卧式敏化机在M型乳化炸药生产线的应用

通过介绍乳化炸药生产线敏化工艺技术的研发,立式二级搅拌式敏化器和卧式敏化机生产工艺和特点、卧式敏化机的技术优势及创新、卧式敏化机工作原理、技术前景及推广等,论述卧式敏化机在乳化炸药生产过程中的应用,其敏化工序是乳化炸药生产线的关键工序,乳化基质混拌及敏化效果如何将直接影响到乳化炸药产品的性能指标和安全,因此敏化设备的选型是否适合乳化线的生产,是保证投产后产品质量的关键,对敏化器的积极研发,以实现乳化炸药生产线本质安全化。

乳化炸药敏化机的改进

我厂使用的敏化机原设计为料筒和炸药的重力直接作用在聚四氟乙烯套上.尽管该套耐腐蚀,耐老化,不吸水,耐高温,磨擦系数小,有自润滑性,但作用力太大造成密封套损坏频繁,密封效果差,轴头漏料.基质进入轴承中,在长时间的研磨作用下,很容易发生安全事故.

化学发泡敏化机中搅拌器结构的研究

在乳化炸药化学发泡敏化过程中,均匀混合对反应的均匀性和反应热的控制都是重要的。本文旨在探索一种新颖的辐射流搅拌器结构,并通过实验与研究可以达到均匀的剪切、混合与分散作用。

钢带凉药、敏化自动控制系统的研制

介绍了一种胶状乳化炸药生产线钢带凉药及敏化过程自动控制系统的研究,该系统既能够解决凉药、敏化工序无人化操作问题,又能控制钢带凉药基质药面厚度、减小传爆隐患,降低工房存药量,实现安全、优质、增效、节能的效果。

乳化炸药连续乳化生产工艺及设备设计初探

叙述了乳化炸药连续生产工艺 ,论述了设备的设计和选型的有关问题 ,并得出相应的结论。

Mechanized Seed Production of Xinhunyou No.6 through Mixed Seeding of Parents' Seeds

Hybrid rice Xinhunyou No. 6 could be cultivated by mixing male and fe- male parents and performing seedling raising followed by transplanting, mechanical planting or mechanical direct seeding according to the production methods of com- mercial rice. During flowering stage, leaf cutting, application of ＂920＂ and pollination were conducted; after pollination, bentazon with a certain concentration was sprayed to kill the male parent; and the hybrid rice was harvested mechanically. Before storage, color separation was performed to remove little remaining male parent, thereby achieving whole-process mechanization of hybrid rice seed production. This study introduced mechanized seed production of Xinhunyou No. 6 through mixed- seeding from the aspects including mechanical direct seeding, seeding raising fol- lowed by transplanting and mechanical planting.

民爆专利信息

专利名称：乳化炸药基质连续敏化机 本实用新型公开了一种乳化炸药基质连续敏化机，它由驱动装置、进料装置、混合输料装置、出料装置及机架组合而成。进料装置由进料斗、压料叶片、压料电机构成；混合输料装置由机体、输送螺杆组成；出料装置安装在混合输料装置的末端。本实用新型具有敏化效率高，适用性广，敏化密度、生产能力灵活可调，对乳化炸药基质破坏性小，安全可靠等优点。可广泛应用于高、中、低温敏化及物理、化学及物理化学联合敏化工艺，特别适用于自动化、机械化连续生产乳化炸药生产线的敏化工艺。

Photovoltaic Performance of Triphenylamine Dyes-sensitized Solar Cells Employing Cobalt Redox Shuttle and Influence of π-conjugated Spacers

Developing photosensitizers suitable for the cobalt electrolyte and understanding the structure-property relationship of organic dyes is warranted for the dye-sensitized solar cells （DSSCs）. The DSSCs incorporating tris（1,10-phenanthroline）eobalt（Ⅱ/Ⅲ）-based redox elec- trolyte and four synthesized organic dyes as photosensitizers are described. The photovoltaic performance of these dyes-sensitized solar cells employing the cobalt redox shuttle and the influences of the w-conjugated spacers of organic dyes upon the photovoltage and photocur- rent of mesoscopic titania solar cells are investigated. It is found that organic dyes with thiophene derivates as linkers are suitable for DSSCs employing cobalt electrolytes. DSSCs sensitized with the as-synthesized dyes in combination with the cobalt redox shuttle yield an overall power conversion efficiency of 6.1% under 100 mW/cm2 AM1.5 G illumination.

