从《史记》《汉书》叙事散偶之别看骈化之轨迹

散文、骈文句式结构区别明显:散文形式自由,长短句相糅,尽显浩然之气;骈文重辞藻,体式求工整,尽显曼妙之雅。因此要分析《史记》、《汉书》所呈现出来的散骈特点,句式散偶的对比是一个不容忽视的内容,通过对两者句式散偶的研究,以求窥探从《史记》到《汉书》的骈化迹象。

High-throughput studies and machine learning for design of β titanium alloys with optimum properties

Based on experimental data,machine learning(ML) models for Young's modulus,hardness,and hot-working ability of Ti-based alloys were constructed.In the models,the interdiffusion and mechanical property data were high-throughput re-evaluated from composition variations and nanoindentation data of diffusion couples.Then,the Ti-(22±0.5)at.%Nb-(30±0.5)at.%Zr-(4±0.5)at.%Cr(TNZC) alloy with a single body-centered cubic(BCC) phase was screened in an interactive loop.The experimental results exhibited a relatively low Young's modulus of(58±4) GPa,high nanohardness of(3.4±0.2) GPa,high microhardness of HV(520±5),high compressive yield strength of(1220±18) MPa,large plastic strain greater than 30%,and superior dry-and wet-wear resistance.This work demonstrates that ML combined with high-throughput analytic approaches can offer a powerful tool to accelerate the design of multicomponent Ti alloys with desired properties.Moreover,it is indicated that TNZC alloy is an attractive candidate for biomedical applications.

Numerical simulation of intermediate phase growth in Ti/Al alternate foils

To investigate the diffusion reaction between Ti/Al solid diffusion couple, Ti/Al alternate foils formed by hot pressing were annealed at 525, 550, 575 and 600 °C for time ranging from 1 to 40 h. The experimental results show that TiAl3 was the only observed phase at Ti/Al interface. The interface thermodynamics favored the preferential formation of TiAl3 in Ti/Al couple. The growth of TiAl3 layer occurred mainly towards Al foil side and exhibited a parabolic law. Using the interdiffusion coefficients calculated based on the contribution of grain boundary diffusion, the growth of TiAl3 was simulated numerically with the finite difference method, and the simulated results were in good agreement with the experimental ones.

Atomic interdiffusion in Ni-Cu system under high magnetic field

The effect of high magnetic field on the atomic interdiffusion in Ni-Cu system was studied using the Cu/Ni/Cu diffusion couples. During the atomic interdiffusion in Ni-Cu system, it was found that the interdiffusion coefficients increased with the increase of molar fraction of Ni atoms in the interdiffusion zones when the couples were annealed with or without the magnetic field. It was noted that all corresponding interdiffusion coefficients under the magnetic field are smaller than those without the magnetic field. The results demonstrate that the magnetic field retards the atomic interdiffusion in Ni-Cu system. This retardation is achieved through reducing the frequency factors but not changing the interdiffusion activation energies.

Directional growth behavior of a(Al) dendrites during concentration-gradientcontrolled solidification process in static magnetic field

The large and small sized Cu（solid）/Al（liquid） couples were prepared to investigate the directional growth behavior of primary a（Al） phase during a concentration-gradient-controlled solidification process under various static magnetic fields（SMFs）.The results show that in the large couples,the α（Al） dendrites reveal a directional growth character whether without or with the SMF.However,the 12 T magnetic field induces regular growth,consistent deflection and the decrease of secondary arm spacing of the dendrites.In the small couples,the α（Al） dendrites still reveal a directional growth character to some extent with a SMF of ≤5 T.However,an 8.8 T SMF destroys the directional growth and induces severe random deflections of the dendrites.When the SMF increases to 12 T,the a（Al） dendrites become quite regular despite of the consistent deflection.The directional growth arises from the continuous long-range concentration gradient field built in the melt.The morphological modification is mainly related to the suppression of natural convections and the induction of thermoelectric magnetic convection by the SMF.

