. However, the presently availa...Thermophotovoltaic (TPV) system has been regarded as one promising means to alleviate current energy demand because it can directly generate electricity from radiation heat via photons. However, the presently available TPV systems suffer from low conversion efficiency and low throughput. A viable solution to increase their efficiency is to apply micro/nanoscale radiation principles in the design of different components to utilize the characteristics ~f thermal radiation at small distances and in microstructures. Several critical issues are reviewed, such as photovoltaic effect, quantum efficiency and efficiency of TPV system. Emphasis is given to the development of wavelength-selective emitters and filters and the aspects of micro/nanoscale heat transfer. Recent progress, along with the challenges and opportunities for future development of TPV systems are also outlined.展开更多
Today, energy saving is one of the main objectives for engineers. In the case of mobile applications, energy can be saved by two different ways: decreasing the total masse of the system and increasing the efficiency ...Today, energy saving is one of the main objectives for engineers. In the case of mobile applications, energy can be saved by two different ways: decreasing the total masse of the system and increasing the efficiency of the overall system. This paper presents two optimization strategies to design a predefined multichannel structure of a boost converter which is dedicated to a solar airplane and used to interface PV panels and the battery system. The first strategy is a multi-criterion method that is able to trace the dependency between the converter's efficiency and its power density through the intermediary of the Pareto front. The second method, a mono-criterion approach, maximizes efficiency while respecting the constraint imposed on power density. The mono-criterion method that is applied to maximizing the European efficiency criterion showed that an increase in the number of channels enhanced the quantity of energy collected over a day by increasing the power density of the converter. At the end of the paper, the optimal design calculated was built to give an example of the result obtained by this design methodology. The results of the efficiency measurements made on a realized prototype are presented in this paper.展开更多
Al-doped ZnO(AZO) has been used as an electron transport and hole blocking buffer layer in inverted organic solar cells(IOSCs). In this paper, the AZO morphology, optical and structural properties and IOSCs performanc...Al-doped ZnO(AZO) has been used as an electron transport and hole blocking buffer layer in inverted organic solar cells(IOSCs). In this paper, the AZO morphology, optical and structural properties and IOSCs performance are investigated as a function of precursor solution concentration from 0.1 mol/L to 1.0 mol/L. We demonstrate that the device with 0.1 mol/L precursor concentration of AZO buffer layers enhances the short-circuit current and the fill factor of IOSCs simultaneously. The resulting device shows that the power conversion efficiency is improved by 35.6% relative to that of the 1.0 mol/L device, due to the improved surface morphology and transmittance(300–400 nm) of AZO buffer layer.展开更多
In recent years, the performance of organic thinfilm solar cells has gained rapid progress, of which the power conversion efficiencies (r/p) of 3%-5% are commonly achieved, which were difficult to obtain years ago a...In recent years, the performance of organic thinfilm solar cells has gained rapid progress, of which the power conversion efficiencies (r/p) of 3%-5% are commonly achieved, which were difficult to obtain years ago and are improving steadily now. The r/p of 7.4% was achieved in the year 2010, and r/p of 9.2% was disclosed and confirmed at website of Mitsubishi Chemical in April, 2011. The promising future is that the r/p of 10% is achievable according to simulation results. Apparently, these are attributed to material innovations, new device structures, and also the better understanding of device physics. This article summarizes recent progress in organic thinfilm solar cells related to materials, device structures and working principles. In the device functioning part, after each brief summary of the working principle, the methods for improvements, such as absorption increment, organic/electrode interface engineering, morphological issues, are addressed and summarized accordingly. In addition, for the purpose of increasing exciton diffusion efficiency, the benefit from triplet exciton, which has been proposed in recent years, is highlighted. In the active material parts, the chemical nature of materials and its impact on device performance are discussed. Particularly, emphasis is given toward the insight for better understanding device physics as well as improvements in device performance either by development of new materials or by new device architecture.展开更多
With the rapid development in recent years, small-molecule organic solar cell is challenging the dominance of its counterpart, polymer solar cell. The top power conversion efficiencies of both single and tandem solar ...With the rapid development in recent years, small-molecule organic solar cell is challenging the dominance of its counterpart, polymer solar cell. The top power conversion efficiencies of both single and tandem solar cells based on small molecules have surpassed 9%. In this mini review, achievements of small molecules with impressive photovoltaic performance especially reported in the last two years were highlighted. The relationship between molecular structure and device performance was analyzed, which draws some rules for rational molecular design. Five series of p- and n-type small molecules were selected based on the consideration of their competitiveness of power conversion efficiencies.展开更多
