The electrochemical and the mass transport behavior of ABTS2-/ABTS'- (2,2'-azinobis(3- ethylbenzothiazoline-6-sulfonate)) redox couple at glassy carbon electrode (GCE) in phos- phate buffer solution (PBS, pH=...The electrochemical and the mass transport behavior of ABTS2-/ABTS'- (2,2'-azinobis(3- ethylbenzothiazoline-6-sulfonate)) redox couple at glassy carbon electrode (GCE) in phos- phate buffer solution (PBS, pH=4.4) is studied in detail by cyclic voltammetry combined with rotating disk electrode system. From the i-E curves recorded at different electrode rotating rate, rate constant, and transfer coefficient for ABTS 2-←→ABTS^-+e reaction at GCE electrode and the diffusion coefficient of ABTS2- in PBS are estimated to be 4.6× 10^-3 cm/s, 0.28, and 4.4× 10^-6 cm^2/s, respectively. The transfer coefficient with a value of ca. 0.28 differs largely from the value of 0.5 that is always assumed in the literature. The origins for the difference of the rate constant determined and the challenges for estimating the stan- dard rate constant are discussed. The performance for such ABTS2- mediated bio-cathode toward oxygen reduction reaction is discussed according to the over-potential drop as well as current output limit associated with the charge transfer kinetics of ABTS2- ←→ABTS-+e redox reaction and/or the mass transport effect.展开更多
A new type of vehicle routing problem (VRP), multiple vehicle routing problem integrated reverse logistics (MVRPRL), is studied. In this problem, there is delivery or pickup (or both) and uncertain features in t...A new type of vehicle routing problem (VRP), multiple vehicle routing problem integrated reverse logistics (MVRPRL), is studied. In this problem, there is delivery or pickup (or both) and uncertain features in the demands of the clients. The deliveries of every client as uncertain parameters are expressed as triangular fuzzy numbers. In order to describe MVRPRL, a multi-objective fuzzy programming model with credibility measure theory is constructed. Then the simulationbased tabu search algorithm combining inter-route and intra-route neighborhoods and embedded restarts are designed to solve it. Computational results show that the tabu search algorithm developed is superior to sweep algorithms and that compared with handling each on separate routes, the transportation costs can be reduced by 43% through combining pickups with deliveries.展开更多
In order to minimize the hot-carrier effect(HCE)and maintain on-state performance in the high voltage N-type lateral double diffused MOS(N-LDMOS), an optimized device structure with step gate oxide is proposed. Co...In order to minimize the hot-carrier effect(HCE)and maintain on-state performance in the high voltage N-type lateral double diffused MOS(N-LDMOS), an optimized device structure with step gate oxide is proposed. Compared with the conventional configuration, the electric field under the gate along the Si-SiO2 interface in the presented N-LDMOS can be greatly reduced, which favors reducing the hot-carrier degradation. The step gate oxide can be achieved by double gate oxide growth, which is commonly used in some smart power ICs. The differences in hot-carrier degradations between the novel structure and the conventional structure are investigated and analyzed by 2D technology computer-aided design(TCAD)numerical simulations, and the optimal length of the thick gate oxide part in the novel N-LDMOS device can also be acquired on the basis of maintaining the characteristic parameters of the conventional device. Finally, the practical degradation measurements of some characteristic parameters can also be carried out. It is found that the hot-carrier degradation of the novel N-LDMOS device can be improved greatly.展开更多
New approaches for facility distribution in chemical plants are proposed including an improved non-overlapping constraint based on projection relationships of facilities and a novel toxic gas dispersion constraint. In...New approaches for facility distribution in chemical plants are proposed including an improved non-overlapping constraint based on projection relationships of facilities and a novel toxic gas dispersion constraint. In consideration of the large number of variables in the plant layout model, our new method can significantly reduce the number of variables with their own projection relationships. Also, as toxic gas dispersion is a usual incident in a chemical plant, a simple approach to describe the gas leakage is proposed, which can clearly represent the constraints of potential emission source and sitting facilities. For solving the plant layout model, an improved genetic algorithm (GA) based on infeasible solution fix technique is proposed, which improves the globe search ability of GA. The case study and experiment show that a better layout plan can be obtained with our method, and the safety factors such as gas dispersion and minimum distances can be well handled in the solution.展开更多