偶散流变与盛唐七绝范式的形成

初唐七绝风调未谐,其发展衍变可以分为三个阶段,总体上有着不断律化、由偶趋散的特征。前两个阶段在声律与对偶上尚存齐梁遗风,第三阶段中,七绝虽"律始就纯",但仍未寻找到适合该类诗体独有的写作方式。盛唐七绝数量大增,且体式多为散体,有别于初唐七绝。这与七绝诗体功能的改变、诗坛风尚的转变,以及盛唐诗人对乐府句法的借鉴学习有关。在七绝的写作中,对偶手法的缺席,有利于抒情、叙事等因素掺入。七绝由偶至散的变化扩大了诗歌的容量,也促进了意脉的流畅贯通,直接改变了七绝的风格,故七绝这一诗体的审美范式得以确立,并被后世称为正体。

Isothermal section of Mg-Nd-Gd ternary system at 723 K

An isothermal section of the Mg-Nd-Gd ternary system at 723 K was established by diffusion triple technique and electron probe microanalysis （EPMA）. Mg3Gd and Mg3Nd form a continuous solid solution （Gd,Nd）3Mg, and a continuous solid solution （Gd,Nd）Mg is also formed between MgGd and MgNd. Mg7Gd, Mg5Gd, Mg2Gd, Mg41Nd5, （Gd,Nd）3Mg and （Gd,Nd）Mg are found in the ternary system. In these intermetallic phases, Mg7Gd has been reported to be a metastable phase in previous literatures. The solubilities of Mg, Gd and Nd in all the phases were detected. Furthermore, four three-phase equilibria, α（Mg）＋Mg7Gd＋Mg41Nd5, Mg7Gd＋Mg5Gd＋Mg41Nd5, Mg5Gd＋Mg41Nd5＋（Gd,Nd）3Mg and （Gd,Nd）3Mg＋（Gd,Nd）Mg＋Mg2Gd, were identified in the isothermal section.

Isothermal section of Al-Ti-Zr ternary system at 1073 K

Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis （EPMA）. Experimental results show that there is a solid solutionβ（Ti,Zr） which dissolves Al up to 16.3% （mole fraction）. Ti and Zr can substitute each other in most Ti-Al and Al-Zr binaryintermediate phases to a certain degree while the maximum solubility of Zr in Ti3Al and TiAl reaches up to 17.9% and 4.0% （molefraction）, respectively. The isothermal section consists of 16 single-phased regions, 27 two-phased regions and 14 three-phasedregions. No ternary phase was detected.

Role of Kirkendall effect in diffusion processes in solids

In the 1940s, KIRKENDALL showed that diffusion in binary solid solutions cannot be described by only one diffusion coefficient. Rather, one has to consider the diffusivity of both species. His findings changed the treatment of diffusion data and the theory of diffusion itself. A diffusion-based framework was successfully employed to explain the behaviour of the Kirkendall plane. Nonetheless, the complexity of a multiphase diffusion zone and the morphological evolution during interdiffusion requires a physico-chemical approach. The interactions in binary and more complex systems are key issues from both the fundamental and technological points of view. This paper reviews the Kirkendall effect from the circumstances of its discovery to recent developments in its understanding, with broad applicability in materials science and engineering.

Effect of Fe content on microstructures and properties of Ti6Al4V alloy with combinatorial approach

A combinatorial approach was applied to investigating the influence of Fe content on the microstructures and properties of Ti6Al4V alloy.A diffusion couple was manufactured with Ti6Al4V and Ti6Al4V20Fe alloys and annealed at 1000°C for 600 h to obtain a wide range of compositions.By combining electron probe micro-analysis(EPMA),scanning electron microscopy(SEM)and nanoindentation,the relationships between composition and microstructure as well as hardness were determined.It is found that after aging the Ti6Al4V5Fe sample contains reasonable(about 55%)volume fraction of fineαphase and shows the peak hardness among the Ti6Al4VxFe alloys.Therefore,it is a promising candidate for the development of titanium alloys.HAADF-STEM and XRD reveal that after quenching from the singleβphase field,the metastableα''lamellae form in the Ti6Al4V5Fe alloy,and on subsequent isothermal aging,theα''lamellae become coarse and act as precursors/preferential nucleation sites for the stableαphase.

