This paper presents a comprehensive treatment of the parametric sensitivity and runaway in fixed bed reactors with one dimensional pseudo homogeneous dispersion model (ODDM). In this case, we find the existence of m...This paper presents a comprehensive treatment of the parametric sensitivity and runaway in fixed bed reactors with one dimensional pseudo homogeneous dispersion model (ODDM). In this case, we find the existence of multiplicity and determine the runaway criterion through the critical isodisper sion curve. The calculated results indicate when the axial dispersion is relatively small, the impact of the axial dispersion on the parametric sensitivity may be neglected; but when the axial dispersion is large, this impact must be considered.展开更多
This paper used the Chinese listing Corporation financial data （2003-2013） to study the relationship between the supply chain finance development, SME financing constraints and cash flow. The study found that the sm...This paper used the Chinese listing Corporation financial data （2003-2013） to study the relationship between the supply chain finance development, SME financing constraints and cash flow. The study found that the small and medium-sized enterprise has obvious cash flow sensitivity, explaining it is subjected to the larger financing constraints. The development of supply chain finance can alleviate the financing constraints of SMEs, but for large enterprises it is unable to play a corresponding role.展开更多
Four novel benzothiazolium ionic liquids with 6PF?([C1Bth][PF6], [C4Bth][PF6], [C5Bth][PF6] and [C6Bth][PF6]) were synthesized, and the rang of their melting points were determined between 358.35 K-424.05 K. The relat...Four novel benzothiazolium ionic liquids with 6PF?([C1Bth][PF6], [C4Bth][PF6], [C5Bth][PF6] and [C6Bth][PF6]) were synthesized, and the rang of their melting points were determined between 358.35 K-424.05 K. The relationship of their melting points and the length of the straight alkyl chain on cation reflected ‘S' type ten-dency. Then, the solubilities of the four ionic liquids in six lower alcohols(methanol, ethanol, 1-propanol, 2-propanol, 1-butanol and 2-methyl-1-propanol) were measured in the temperature rang of 253.15-383.15 K at at-mospheric pressure with static analytical method, respectively. It was found that [C6Bth][PF6] in all investigated ionic liquids had the largest solubility in six alcohols and the solubility of [C4Bth][PF6] in methanol was very sensi-tive for temperature in 313.15-333.15 K, which was so-called "temperature-sensitivity". This feature is of great significance to their application of catalyzing reaction or extraction process, and makes the recovery and reuse of ionic liquids(ILs) become easier. Moreover, the experimental solubility data were correlated with the modified Apelblat equation and λh equation, respectively. It was found that the result of correlation using two divided tem-perature ranges was better than that of using the whole temperature range.展开更多
The aim of this work is double. Firstly, we want to stress out that investing in renewable energies in 2009 in Spain was a profitable activity. This question will be answered studying the possibilities of expanding ＂...The aim of this work is double. Firstly, we want to stress out that investing in renewable energies in 2009 in Spain was a profitable activity. This question will be answered studying the possibilities of expanding ＂Sierra de Tineo＂ wind farm in the Principality of Asturias （location, wind resource, data analysis, simulation, legal standards and economic and sensitivity study of the investment）, and for that, data from the year 2009 have been used. And secondly, the goal is to set the bases for a future paper where the current situation of Spain （within the renewable framework）, will be compared with the 2009 scenario.展开更多
机器学习模型广泛应用于区域性滑坡易发性分析。模型的选择关系到评价结果的可信度、准确率和稳定性。现有滑坡易发性分析模型对比研究侧重模型的预测精度。模型的稳定性和数据量敏感性对机器学习模型的性能评估同样非常重要。本文以福...机器学习模型广泛应用于区域性滑坡易发性分析。模型的选择关系到评价结果的可信度、准确率和稳定性。现有滑坡易发性分析模型对比研究侧重模型的预测精度。模型的稳定性和数据量敏感性对机器学习模型的性能评估同样非常重要。本文以福建省南平市蔡源流域为研究区,以四川省绵阳市北川县为验证区,从预测精度、稳定性和数据量敏感性3个方面深入对比BP(Back Propagation)人工神经网络模型和CART(Classification and Regression Tree)决策树模型在滑坡易发性分析中的效果,主要结论如下:①在逐渐增加一定数量训练样本的过程中,BP人工神经网络模型预测精度的增长率更高。在蔡源流域内,当训练样本数量增加10000时,BP人工神经网络模型的预测精度上升5.22%,CART决策树模型的预测精度上升2.11%。②BP人工神经网络的预测精度高于CART决策树模型,且较为稳定。在100组数据集上,BP人工神经网络模型验证集预测精度的均值和验证集滑坡样本预测精度的均值分别为81.60%和84.86%,高于CART决策树模型的72.97%和76.59%。与此同时,BP人工神经网络模型对应预测精度的标准差分别是0.32%和0.37%,小于CART决策树模型的0.35%和0.67%。③BP人工神经网络模型分析的滑坡易发区相比CART决策树模型,更接近实际滑坡的空间分布。最后,北川县的验证实验也出现了相同的现象。展开更多