This exploration examines unsteady magnetohydrodynamic(MHD) three-dimensional flow of viscous material between rotating plates subject to radiation,Joule heating and chemical reaction.The non-linear partial differenti...This exploration examines unsteady magnetohydrodynamic(MHD) three-dimensional flow of viscous material between rotating plates subject to radiation,Joule heating and chemical reaction.The non-linear partial differential system is re-structured into the ordinary differential expressions by the implication of appropriate transformations.The developed differential equations are computed by homotopy analysis technique.Numerical consequences have been accomplished by various values of emerging parameters.Coefficients of skin friction and heat and mass transfer rates have been scrutinized.Irreversibility analysis is carried out.Influence of various prominent variables on entropy generation is presented.Moreover,the temperature increases for higher Dufour number and concentration distribution reduces against Soret number.Higher squeezing parameter enhances velocity while concentration reduces with an increment in squeezing parameter.Both entropy rate and Bejan number increase against higher diffusion parameter.展开更多
From the US New Energy Plan, personnel appointment, and diplomatic activities, etc., we can see that US is now on the way to returning to the negotiation table and undertaking the leadership in addressing climate chan...From the US New Energy Plan, personnel appointment, and diplomatic activities, etc., we can see that US is now on the way to returning to the negotiation table and undertaking the leadership in addressing climate change. What US has done puts tremendous challenges on China, which emits large amount of greenhouse gas into the atmosphere. However, different from US, China is undergoing rapid development, and huge energy consumption is unavoidable. China has to make a balance between developing economy and addressing climate change. This paper focuses on the US climate change policies and its greenhouse gas emissions, and its influences on China climate change policy. China greenhouse gas emissions and relative policies are also analyzed to see what situation China is in, and what challenges that China is facing. Consequently, combing China's local situation, we propose several solutions for China to address climate change, i.e. moving towards a low carbon economy, struggling for emitting more, enhancing China-US cooperation, and implementing different climate change policies based on local situation. Meanwhile, the achievements that China has made are also introduced.展开更多
Hotspot topic trends can be captured by analyzing user attributes and historical behavior in social network. In this paper, we propose a user participation behavior prediction model for social hotspots, based on user ...Hotspot topic trends can be captured by analyzing user attributes and historical behavior in social network. In this paper, we propose a user participation behavior prediction model for social hotspots, based on user behavior and relationship data, to predict user participation behavior and topic development trends. Firstly, for the complex factors of user behavior, three dynamic influence factor functions are defined, including individual, peer and community influence. These functions take timeliness into account using a time discretization method. Secondly, to determine laws of individual behavior and group behavior within a social topic, a hotspot user participation behavior prediction model is proposed and associated with the basic concepts of randora field and Markov property in information diffusion. The experimental results show that the model can not only dynamically predict the individual behavior, but also grasp the development trends of topics.展开更多
Objective: To investigate the expressions and their relationship of pituitary tumor transforming gene (PTTG) and proliferating cell nuclear antigen (PCNA) in glioma. Methods: The protein expressions of PTTG and ...Objective: To investigate the expressions and their relationship of pituitary tumor transforming gene (PTTG) and proliferating cell nuclear antigen (PCNA) in glioma. Methods: The protein expressions of PTTG and PCNA were detected by immunostaining assay using streptavidin-peroxidase (SP) method in 80 cases of glioma. Results: The positive rates of PTTG in grades Ⅰ-Ⅳ gliomas were 56.3%, 68.2%, 80.8%, and 100.0% respectively, and the protein expression of PTTG increased with the increasing of the pathological grade (X^2= 9.602, P 〈 0.05); The positive rates of PCNA protein were 37.5%, 54.5%, 69.2%, and 93.8% respectively, and the protein expression of PCNA increased with the increasing of the pathological grade (X2 = 12.147, P 〈 0.01). The expression of PTTG had positive correlation with the expression of PCNA protein (~s = 0.557, P 〈 0.01). Conclusion: The expressions of PTTG and PCNA proteins were related to malignant degree of glioma, and may cooperate with each other in the tumorigenesis and progression and can be considered as the indicators of the biological behaviors in glioma.展开更多
A flux equation of diffusion for bi-disperse porous catalyst pellets was proposed by modifying the previously developed model equation over fractal trajectories. The proposed fractal model equation considered the same...A flux equation of diffusion for bi-disperse porous catalyst pellets was proposed by modifying the previously developed model equation over fractal trajectories. The proposed fractal model equation considered the same tortuous degree for both micro-and macro-pores. The experimental data of diffusion over a bi-disperse Ni/gamma-alumina pellet were obtained with a standard Wicke-Kallenbach diffusion cell for both carbon monoxide- ethylene and carbon dioxide-ethylene binary mixtures. The fitting between experimental results and the fractal model equation leads to a fractal dimension of 1.11. The prediction of diffusion flux over the bi-disperse Ni/gamma- alumina pellet by the proposed fractal model equation is much better than the traditional tortuosity-based model equation by comparison with the measured flux through the pellet.展开更多
Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the ga...Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the gas-liquid exothermic reaction and axial dispersions of both gas and liquid phase is employed to study the performance of EBCR for the process of p-xylene(PX) oxidation. The computational results show that there are remarkable concentration and temperature gradients in EBCR for high ratio of height to diameter (H/DT). The temperature is lower at the bottom of column and higher at the top, due to rapid evaporation induced by the feed gas near the bottom. The concentration profiles in the gas phase are more nonuniform than those (except PX) in the liquid phase, which causes more solvent burning consumption at high H/DT ratio. For p-xylene oxidation, theo ptimal H/DT is around 5.展开更多
Saffron is the most precious and expensive agricultural product. A dehydration treatment is necessary to convert Crocus sativus L. stigmas into saffron spice. To the best of our knowledge, no information on mass trans...Saffron is the most precious and expensive agricultural product. A dehydration treatment is necessary to convert Crocus sativus L. stigmas into saffron spice. To the best of our knowledge, no information on mass transfer parameters of saffron stigmas is available in the literature. This study aimed at investigating the moisture transfer parameters and quality attributes of saffron stigmas under infrared treatment at different temperatures(60,70, …, 110 ℃). It was observed that the dehydration process of the samples occurred in a short accelerating rate period at the start followed by a falling rate period. The effective moisture diffusivity and convective mass transfer coefficient were determined by using the Dincer and Dost model. The diffusivity values varied from1.1103 × 10^-10m^2·s^-1to 4.1397 × 10^-10m^2·s^-1 and mass transfer coefficient varied in the range of 2.6433 × 10^-7–8.7203 × 10^-7m·s^-1. The activation energy was obtained to be 27.86 kJ·mol^-1. The quality assessment results showed that the total crocin content increased, when the temperature increased up to90 ℃ but, in higher temperatures, the amount of crocin decreased slightly. The total safranal content of the samples decreased slightly when drying temperature increased from 60 ℃ to 70 ℃ and then continuously increased up to 110 ℃. Also, the amount of picrocrocin increased from 83.1 to 93.3 as the drying temperature increased from 60 ℃ to 100 ℃.展开更多
基金This work was supported by one hundred Talents' Program of the Chinese Academy of Science, the National Natural Science Foundation of China (No.21073176), 973 Program from the Ministry of Science and Technology of China (No.2010CB923302).
文摘The electrochemical and the mass transport behavior of ABTS2-/ABTS'- (2,2'-azinobis(3- ethylbenzothiazoline-6-sulfonate)) redox couple at glassy carbon electrode (GCE) in phos- phate buffer solution (PBS, pH=4.4) is studied in detail by cyclic voltammetry combined with rotating disk electrode system. From the i-E curves recorded at different electrode rotating rate, rate constant, and transfer coefficient for ABTS 2-←→ABTS^-+e reaction at GCE electrode and the diffusion coefficient of ABTS2- in PBS are estimated to be 4.6× 10^-3 cm/s, 0.28, and 4.4× 10^-6 cm^2/s, respectively. The transfer coefficient with a value of ca. 0.28 differs largely from the value of 0.5 that is always assumed in the literature. The origins for the difference of the rate constant determined and the challenges for estimating the stan- dard rate constant are discussed. The performance for such ABTS2- mediated bio-cathode toward oxygen reduction reaction is discussed according to the over-potential drop as well as current output limit associated with the charge transfer kinetics of ABTS2- ←→ABTS-+e redox reaction and/or the mass transport effect.
基金The National Natural Science Foundation of China(No.70772059)Youth Science and Technology Innovation Foundation of Nanjing Agriculture University(No.KJ06029)
文摘A new type of vehicle routing problem (VRP), multiple vehicle routing problem integrated reverse logistics (MVRPRL), is studied. In this problem, there is delivery or pickup (or both) and uncertain features in the demands of the clients. The deliveries of every client as uncertain parameters are expressed as triangular fuzzy numbers. In order to describe MVRPRL, a multi-objective fuzzy programming model with credibility measure theory is constructed. Then the simulationbased tabu search algorithm combining inter-route and intra-route neighborhoods and embedded restarts are designed to solve it. Computational results show that the tabu search algorithm developed is superior to sweep algorithms and that compared with handling each on separate routes, the transportation costs can be reduced by 43% through combining pickups with deliveries.