Investigation of mechanical and diffusion properties in bcc Ti−Nb−Zr−Sn alloys via a high-throughput method

The mechanical and diffusion properties of bcc Ti−Nb−Zr−Sn alloys in the Ti-rich corner were analyzed through a high-throughput method with the combination of nanoindentation and diffusion couple techniques.Nine groups of quaternary Ti−Nb−Zr−Sn diffusion couples were prepared after annealing at 1273 K for 25 h.The composition-dependent mechanical properties were determined by nanoindentation and electron probe microanalysis(EPMA)techniques.Moreover,the corresponding interdiffusion coefficients were confirmed from the composition gradients of the quaternary diffusion couples using a pragmatic numerical inverse method.A composition-dependent database on the mechanical and diffusion properties was utilized to discuss the processability during the hot working.The results reveal that the solute elements Nb and Sn are strictly controlled to increase the hardness and wear resistance of Ti−Nb−Zr−Sn alloys,and the additional element Zr is mainly useful to improve the processability during the hot working.

High-throughput determination of mechanical and diffusion properties of Ti–Ta–Fe alloys

The mechanical and diffusion properties of Ti-Ta-Fe alloys in the Ti-rich region were investigated by utilizing a high-throughput method, with the combination of nanoindentation and diffusion couple techniques.Five groups of ternary Ti-Ta-Fe diffusion couples were prepared after annealing at 1273 K for 25 h. The composition-dependent mechanical properties of bcc Ti-Ta-Fe system were experimentally determined by means of nanoindentation and electron probe microanalysis(EPMA) techniques. Moreover, the interdiffusion coefficients of Ti-Ta-Fe alloys at 1273 K were confirmed from the composition gradients of the ternary diffusion couples with the support of a pragmatic numerical inverse method. A composition-dependent database on the mechanical and diffusion properties of Ti-Ta-Fe alloys was carefully established and utilized for the discussion of the processability during the hot working. The results indicated that the content of Fe should be controlled for the Ti alloys with high hardness and low Young’s modulus.

Phase equilibria in Ti-Ni-Pt ternary system

Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffraction(XRD)techniques,isothermal sections at 1073 and 1173 K of this system were constructed and existence of ternary phase Ti2(Ni,Pt)3 was confirmed.In addition,binary compounds Ti3Pt5 and TiPt3-were found to be stable at 1073 and 1173 K,and remarkable ternary solubility in some binary compounds was detected,e.g.,solubility of Pt in TiNi can be up to about 36%(molar fraction)at 1073 K and 40%(molar fraction)at 1173 K.Furthermore,a ternary invariant transition reaction TiNi3+Ti3Pt5→Ti2(Ni,Pt)3+TiPt3+at a temperature between 1073 and 1173 K was deduced.

Self-organized layered growth phenomena of diffusion couples with spinodal decomposition in binary alloys

In order to investigate the formation mechanisms of the layered growth phenomena in diffusion couples with spinodal decomposition,a phase field model combined with elastic strain field was employed.Microstructure evolutions of diffusion couple with spinodal decomposition in binary alloys were numerically simulated by considering concentration fluctuation and elastic anisotropy.The simulation results indicate that the number of the periodical layers decreases with the increase of initial concentration fluctuation,even with large elastic anisotropy.The growth of layered microstructures can be attributed to the directional diffusion enhanced by initially discontinuous chemical potential at the interface.

Microstructure characterization of NiFe_2O_4-NiO solid-solid diffusion couple

The solid state interdiffusion between NiFe204 and NiO in nitrogen atmosphere was studied by means of diffusion couple technique. NiFe204/NiO diffusion couple with plane interfaces was made by clamping method and sintering at 1 300℃ for 10 h. Scanning electronic microscopy （SEM） and energy-dispersive X-ray spectrometry （EDS） were used to analyze the microstructure and phase composition of the diffusion couples. The results indicate that a porous layer of uniform thickness forms along the NiFe2O4/NiO bonding interface and exhibits a deep penetration in the NiFe2O4 due to the Kirkendall effect. Furthermore, SEM observations reveal that the needle-like nickel ferrite precipitates form in NiO near the interface and the formation mechanism of them are inferred to be diffusion type solid-state phase changes.