Functional dyspepsia:The role of visceral hypersensitivity in its pathogenesis

Functional, or non-ulcer, dyspepsia （FD） is one of the most common reasons for referral to gastroenterologists. It is associated with significant morbidity and impaired quality of life. Many authorities believe that functional dyspepsia and irritable bowel syndrome represent part of the spectrum of the same disease process. The pathophysiology of FD remains unclear but several theories have been proposed including visceral hypersensitivity, gastric motor dysfunction, Helicobacter pylori infection and psychosocial factors. In this review, we look at the evidence, to date, for the role of visceral hypersensitivity in the aetiology of FD.

Doping [Ru(bpy)3]^(2+ )into metal-organic framework to facilitate the separation and reuse of noble-metal photosensitizer during CO2 photoreduction

It is desirable to develop highly efficient and sustainable catalytic systems for CO_(2) photoreduction using efficient heterogeneous photosensitizers(PSs);however,this remains a great challenge.In this study,we doped[Ru(bpy)3]^(2+) into UiO-metal-organic frameworks(MOFs)to facilitate the separation and reuse of noble metal PS.By simply adjusting the loading amount,a series of heterogeneous photoactive MOFs,namely,UiO-Ru-1,UiO-Ru-2,and UiO-Ru-3,were constructed to act as heterogeneous PSs to drive the efficient CO_(2) photoreduction under visible-light irradiation.Remarkably,UiO-Ru-2 exhibited the best photosensitizing ability among the prepared MOFs in sensitizing the iron quarterpyridine catalyst(C-l),and the CO yield reached as high as 171 mmol/g with ca.100%selectivity,which is a record value among all the MOF-based photocatalysts.This photoactive MOF can be recycled and reused three times without any obvious activity loss,signifying its good photochemical stability.Experimental investigations confirmed that the strong visible absorption,long-lived excited state,appropriate redox potential,good photocatalytic stability,and excellent collaboration with C-l were attributable to the superior catalytic activity.This work highlights an avenue for constructing heterogeneous PSs with excellent recyclability using MOF as the platform for efficient CO_(2) reduction.

A Reduced Mechanism for Flame Inhibition by Phosphorus-containing Compounds Based on Level of Importance Analysis

A reduced mechanism for propane/air combustion and its flame inhibition by phosphorus-containing compounds (PCCs) is constructed with the level of importance (LOI) method. The analysis is performed on solutions of freely propagating premixed flames with detailed chemical kinetics involving 121 species and 682 reactions proposed by Jayaweera et al. For the non-homogeneous reaction-diffusion system, the chemical lifetime of each species is weighted by its diffusion timescale, and the characteristic flame timescale is used to normalize the chemical lifetime. The definition of sensitivity in LOI is extended so that multi-parameters can be used as sensitivity targets. Propane, oxygen, dimethyl methylphosphonate (DMMP), and flame speed are selected to be perturbed for sensitivity analysis, the species with low LOI index are removed, and reactions involving the redundant species are excluded from the mechanism. A skeletal mechanism is obtained, which consists of 57 species and 268 elementary reactions. Calculations for laminar flame speeds, key flame radicals and catalytic cycles using the skeletal mechanism are in good agreement with those by using the detailed mechanism over a wide range of equivalence ratio undoped and doped with DMMP.