Species sensitivity analysis is one of the major techniques applied to derive water quality criteria. Presently, the toxicity data used for development of water quality criteria are mainly in the biological individual...Species sensitivity analysis is one of the major techniques applied to derive water quality criteria. Presently, the toxicity data used for development of water quality criteria are mainly in the biological individual level. With the increase of ecotoxicogenomics toxicity data, it is worth studying whether the gene expression effect data can be used to derive water quality criteria. Taking cadmium, copper and zinc as examples, we analyzed the toxic effects of the three heavy metals by constructing the species sensitivity distribution curves on the basis of extensive toxicity data. The results showed that the rank of species sensitivity for the acute, chronic and gene expression effect toxicity data of cadmium is "chronic>gene>acute". Although the gene expression effect data of copper and zinc are insufficient, the trend of data sensitivity of zinc is similar to cadmium. However, the trend of species sensitivity of copper is different from that of cadmium and zinc with higher sensitivity of gene expression data. It suggested that though the existing data of gene expression effects are not sufficient enough, they have the potential to be used in the development of chronic water quality criteria. For application in the derivation of water quality criteria, illogical test concentration design and insufficient target genes are two main weaknesses in the study of gene expression effects.展开更多
In order to discover the effect of head cavity on resonance damping characteristics in solid rocket motors, large-eddy simulations with wall-adapting-local-eddy-viscosity subgrid scale turbulent model are implemented ...In order to discover the effect of head cavity on resonance damping characteristics in solid rocket motors, large-eddy simulations with wall-adapting-local-eddy-viscosity subgrid scale turbulent model are implemented to study the oscillation flow field induced by vortex shedding based on the VKI （yon Karman Institute） experimental motor. Firstly, mesh sensitivity analysis and grid-independent analysis are carried out for the computer code validation. Then, the numerical method is further validated by comparing the calculated results and experimental data. Thirdly, the effects of head-end cavity on the pressure oscillation am-plitudes are studied in this paper. The results indicate that cavity volume, location and configuration have a cooperative ef- fect on the oscillation amplitude. It is proved that Rayleigh criterion can be used as a guiding principle for the design of reso- nance damping cavity. The change of the head-end cavity breaks the balance between the mass flux and acoustic energy. Therefore, the pressure oscillation characteristics change accordingly. It is concluded that a large mass flux added at the pres- sure antinode could attribute to significant amplitude. Meanwhile, the damping effect of the cavity is stronger when the dis- tance between cavity and pressure antinode becomes shorter. Finally, this method is applied to the modification of an engi- neering solid rocket motor. The static test of solid rocket motor reflects that the oscillations can be effectively suppressed by a head-end cavity.展开更多
文摘This paper presents a comprehensive treatment of the parametric sensitivity and runaway in fixed bed reactors with one dimensional pseudo homogeneous dispersion model (ODDM). In this case, we find the existence of multiplicity and determine the runaway criterion through the critical isodisper sion curve. The calculated results indicate when the axial dispersion is relatively small, the impact of the axial dispersion on the parametric sensitivity may be neglected; but when the axial dispersion is large, this impact must be considered.
文摘This paper used the Chinese listing Corporation financial data （2003-2013） to study the relationship between the supply chain finance development, SME financing constraints and cash flow. The study found that the small and medium-sized enterprise has obvious cash flow sensitivity, explaining it is subjected to the larger financing constraints. The development of supply chain finance can alleviate the financing constraints of SMEs, but for large enterprises it is unable to play a corresponding role.
基金Supported by the National Natural Science Foundation of China(81102344)the Scientific Research Fund of Sichuan Prov-ince Education Department(12ZA080)+1 种基金Mianyang Normal University for Excellent Plan Fund(QD2012A06)the Project of Mianyang Science and Technology Bureau(10Y003-8)
文摘Four novel benzothiazolium ionic liquids with 6PF?([C1Bth][PF6], [C4Bth][PF6], [C5Bth][PF6] and [C6Bth][PF6]) were synthesized, and the rang of their melting points were determined between 358.35 K-424.05 K. The relationship of their melting points and the length of the straight alkyl chain on cation reflected ‘S' type ten-dency. Then, the solubilities of the four ionic liquids in six lower alcohols(methanol, ethanol, 1-propanol, 2-propanol, 1-butanol and 2-methyl-1-propanol) were measured in the temperature rang of 253.15-383.15 K at at-mospheric pressure with static analytical method, respectively. It was found that [C6Bth][PF6] in all investigated ionic liquids had the largest solubility in six alcohols and the solubility of [C4Bth][PF6] in methanol was very sensi-tive for temperature in 313.15-333.15 K, which was so-called "temperature-sensitivity". This feature is of great significance to their application of catalyzing reaction or extraction process, and makes the recovery and reuse of ionic liquids(ILs) become easier. Moreover, the experimental solubility data were correlated with the modified Apelblat equation and λh equation, respectively. It was found that the result of correlation using two divided tem-perature ranges was better than that of using the whole temperature range.