Dispersion of graphene in silane coupling agent aqueous solutions

In order to reduce the agglomeration of nanographene and improve its dispersibility,six silane coupling agents were used to modify the surface of the nanographene particles.Visual inspection,Fourier-transform infrared spectroscopy,transmission electron microscopy,Raman spectroscopy,and X-ray diffraction were employed to evaluate the dispersion properties of the resulting graphene in an aqueous solution of silane coupling agents.Results show that all six types of silane coupling agents are efficient in promoting the dispersion of graphene in aqueous solutions,and no obvious sedimentation of the graphene dispersion solution is observed after a stationary storage period of 30 d.Taking 3-aminopropyltriethoxysilane(KH-550)as an example,after the graphene is dispersed in the KH-550 aqueous solution,the carboxyl group on the surface of the graphene reacts with the KH-550 amino group to form an amide bond,and KH-550 is successfully grafted onto the graphene surface.Polar functional groups ionize in water,creating an electrostatic repulsion effect,or hydrophilic functional groups form hydrogen bonds with water molecules,which is believed to improve the dispersion stability of graphene.The dispersed graphene is curled and contains many folds.Each fold has about three or four layers,with an interlayer spacing of about 0.65 nm.The dispersed graphene also has a complete lattice and a reduced number of defects.Nanographene disperses well in silane coupling agent aqueous solutions and can,therefore,be used to prepare cement-based composites.

Solutions Of Boundary-Value Problems of the Generalized Theory of Couple-Stress Thermodiffusion

We have considered the basic dynamic homogeneous system of partial differential equations of generalized Green-Lindsay couple-stress thermodiffusion on the plane for homogeneous, isotropic elastic media with the centre of symmetry. We have constructed regular solution of the boundary problems on the line. In the works are obtained in quadrates the solution of the boundary-value problem of the generalized Green-Lindsay theory of couple-stress thermodiffusion, when on border of area are given： the component of normal of displacement vector, the component of touching of stress vector, rotations, flow of heat and flow of diffusion.

Nonlinear Absorption and Dispersion Response in Optically Dense Media Driven by a Single-Mode Laser

Taking the density-dependent near dipole-dipole （NDD） interaction into consideration, we theoretically investigate the response of nonlinear absorption and dispersion in optically dense media of three-level atoms driven by a single-mode probe laser. The influence of the NDD effects on the absorption and dispersion spectra of the probe field is predicted via numerical calculations. It is shown that the NDD effects reduce gradually to transient absorption and amplification with the increase of the strengths of the NDD interaction, but do not change the steady-state behavior. Due to the presence of the NDD effects, steady-state absorption spectra exhibit asymmetric double-peak structure and overall shifts when a continuous-wave （cw） probe field is applied. However, frequency dispersion spectra are insensitive to them near the zero detuning.

Configuration resonance in scattering scanning near-field optical microscopy

A theoretical model is proposed in order to study the configuration resonance in s-SNOM. The electromagnetic coupling between the sample and the probe tip is described with the quasi-electrostatic field theory. This method permits us to analyze the confignrational resonance evoked by the interaction between the probe tip and the sample in s-SNOM intuitively. The resonant conditions for a certain system are presented in an explicit form. On the condition of considering the actual size of the sample dipoles and the probe dipole, we discuss the possibility of realizing the configurational resonance for various material samples. The numerical results indicate that the polarizability of the dielectric probe tip is too small to arouse this resonance, whereas, with the surface plasmon resonance emerging on the metallic nanoparticles, the enhanced polarizability of the metallic probe tip ensures the requirements of fulfilling the resonance.

Wideband dipole logging based on segmen linear frequency modulation excitation

A wideband dipole signal is required for dipole dispersion correction and nearborehole imaging. To obtain the broadband flexural wave dispersion, we use a nonlinear frequency modulation （NLFM） signal and propose a segment linear frequency modulation （SLFM） signal as the dipole excitation signal to compensate for the excitation intensity. The signal-to-noise ratio （SNR） of the signal over the entire frequency band is increased. The finite-difference method is used to simulate the responses from a Ricker wavelet, a linear frequency modulation （LFM） signal, an NLFM signal, and an SLFM signal in two borehole models of a homogeneously hard formation and a radially stratified formation. The dispersion and radial tomography results at low SNR of the sound source signals are compared. Numerical modeling suggests that the energy of the flexural waves excited by the Ricker wavelet source is concentrated near the Airy phase. In this case, the dispersion is incomplete and information regarding the formation near or far from the borehole cannot be obtained. The LFM signal yields dispersion information near the Airy phase and the high-frequency range but not in the low-frequency range. Moreover, the information regarding the formation far from the borehole is not accurate. The NLFM signal extends the frequency range of the flexural waves by compensating for the excitation intensity and yields information regarding the formation information, but it is not easy to obtain. The SLFM signal yields the same results as the NLFM signal and is easier to implement. Consequently, the dipole detection range expands and the S-wave velocity calculation accuracy improves.