敏化型304不锈钢在约100℃硫酸钠溶液中的晶间应力腐蚀断裂

用板材拉伸试样在５０－１２５℃０．０１ＭＮａ２ＳＯ４溶液中研究了恒载荷、低应变速率下敏化型３０４（ＵＮＳ２３０４００）不锈钢的晶间应力腐蚀断裂（ＩＧＳＣＣ）敏感性。在１２５℃，晶间应力腐蚀断裂的敏感性主要处于钝化区的中部，ＩＧＳＣＣ的临界电位（Ｅｃｒｉｔ）接近于钝化电位，这与以前在１５０℃下的试验结果一致。但在７５℃和１００℃，ＩＧＳＣＣ却存在于活化到钝化的过渡电位区域内。在钝化电位以上。

p-型和pn-型染料敏化太阳能电池

针对(1)p-型染料敏化太阳能电池(DSCs)存在的科学问题,即光阴极染料的吸附量偏低和电池内部的暗反应比较严重和(2)pn-型DSCs存在的光阳极和光阴极不匹配等问题,从电极、染料和电解质三个方面系统综述了p-型和pn-型DSCs的研究进展并分析了问题可行的解决方案,最后对p-型和pn-型DSCs的发展前景进行了展望.

基于p型光电极的染料敏化太阳能电池研究进展

基于p型光电极的染料敏化太阳能电池是一种受到广泛关注的新型太阳能电池。根据电池的结构不同可以将其分为p型和p-n叠层型染料敏化太阳能电池。其中p-n型叠层染料敏化太阳能电池的理论光电效率可以达到43%,高于传统的基于n型TiO_2光阳极的染料敏化太阳能电池理论效率(30%),引起了科学界的高度关注。本文将总结基于p型光电极染料敏化太阳能电池(p型和p-n型叠层器件)的研究成果,重点介绍用于p型和p-n型叠层染料敏化太阳能电池的电极材料,染料及电解质的研究进展;同时总结目前该类电池发展中亟需解决的问题以及进一步提高器件效率的途径。

提高JWL-Ⅲ型高温敏化乳化炸药威力的研究

通过增加管路预混器,调整配方中硝酸钠及其水分含量、油水相温度工艺参数,采用一体化复合油相材料等措施,经工程爆破试验验证,炸药单耗和爆破成本均有不同程度的降低,且提高了JWL-Ⅲ型高温敏化乳化炸药威力。

Modeling Seasonal Variations of Subsurface Chlorophyll Maximum in South China Sea

In the South China Sea(SCS), the subsurface chlorophyll maximum(SCM) is frequently observed while the mechanisms of SCM occurrence have not been well understood. In this study, a 1-D physical-biochemical coupled model was used to study the seasonal variations of vertical profiles of chlorophyll-a(Chl-a) in the SCS. Three parameters(i.e., SCM layer(SCML) depth, thickness, and intensity) were defined to characterize the vertical distribution of Chl-a in SCML and were obtained by fitting the vertical profile of Chl-a in the subsurface layer using a Gaussian function. The seasonal variations of SCMs are reproduced reasonably well compared to the observations. The annual averages of SCML depth, thickness, and intensity are 75 ± 10 m, 31 ± 6.7 m, and 0.37 ± 0.11 mg m-3, respectively. A thick, close to surface SCML together with a higher intensity occurs during the northeastern monsoon. Both the SCML thickness and intensity are sensitive to the changes of surface wind speed in winter and summer, but the surface wind speed exerts a minor influence on the SCML depth; for example, double strengthening of the southwestern monsoon in summer can lead to the thickening of SCML by 46%, the intensity decreasing by 30%, and the shoaling by 6%. This is because part of nutrients are pumped from the upper nutricline to the surface mixed layer by strong vertical mixing. Increasing initial nutrient concentrations by two times will increase the intensity of SCML by over 80% in winter and spring. The sensitivity analysis indicates that light attenuation is critical to the three parameters of SCM. Decreasing background light attenuation by 20% extends the euphotic zone, makes SCML deeper(~20%) and thicker(12% – 41%), and increases the intensity by over 16%. Overall, the depth of SCML is mainly controlled by light attenuation, and the SCML thickness and intensity are closely associated with wind and initial nitrate concentration in the SCS.