基金The Natural Science Foundation of Jiangsu Province(No.BK2008287)the Preresearch Project of the National Natural Science Foundation of Southeast University(No.XJ2008312)
文摘In order to minimize the hot-carrier effect(HCE)and maintain on-state performance in the high voltage N-type lateral double diffused MOS(N-LDMOS), an optimized device structure with step gate oxide is proposed. Compared with the conventional configuration, the electric field under the gate along the Si-SiO2 interface in the presented N-LDMOS can be greatly reduced, which favors reducing the hot-carrier degradation. The step gate oxide can be achieved by double gate oxide growth, which is commonly used in some smart power ICs. The differences in hot-carrier degradations between the novel structure and the conventional structure are investigated and analyzed by 2D technology computer-aided design(TCAD)numerical simulations, and the optimal length of the thick gate oxide part in the novel N-LDMOS device can also be acquired on the basis of maintaining the characteristic parameters of the conventional device. Finally, the practical degradation measurements of some characteristic parameters can also be carried out. It is found that the hot-carrier degradation of the novel N-LDMOS device can be improved greatly.
基金Supported by the National Natural Science Foundation of China (61074153, 61104131), and the Fundamental Research Funds for Central Universities of China (ZY1111, JD1104).
文摘New approaches for facility distribution in chemical plants are proposed including an improved non-overlapping constraint based on projection relationships of facilities and a novel toxic gas dispersion constraint. In consideration of the large number of variables in the plant layout model, our new method can significantly reduce the number of variables with their own projection relationships. Also, as toxic gas dispersion is a usual incident in a chemical plant, a simple approach to describe the gas leakage is proposed, which can clearly represent the constraints of potential emission source and sitting facilities. For solving the plant layout model, an improved genetic algorithm (GA) based on infeasible solution fix technique is proposed, which improves the globe search ability of GA. The case study and experiment show that a better layout plan can be obtained with our method, and the safety factors such as gas dispersion and minimum distances can be well handled in the solution.
文摘This exploration examines unsteady magnetohydrodynamic(MHD) three-dimensional flow of viscous material between rotating plates subject to radiation,Joule heating and chemical reaction.The non-linear partial differential system is re-structured into the ordinary differential expressions by the implication of appropriate transformations.The developed differential equations are computed by homotopy analysis technique.Numerical consequences have been accomplished by various values of emerging parameters.Coefficients of skin friction and heat and mass transfer rates have been scrutinized.Irreversibility analysis is carried out.Influence of various prominent variables on entropy generation is presented.Moreover,the temperature increases for higher Dufour number and concentration distribution reduces against Soret number.Higher squeezing parameter enhances velocity while concentration reduces with an increment in squeezing parameter.Both entropy rate and Bejan number increase against higher diffusion parameter.
基金supported by National Key Project of Scientific and Technical Supporting Programs Funded by Ministry of Science and Technology of China in the 11th Five-Year Plan (Grant No. 2007BAC03A03)
文摘From the US New Energy Plan, personnel appointment, and diplomatic activities, etc., we can see that US is now on the way to returning to the negotiation table and undertaking the leadership in addressing climate change. What US has done puts tremendous challenges on China, which emits large amount of greenhouse gas into the atmosphere. However, different from US, China is undergoing rapid development, and huge energy consumption is unavoidable. China has to make a balance between developing economy and addressing climate change. This paper focuses on the US climate change policies and its greenhouse gas emissions, and its influences on China climate change policy. China greenhouse gas emissions and relative policies are also analyzed to see what situation China is in, and what challenges that China is facing. Consequently, combing China's local situation, we propose several solutions for China to address climate change, i.e. moving towards a low carbon economy, struggling for emitting more, enhancing China-US cooperation, and implementing different climate change policies based on local situation. Meanwhile, the achievements that China has made are also introduced.
基金supported by the National Key Basic Research Program(973 program)of China(No.2013CB329606)National Science Foundation of China(Grant No.61272400)+2 种基金Science and Technology Research Program of the Chongqing Municipal Education Committee(No.KJ1500425)Wen Feng Foundation of CQUPT(No.WF201403)Chongqing Graduate Research And Innovation Project(No.CYS14146)
文摘Hotspot topic trends can be captured by analyzing user attributes and historical behavior in social network. In this paper, we propose a user participation behavior prediction model for social hotspots, based on user behavior and relationship data, to predict user participation behavior and topic development trends. Firstly, for the complex factors of user behavior, three dynamic influence factor functions are defined, including individual, peer and community influence. These functions take timeliness into account using a time discretization method. Secondly, to determine laws of individual behavior and group behavior within a social topic, a hotspot user participation behavior prediction model is proposed and associated with the basic concepts of randora field and Markov property in information diffusion. The experimental results show that the model can not only dynamically predict the individual behavior, but also grasp the development trends of topics.