Photogenerated carrier transfer mechanism and photocatalysis properties of TiO_2 sensitized by Zn(Ⅱ) phthalocyanine

The Zn(Ⅱ) phthalocyanine sensitized TiO2(ZnPc-TiO2) nanoparticles were prepared by hydrothermal method via impregnation with ZnPc.The as-prepared photocatalysts were characterized by X-ray diffractometry(XRD) and diffuse reflectance spectroscopy(DRS),and the surface photovoltage spectroscopy(SPS) and photocatalytic degradation of rhodamine B(RhB) were studied under illuminating.The experimental results indicate that TiO2 sensitized by ZnPc extends its absorption band into the visible region effectively,and the sensitized TiO2 has higher activity than TiO2(Degussa P-25) under the simulated solar light and the visible light.Based on the DRS and SPS results,the mechanism about the photogenerated carrier transfer between TiO2 and ZnPc is proposed.At a lower ZnPc content(≤0.20 μmol/g),ZnPc monomer acts as the electron donor,which provides the photoinduced electrons to the conduction band of TiO2.These photoinduced electrons can transfer to molecular oxygen(O2),leading to the formation of active species,such as superoxide/hydroxide radicals and singlet oxygen,which is beneficial to the photocatalytic reaction.While at a higher ZnPc content(>0.20 μmol/g),the formation of ZnPc dimer results in the decrease of photocatalytic activities of ZnPc-TiO2 photocatalyst.

Explicit diagnosis of the local ozone production rate and the ozone-NOx-VOC sensitivities

In the troposphere, ozone is a harmful gas compound to both human health and vegetation. Ozone is produced from the reaction of NO_x(@NO + NO_2) and VOCs(volatile organic compounds) with light. Due to the highly nonlinear relationships between ozone and its precursors, proper ozone mitigation relies on the knowledge of chemical mechanisms. In this study, an observation-based method is used to simulate ozone formation and elucidate its controlling factors for a rural site on the North China Plain. The instantaneous ozone production rate is calculated utilizing a box model using the dataset obtained from the Wangdu campaign. First, the model was operated in a time-dependent mode to calculate the ozone production rate at each time stamp. The calculated ozone formation rate showed a diurnal average maximum value of 17 ppbv/h(1-h diurnal averaged). The contribution of individual peroxy radicals to ozone production was analyzed. In addition, the functional dependence of calculated P(O_3) reveals that ozone production was in a NO_x-limited regime during the campaign. Furthermore, the missing peroxy radical source will further extend NO_x-limited conditions to earlier in the day, making NO_xlimitation dominate more of a day than the current chemical model predicts. Finally, a multiple scenarios mode,also known as EKMA(empirical kinetic modeling approach), was used to simulate the response of P(O_3) to the imaginary change in precursor concentrations. We found that ozone production was in the NO_x-limited region. However, the use of NO_2 measured by the molybdenum converter and/or the absence of a peroxy radical source in the current chemical model could over-emphasize the VOC-limited effect on ozone production.

Plasma density evolution in plasma opening switch obtained by a time-resolved sensitive He-Ne interferometer

To understand the formation process of vacuum gap in coaxial microsecond conduction time plasma opening switch(POS),we have made measurements of the line-integrated plasma density during switch operation using a time-resolved sensitive He-Ne interferometer.The conduction current and conduction time in experiments are about 120 kA and 1 s,respectively.As a result,more than 85%of conduction current has been transferred to an inductive load with rise time of 130 ns.The radial dependence of the density is measured by changing the radial location of the line-of-sight for shots with the same nominal POS parameters.During the conduction phase,the line-integrated plasma density in POS increases at all radial locations over the gun-only case by further ionization of material injected from the guns.The current conduction is observed to cause a radial redistribution of the switch plasma.A vacuum gap forms rapidly in the plasma at 5.5 mm from the center conductor,which is consistent with the location where magnetic pressure is the largest,allowing current to be transferred from the POS to the load.