Unrealistic treatment of detrained water substance in FGOALS-s2 and its influence on the model's climate sensitivity

Based on a series of aqua-planet and air–sea coupled experiments,the influence of unrealistic treatment of water substance in the Flexible Global Ocean–Atmosphere–Land System Model,spectral version 2（FGOALS-s2）,on the model＇s climate sensitivity is investigated in this paper.Because the model does not adopt an explicit microphysics scheme,the detrained water substance from the convection scheme is converted back to the humidity.This procedure could lead to an additional increase of water vapor in the atmosphere,which could strengthen the model＇s climate sensitivity.Further sensitivity experiments confirm this deduction.After removing the water vapor converted from the detrained water substance,the water vapor reduced significantly in the upper troposphere and the high clouds also reduced.Quantitative calculations show that the water vapor reduced almost 10% of the total water vapor,and 50% at 150 h Pa,when the detrained water substance was removed,contributing to the 30% atmospheric surface temperature increase.This study calls for an explicit microphysics scheme to be introduced into the model in order to handle the detrained water vapor and thus improve the model＇s simulation skill.

A Comparative Visualization Strategy of Probabilistic Susceptibility Maps for Analyzing Different Types of Slope Failures

This paper presents a comparative visualization strategy of slope failure susceptibility maps for analyzing different types of simultaneous occurrences of slope failures. Through the SEM （structural equation modeling）, slope failure susceptibility maps are produced by using causal factors （i.e., geographical information, satellite remotely sensed data）. As for a conventional pair-wise comparative procedure, the differences between susceptibility maps are delineated on difference maps, that can be, however, applied for evaluating differences only between pairs of susceptibility maps. One of the strong requirements from specialists working on slope stability evaluation is a comparative and visualization strategy of susceptibility maps with respect to ＂different types of simultaneous slope failures＂, for which the discussion is insufficient in the previous research activities for constructing the quantitative models for slope failure hazard mapping. As a measure, a color composite map based on susceptibility maps has been produced. The combination of assigning susceptibility maps to RGB-color planes is determined based on an index of ＂NCCT （normalized correlated color temperature）＂ which represents the relationship between chromaticity and human visual perception. Through the cases examined, the result indicates that the proposed color composite map, as a heuristic visualization strategy, is useful for simultaneously evaluating the hazardous areas affected by ＂different types of slope failures＂.

Sensitivity of Climate Changes to CO_2 Emissions in China

In this study, the authors demonstrate that the Coupled Model Intercomparison Project Phase 5 （CMIP5） models project a robust response in changes of mean and climate extremes to warming in China. Under a scenario of a 1% CO2 increase per year, surface temperature in China is projected to increase more rapidly than the global average, and the model ensemble projects more precipitation （2.2%/℃）. Responses in changes of climate extremes are generally much stronger than that of climate means. The majority of models project a consistent re- sponse, with more warm events but fewer cold events in China due to CO2 warming. For example, the ensemble mean indicates a high positive sensitivity for increasing summer days （12.4%/℃） and tropical nights （26.0%/℃）, but a negative sensitivity for decreasing frost days （-4.7%/℃） and ice days （-7.0%/℃）. Further analyses indicate that precipitation in China is likely to become more extreme, featuring a high positive sensitivity. The sensitivity is high （2.4%/℃） for heavy precipitation days （〉 10 mm d l） and increases dramatically （5.3%/℃） for very heavy precipitation days （〉 20 mm d-1）, as well as for precipitation amounts on very wet days （10.8%/℃） and extremely wet days （22.0%/℃）. Thus, it is concluded that the more extreme precipitation events generally show higher sensitivity to CO2 warming. Additionally, southern China is projected to experience an increased risk of drought and flood occurrence, while an increased risk of flood but a decreased risk of drought is likely in other regions of China.