基金Supported by a grant from the Natural Science Foundation of College and University of Jiangsu Province (No. 05KJD320238).
文摘Objective: To investigate the expressions and their relationship of pituitary tumor transforming gene (PTTG) and proliferating cell nuclear antigen (PCNA) in glioma. Methods: The protein expressions of PTTG and PCNA were detected by immunostaining assay using streptavidin-peroxidase (SP) method in 80 cases of glioma. Results: The positive rates of PTTG in grades Ⅰ-Ⅳ gliomas were 56.3%, 68.2%, 80.8%, and 100.0% respectively, and the protein expression of PTTG increased with the increasing of the pathological grade (X^2= 9.602, P 〈 0.05); The positive rates of PCNA protein were 37.5%, 54.5%, 69.2%, and 93.8% respectively, and the protein expression of PCNA increased with the increasing of the pathological grade (X2 = 12.147, P 〈 0.01). The expression of PTTG had positive correlation with the expression of PCNA protein (~s = 0.557, P 〈 0.01). Conclusion: The expressions of PTTG and PCNA proteins were related to malignant degree of glioma, and may cooperate with each other in the tumorigenesis and progression and can be considered as the indicators of the biological behaviors in glioma.
基金Supported by the National Natural Science Foundation of China (No. 50228203 and No. 20476076)
文摘A flux equation of diffusion for bi-disperse porous catalyst pellets was proposed by modifying the previously developed model equation over fractal trajectories. The proposed fractal model equation considered the same tortuous degree for both micro-and macro-pores. The experimental data of diffusion over a bi-disperse Ni/gamma-alumina pellet were obtained with a standard Wicke-Kallenbach diffusion cell for both carbon monoxide- ethylene and carbon dioxide-ethylene binary mixtures. The fitting between experimental results and the fractal model equation leads to a fractal dimension of 1.11. The prediction of diffusion flux over the bi-disperse Ni/gamma- alumina pellet by the proposed fractal model equation is much better than the traditional tortuosity-based model equation by comparison with the measured flux through the pellet.
基金Supported by the National Natural Science Foundation of China (No. 20076039) and SINOPEC.
文摘Evaporating bubble column reactor (EBCR) is a kind of aerated reactor in which the reaction heat is removed by the evaporation of volatile reaction mixture. In this paper, a mathematical model that accounts for the gas-liquid exothermic reaction and axial dispersions of both gas and liquid phase is employed to study the performance of EBCR for the process of p-xylene(PX) oxidation. The computational results show that there are remarkable concentration and temperature gradients in EBCR for high ratio of height to diameter (H/DT). The temperature is lower at the bottom of column and higher at the top, due to rapid evaporation induced by the feed gas near the bottom. The concentration profiles in the gas phase are more nonuniform than those (except PX) in the liquid phase, which causes more solvent burning consumption at high H/DT ratio. For p-xylene oxidation, theo ptimal H/DT is around 5.
文摘Saffron is the most precious and expensive agricultural product. A dehydration treatment is necessary to convert Crocus sativus L. stigmas into saffron spice. To the best of our knowledge, no information on mass transfer parameters of saffron stigmas is available in the literature. This study aimed at investigating the moisture transfer parameters and quality attributes of saffron stigmas under infrared treatment at different temperatures(60,70, …, 110 ℃). It was observed that the dehydration process of the samples occurred in a short accelerating rate period at the start followed by a falling rate period. The effective moisture diffusivity and convective mass transfer coefficient were determined by using the Dincer and Dost model. The diffusivity values varied from1.1103 × 10^-10m^2·s^-1to 4.1397 × 10^-10m^2·s^-1 and mass transfer coefficient varied in the range of 2.6433 × 10^-7–8.7203 × 10^-7m·s^-1. The activation energy was obtained to be 27.86 kJ·mol^-1. The quality assessment results showed that the total crocin content increased, when the temperature increased up to90 ℃ but, in higher temperatures, the amount of crocin decreased slightly. The total safranal content of the samples decreased slightly when drying temperature increased from 60 ℃ to 70 ℃ and then continuously increased up to 110 ℃. Also, the amount of picrocrocin increased from 83.1 to 93.3 as the drying temperature increased from 60 ℃ to 100 ℃.