Antiferromagnetic (AFM) materials have attracted wide attention in spin-orbit torque (SOT)-based spintronic due to its abundant spin-dependent properties and unique advantage of immunity against external field perturb...Antiferromagnetic (AFM) materials have attracted wide attention in spin-orbit torque (SOT)-based spintronic due to its abundant spin-dependent properties and unique advantage of immunity against external field perturbations.To act as the charge-to-spin conversion source in energy-saving spintronic devices,it is of great importance for the AFM material to possess a large spin torque efficiency(ξDL).In this work,using the spin torque ferromagnetic resonance (ST-FMR) technique and a Mn2Au/Ni Fe(Py) bilayer system,we systemically study the ξDLof AFM Mn2Au films with different crystal structures.Compared with polycrystalline Mn2Au with effective ξDL<0.051,we show a much larger ξDLof~0.333 in single-crystal Mn2Au,which arises from the large spin Hall conductivity instead of electrical resistivity.Moreover,with a further contribution of interfacial effects,the effective ξDLof single-crystalline Mn2Au/Py system increases to 0.731,which is more than two times larger than the value of ~0.22 reported for the Mn2Au/CoFeB system.By utilizing the largeξDLof Mn2Au in a perpendicularly magnetized Mn Ga/Mn2Au system,energy-efficient deterministic magnetization switching with a current density at ~10^(6)A cm^(-2)is achieved.Our results reveal a significant potential of Mn2Au as an efficient SOT source and shed light on its application in future AFM material-based SOT integration technology.展开更多
A novel complex nanostructured TiO2 electrode and fabrication process were proposed and demonstrated to improve the performance of dye-sensitized solar cells(DSSCs).In the proposed process,a nanoporous TiO2 layer was ...A novel complex nanostructured TiO2 electrode and fabrication process were proposed and demonstrated to improve the performance of dye-sensitized solar cells(DSSCs).In the proposed process,a nanoporous TiO2 layer was firstly fabricated on the FTO(fluorine-doped tin oxide) conducting substrate by an anodization process,then a nanoparticulate TiO2 film was deposited on the nanoporous TiO2 layer by the screen printed method to form the complex nanostructured TiO2 electrode.The experiments demonstrated that the nanoporous TiO layer can enhance the light scattering,decrease the contact resistance between TiO2 electrode and FTO,and suppress the recombination of I3-ion with the injected electrons of FTO.The process variables are crucial to obtain the optimized performance of DSSCs.By adopting the optimized process,improved conversion efficiency of DSSCs was achieved at AM 1.5 sunlight.展开更多
基金Project(2009AA05Z215) supported by the National High Technology Research and Development Program of China
文摘Thermophotovoltaic (TPV) system has been regarded as one promising means to alleviate current energy demand because it can directly generate electricity from radiation heat via photons. However, the presently available TPV systems suffer from low conversion efficiency and low throughput. A viable solution to increase their efficiency is to apply micro/nanoscale radiation principles in the design of different components to utilize the characteristics ~f thermal radiation at small distances and in microstructures. Several critical issues are reviewed, such as photovoltaic effect, quantum efficiency and efficiency of TPV system. Emphasis is given to the development of wavelength-selective emitters and filters and the aspects of micro/nanoscale heat transfer. Recent progress, along with the challenges and opportunities for future development of TPV systems are also outlined.
文摘Today, energy saving is one of the main objectives for engineers. In the case of mobile applications, energy can be saved by two different ways: decreasing the total masse of the system and increasing the efficiency of the overall system. This paper presents two optimization strategies to design a predefined multichannel structure of a boost converter which is dedicated to a solar airplane and used to interface PV panels and the battery system. The first strategy is a multi-criterion method that is able to trace the dependency between the converter's efficiency and its power density through the intermediary of the Pareto front. The second method, a mono-criterion approach, maximizes efficiency while respecting the constraint imposed on power density. The mono-criterion method that is applied to maximizing the European efficiency criterion showed that an increase in the number of channels enhanced the quantity of energy collected over a day by increasing the power density of the converter. At the end of the paper, the optimal design calculated was built to give an example of the result obtained by this design methodology. The results of the efficiency measurements made on a realized prototype are presented in this paper.
基金supported by the National Natural Science Foundation of China(No.61377031)the Scientific Research Foundation of Zhejiang Ocean University(No.Q1444)
文摘Al-doped ZnO(AZO) has been used as an electron transport and hole blocking buffer layer in inverted organic solar cells(IOSCs). In this paper, the AZO morphology, optical and structural properties and IOSCs performance are investigated as a function of precursor solution concentration from 0.1 mol/L to 1.0 mol/L. We demonstrate that the device with 0.1 mol/L precursor concentration of AZO buffer layers enhances the short-circuit current and the fill factor of IOSCs simultaneously. The resulting device shows that the power conversion efficiency is improved by 35.6% relative to that of the 1.0 mol/L device, due to the improved surface morphology and transmittance(300–400 nm) of AZO buffer layer.