Flow behavior and fracture of Al−Mg−Si alloy at cryogenic temperatures

The tensile and fracture behaviors of AA6061 alloy were investigated in order to provide quantitative data about this alloy at cryogenic temperatures.Specimens of AA6061 alloy were solution heat treated before tensile tests at 298,173 and 77 K and tested at strain rates in the range from 0.1 to 0.0001 s^(−1).The results indicate the suppression of the Portevin−Le Chatelier(PLC)effect and dynamic strain aging(DSA)at 77 K.In contrast,at 298 K,a remarkable serrated flow,characteristic of the PLC effect,is observed.Furthermore,the tensile behavior at 77 K,compared with that observed at 173 and 298 K,shows a simultaneous increase in strength,uniform elongation,modulus of toughness,strain-hardening exponent and strain rate sensitivity,which is related to a decrease in the dynamic recovery rate at low temperature.These responses are reflected on the fracture morphology,since the dimple size decreases at 77 K,while the area covered by dimples increases.Comparisons of the Johnson−Cook model show that a good agreement can be obtained for tests at 173 and 77 K,in which DSA is suppressed.

Explicit diagnosis of the local ozone production rate and the ozone-NOx-VOC sensitivities

In the troposphere, ozone is a harmful gas compound to both human health and vegetation. Ozone is produced from the reaction of NO_x(@NO + NO_2) and VOCs(volatile organic compounds) with light. Due to the highly nonlinear relationships between ozone and its precursors, proper ozone mitigation relies on the knowledge of chemical mechanisms. In this study, an observation-based method is used to simulate ozone formation and elucidate its controlling factors for a rural site on the North China Plain. The instantaneous ozone production rate is calculated utilizing a box model using the dataset obtained from the Wangdu campaign. First, the model was operated in a time-dependent mode to calculate the ozone production rate at each time stamp. The calculated ozone formation rate showed a diurnal average maximum value of 17 ppbv/h(1-h diurnal averaged). The contribution of individual peroxy radicals to ozone production was analyzed. In addition, the functional dependence of calculated P(O_3) reveals that ozone production was in a NO_x-limited regime during the campaign. Furthermore, the missing peroxy radical source will further extend NO_x-limited conditions to earlier in the day, making NO_xlimitation dominate more of a day than the current chemical model predicts. Finally, a multiple scenarios mode,also known as EKMA(empirical kinetic modeling approach), was used to simulate the response of P(O_3) to the imaginary change in precursor concentrations. We found that ozone production was in the NO_x-limited region. However, the use of NO_2 measured by the molybdenum converter and/or the absence of a peroxy radical source in the current chemical model could over-emphasize the VOC-limited effect on ozone production.

Effect of Pingan Fang, a Traditional Chinese Medicine compound, on behavioral sensitization and conditioned place preference induced by ethanol in mice

OBJECTIVE:To observe the effect of Pingan Fang(PG)on behavioral sensitization and conditioned place preference(CPP)induced by ethanol in mice,and to determine the intervention mechanism of PG on alcohol addiction.METHODS:A behavioral sensitization mouse model induced by ethanol was established to observe the effect of PG on the development and expression of behavioral sensitization induced by ethanol by recording the spontaneous activity of mice.The resident time of mice in a white box was measured to evaluate the effect of PG on developing CPP induced by ethanol.Concentrations of dopamine(DA),Glutamate(Glu),and?-aminobutyric acid(GABA)in the corresponding mesolimbic region of mice were determined by enzyme-linked immunosorbent assay.RESULTS:Although PG did not alter spontaneous activity in mice,it reduced the growth of spontaneous activity stimulated by ethanol.The residence time in the white box after-ethanol-training of mice in CPP experiments was decreased.CONCLUSION:Our data suggested that PG blocked the development and expression of behavioral sensitization induced by ethanol and the development of CPP in mice.The mechanism might be related to the decreased content of DA and Glu and increased content of GABA in the mesolimbic dopamine system.This suggests that PG might be useful for the prevention and treatment of alcohol addiction.

