A highly sensitive and selective two-photon sensing scheme for detection of cartap was developed by using Au@Ag bimetallic core-shell nanoparticles.Cartap was found to induce the aggregation of Au@Ag nanoparticles and...A highly sensitive and selective two-photon sensing scheme for detection of cartap was developed by using Au@Ag bimetallic core-shell nanoparticles.Cartap was found to induce the aggregation of Au@Ag nanoparticles and up to 700-fold enhancement in two-photon photoluminescence.Huge enhancement in two-photon photoluminescence allows achieving a detection limit of as low as 0.0062 mg/kg,which is better than the conventional colorimetric methods.This two-photon sensing scheme has a broad dynamic range and displays excellent selectivity in detection of cartap against over other ten kinds of commonly used insecticides.展开更多
基金the Ministry of Education, Singapore (R-143-000-607-112)the National Research Foundation, Prime Minister’s Office, Singapore under its Competitive Research Program (NRF-CRP10-2012-04)Medium Sized Centre Programme
文摘A highly sensitive and selective two-photon sensing scheme for detection of cartap was developed by using Au@Ag bimetallic core-shell nanoparticles.Cartap was found to induce the aggregation of Au@Ag nanoparticles and up to 700-fold enhancement in two-photon photoluminescence.Huge enhancement in two-photon photoluminescence allows achieving a detection limit of as low as 0.0062 mg/kg,which is better than the conventional colorimetric methods.This two-photon sensing scheme has a broad dynamic range and displays excellent selectivity in detection of cartap against over other ten kinds of commonly used insecticides.