文摘The aim of this work is double. Firstly, we want to stress out that investing in renewable energies in 2009 in Spain was a profitable activity. This question will be answered studying the possibilities of expanding ＂Sierra de Tineo＂ wind farm in the Principality of Asturias （location, wind resource, data analysis, simulation, legal standards and economic and sensitivity study of the investment）, and for that, data from the year 2009 have been used. And secondly, the goal is to set the bases for a future paper where the current situation of Spain （within the renewable framework）, will be compared with the 2009 scenario.
文摘机器学习模型广泛应用于区域性滑坡易发性分析。模型的选择关系到评价结果的可信度、准确率和稳定性。现有滑坡易发性分析模型对比研究侧重模型的预测精度。模型的稳定性和数据量敏感性对机器学习模型的性能评估同样非常重要。本文以福建省南平市蔡源流域为研究区,以四川省绵阳市北川县为验证区,从预测精度、稳定性和数据量敏感性3个方面深入对比BP(Back Propagation)人工神经网络模型和CART(Classification and Regression Tree)决策树模型在滑坡易发性分析中的效果,主要结论如下:①在逐渐增加一定数量训练样本的过程中,BP人工神经网络模型预测精度的增长率更高。在蔡源流域内,当训练样本数量增加10000时,BP人工神经网络模型的预测精度上升5.22%,CART决策树模型的预测精度上升2.11%。②BP人工神经网络的预测精度高于CART决策树模型,且较为稳定。在100组数据集上,BP人工神经网络模型验证集预测精度的均值和验证集滑坡样本预测精度的均值分别为81.60%和84.86%,高于CART决策树模型的72.97%和76.59%。与此同时,BP人工神经网络模型对应预测精度的标准差分别是0.32%和0.37%,小于CART决策树模型的0.35%和0.67%。③BP人工神经网络模型分析的滑坡易发区相比CART决策树模型,更接近实际滑坡的空间分布。最后,北川县的验证实验也出现了相同的现象。
基金supported by the Great Program of National Water Body Pollution Control and Treatment (Grant No. 2012ZX07501-003-006)Special Project of Revolution Startup of CRAES (Grant No. 2011GQ-02)
文摘Species sensitivity analysis is one of the major techniques applied to derive water quality criteria. Presently, the toxicity data used for development of water quality criteria are mainly in the biological individual level. With the increase of ecotoxicogenomics toxicity data, it is worth studying whether the gene expression effect data can be used to derive water quality criteria. Taking cadmium, copper and zinc as examples, we analyzed the toxic effects of the three heavy metals by constructing the species sensitivity distribution curves on the basis of extensive toxicity data. The results showed that the rank of species sensitivity for the acute, chronic and gene expression effect toxicity data of cadmium is "chronic>gene>acute". Although the gene expression effect data of copper and zinc are insufficient, the trend of data sensitivity of zinc is similar to cadmium. However, the trend of species sensitivity of copper is different from that of cadmium and zinc with higher sensitivity of gene expression data. It suggested that though the existing data of gene expression effects are not sufficient enough, they have the potential to be used in the development of chronic water quality criteria. For application in the derivation of water quality criteria, illogical test concentration design and insufficient target genes are two main weaknesses in the study of gene expression effects.
基金supported by the National Natural Science Foundation of China(Grant No.51076015)
文摘In order to discover the effect of head cavity on resonance damping characteristics in solid rocket motors, large-eddy simulations with wall-adapting-local-eddy-viscosity subgrid scale turbulent model are implemented to study the oscillation flow field induced by vortex shedding based on the VKI （yon Karman Institute） experimental motor. Firstly, mesh sensitivity analysis and grid-independent analysis are carried out for the computer code validation. Then, the numerical method is further validated by comparing the calculated results and experimental data. Thirdly, the effects of head-end cavity on the pressure oscillation am-plitudes are studied in this paper. The results indicate that cavity volume, location and configuration have a cooperative ef- fect on the oscillation amplitude. It is proved that Rayleigh criterion can be used as a guiding principle for the design of reso- nance damping cavity. The change of the head-end cavity breaks the balance between the mass flux and acoustic energy. Therefore, the pressure oscillation characteristics change accordingly. It is concluded that a large mass flux added at the pres- sure antinode could attribute to significant amplitude. Meanwhile, the damping effect of the cavity is stronger when the dis- tance between cavity and pressure antinode becomes shorter. Finally, this method is applied to the modification of an engi- neering solid rocket motor. The static test of solid rocket motor reflects that the oscillations can be effectively suppressed by a head-end cavity.