Irritable bowel syndrome with diarrhea (IBS-D) treated with moxibustion on heat-sensitive acupoints: a randomized controlled trial

Objective To compare the effects between acupuncture combined with moxibustion on heat-sensitive acupoints and acupuncture on irritable bowel syndrome with diarrhea （IBS-D）. Methods Sixty-four cases were randomly divided into an acupuncture and moxibustion group （n=32） and an acupuncture group （n=32）. Conventional acupuncture at Tiānshū （天枢 ST 14）, Zúsānlǐ （足三里 ST 36）, Gōngsūn （公孙 SP 4） and other acupoints was used in the two groups, and moxibustion on heat-sensitive acupoints was added in the acupuncture and moxibustion group. The treatment frequency was 5 times a week, and 4 weeks were a course. After 2 courses, the therapeutic effect was evaluated. Results The clinical symptom scores after treatment in two groups decreased obviously than those before treatment （both P〈0.01）. The cured and markedly effective rate in the acupuncture and moxibustion group was 87.5% （28/32）, and that in the acupuncture group was 37.5% （12/32）, so the effect in the acupuncture and moxibustion group was better than that in the acupuncture group （P〈0.01）. The improvement of all kinds of symptom scores in the acupuncture and moxibustion group was all better than that in the acupuncture group （all P〈0.05）. Conclusion The clinical effect of acupuncture combined with moxibustion on heat-sensitive acupoints on IBS-D is better than that of acupuncture.

Topology optimization of thermoelastic structures using the guide-weight method

The guide-weight method is introduced to solve the topology optimization problems of thermoelastic structures in this paper.First,the solid isotropic microstructure with penalization(SIMP)with different penalty factors is selected as a material interpolation model for the thermal and mechanical fields.The general criteria of the guide-weight method is then presented.Two types of iteration formulas of the guide-weight method are applied to the topology optimization of thermoelastic structures,one of which is to minimize the mean compliance of the structure with material constraint,whereas the other one is to minimize the total weight with displacement constraint.For each type of problem,sensitivity analysis is conducted based on SIMP model.Finally,four classical 2-dimensional numerical examples and a 3-dimensional numerical example considering the thermal field are selected to perform calculation.The factors that affect the optimal topology are discussed,and the performance of the guide-weight method is tested.The results show that the guide-weight method has the advantages of simple iterative formula,fast convergence and relatively clear topology result.

Rutile TiO2 Microspheres with Exposed Nano-Acicular Single Crystals for Dye-Sensitized Solar Cells

Uniquely structured rutile TiO2 microspheres with exposed nano-acicular single crystals have been successfully synthesized via a facile hydrothermal method. After calcination at 450 ℃ for 2 h, the futile TiO2 microspheres with a high surface area of 132 m2/g have been utilized as a light harvesting enhancement material for dye-sensitized solar cells （DSSCs）. The resultant DSSCs exhibit an overall light conversion efficiency of 8.41% for TiO2 photoanodes made of futile TiO2 microspheres and anatase TiO, nanoparticles （mass ratio of 1：1）, significantly higher than that of pure anatase TiO2 nanoparticle photoanodes of similar thickness （6.74%）. Such a significant improvement in performance can be attributed to the enhanced light harvesting capability and synergetic electron transfer effect. This is because the photoanodes made of futile TiO2 microsphere possess high refractive index which improves the light utilisation efficiency, suitable microsphere core sizes （450-800 nm） to effectively scatter visible light, high surface area for dye loading, and synergetic electron transfer effects between nanoparticulate anatase and nano-acicular futile single crystals phases giving high electron collection efficiency.