基金supported by the National Natural Science Foundation of China (20974046, 61077021 & 61076016)New Century Excellent Talents funding from Ministry of Education of China (NCET-08-0697)National Basic Research Program of China (973 Program, 2009CB930600)
文摘In recent years, the performance of organic thinfilm solar cells has gained rapid progress, of which the power conversion efficiencies (r/p) of 3%-5% are commonly achieved, which were difficult to obtain years ago and are improving steadily now. The r/p of 7.4% was achieved in the year 2010, and r/p of 9.2% was disclosed and confirmed at website of Mitsubishi Chemical in April, 2011. The promising future is that the r/p of 10% is achievable according to simulation results. Apparently, these are attributed to material innovations, new device structures, and also the better understanding of device physics. This article summarizes recent progress in organic thinfilm solar cells related to materials, device structures and working principles. In the device functioning part, after each brief summary of the working principle, the methods for improvements, such as absorption increment, organic/electrode interface engineering, morphological issues, are addressed and summarized accordingly. In addition, for the purpose of increasing exciton diffusion efficiency, the benefit from triplet exciton, which has been proposed in recent years, is highlighted. In the active material parts, the chemical nature of materials and its impact on device performance are discussed. Particularly, emphasis is given toward the insight for better understanding device physics as well as improvements in device performance either by development of new materials or by new device architecture.
基金supported by the National Basic Research Program of China(2014CB643502)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB12010200)the National Natural Science Foundation of China(91333113)
文摘With the rapid development in recent years, small-molecule organic solar cell is challenging the dominance of its counterpart, polymer solar cell. The top power conversion efficiencies of both single and tandem solar cells based on small molecules have surpassed 9%. In this mini review, achievements of small molecules with impressive photovoltaic performance especially reported in the last two years were highlighted. The relationship between molecular structure and device performance was analyzed, which draws some rules for rational molecular design. Five series of p- and n-type small molecules were selected based on the consideration of their competitiveness of power conversion efficiencies.
基金supported by the Agency for Science,Technology and Research (A*STAR) of Singapore (A1983c0036)the Singapore Ministry of Education (MOE2018-T2-2043)A*STAR IAF-ICP 11801E0036。
文摘Antiferromagnetic (AFM) materials have attracted wide attention in spin-orbit torque (SOT)-based spintronic due to its abundant spin-dependent properties and unique advantage of immunity against external field perturbations.To act as the charge-to-spin conversion source in energy-saving spintronic devices,it is of great importance for the AFM material to possess a large spin torque efficiency(ξDL).In this work,using the spin torque ferromagnetic resonance (ST-FMR) technique and a Mn2Au/Ni Fe(Py) bilayer system,we systemically study the ξDLof AFM Mn2Au films with different crystal structures.Compared with polycrystalline Mn2Au with effective ξDL<0.051,we show a much larger ξDLof~0.333 in single-crystal Mn2Au,which arises from the large spin Hall conductivity instead of electrical resistivity.Moreover,with a further contribution of interfacial effects,the effective ξDLof single-crystalline Mn2Au/Py system increases to 0.731,which is more than two times larger than the value of ~0.22 reported for the Mn2Au/CoFeB system.By utilizing the largeξDLof Mn2Au in a perpendicularly magnetized Mn Ga/Mn2Au system,energy-efficient deterministic magnetization switching with a current density at ~10^(6)A cm^(-2)is achieved.Our results reveal a significant potential of Mn2Au as an efficient SOT source and shed light on its application in future AFM material-based SOT integration technology.
基金supported by the National Natural Science Foundation of China (Grant Nos. 60906040,60925015)the Shanghai Nano Project(Grant No. 11nm0500600)
文摘A novel complex nanostructured TiO2 electrode and fabrication process were proposed and demonstrated to improve the performance of dye-sensitized solar cells(DSSCs).In the proposed process,a nanoporous TiO2 layer was firstly fabricated on the FTO(fluorine-doped tin oxide) conducting substrate by an anodization process,then a nanoparticulate TiO2 film was deposited on the nanoporous TiO2 layer by the screen printed method to form the complex nanostructured TiO2 electrode.The experiments demonstrated that the nanoporous TiO layer can enhance the light scattering,decrease the contact resistance between TiO2 electrode and FTO,and suppress the recombination of I3-ion with the injected electrons of FTO.The process variables are crucial to obtain the optimized performance of DSSCs.By adopting the optimized process,improved conversion efficiency of DSSCs was achieved at AM 1.5 sunlight.