Aim To study the relationships between average molecular mass and intrinsic viscosity of polyanhydrides. Methods With chloroform as solvent and petroleum ether as the precipitating agent polyanhydride was separated in...Aim To study the relationships between average molecular mass and intrinsic viscosity of polyanhydrides. Methods With chloroform as solvent and petroleum ether as the precipitating agent polyanhydride was separated into a series of grades with different average molecular mass. The absolute average molecular mass (M) and intrinsic viscosity ([]) of every grade were measured. Results and Conclusion The relationships between [] and M of three typical polyanhydrides were obtained from bi-logarithm coordinate plotting of [] versus M.展开更多
The probe absorption-dispersion spectra of a radio-frequency (RF)-driven five-level atom embedded in a photonic crystal are investigated by considering the isotropic double-band photonic-bandogap (PBG) reservoir. ...The probe absorption-dispersion spectra of a radio-frequency (RF)-driven five-level atom embedded in a photonic crystal are investigated by considering the isotropic double-band photonic-bandogap (PBG) reservoir. In the model used, the two transitions are, respectively, coupled by leading to some curious phenomena. Numerical simulations the upper and lower bands in such a PBG material, thus are performed for the optical spectra. It is found that when one transition frequency is inside the band gap and the other is outside the gap, there emerge three peaks in the absorption spectra. However, for the case that two transition frequencies lie inside or outside the band gap, the spectra display four absorption profiles. Especially, there appear two sharp peaks in the spectra when both transition frequencies exist inside the band gap. The influences of the intensity and frequency of the RF-driven field on the absorptive and dispersive response are analyzed under different band-edge positions. It is found that a transparency window appears in the absorption spectra and is accompanied by a very steep variation of the dispersion profile by adjusting system parameters. These results show that the absorption-dispersion properties of the system depend strongly on the RF-induced quantum interference and the density of states (DOS) of the PBG reservoir.展开更多
Bioaerosol, an important constituent of the atmosphere, can directly affect light radiation characteristics due to absorption and scattering effects. Current research lacks a reasonable explanation for the extinction ...Bioaerosol, an important constituent of the atmosphere, can directly affect light radiation characteristics due to absorption and scattering effects. Current research lacks a reasonable explanation for the extinction abilities of bioaerosols in a broadband. Herein, we measured the reflectance spectra of 12 com m on biomaterials and calculated their complex refractive indexes. The peaks of the imaginary part of the complex refractive indexes are located at wavelengths of approximately 0.7, 2.7, 6.1 and 9.5μm. Based on photographs of the floating structures of bioaerosols, we constructed a model for calculating the extinction abilities of bioaerosols in the wavelength range of 240 nm to 14 (im. Taking AN02 spores as an example, absorption was found to account for more than 90% of the total extinction. In addition, the theoretical calculations and experimental data of transmittance corresponding to the smoke box show that bioaerosol exhibits significant broadband extinction ability from UV to IR bands, which provides new directions for the development of broadband light attenuation materials.展开更多
In this paper, composite coagulants (PFS, PFSC05, PFSC1 and PFSC5), prepared by mixing polyferric sulfate (PFS) and cationic polyelectrolyte (CP) coagulants with different weight percent (Wv) of CP (Wp = 0%, ...In this paper, composite coagulants (PFS, PFSC05, PFSC1 and PFSC5), prepared by mixing polyferric sulfate (PFS) and cationic polyelectrolyte (CP) coagulants with different weight percent (Wv) of CP (Wp = 0%, 0.5%, 1% and 5%, respectively), were adopted to treat cyanide-containing wastewater. PFSC5 exhibited superior coagulation performances at optimal conditions: the removal of total cyanide (TCN) and chemical oxygen demand (COD) was 95%-97% and 50%-55%, respectively. The effects of CP on the properties and structure of flocs were investigated by laser diffraction instrument and small-angle laser light scattering (SALLS), respectively. The results show that the flocs of PFSC5 have higher growth rate, higher strength factor and lower recovery factor than other flocs. They are also much denser and more uniform owing to the higher fractal dimension (DO and less microflocs (10-100μm). Furthermore, the dense structure of the PFSC5 flocs can be restored after shear and is more resistant to hydraulic conditions. Particularly, detailed morphology evolution of the flocs was in-situ detected by on-line particle imaging. Due to strong ionic strength in wastewater, the CP in PFSC5 plays a significant role of adsorption, while the main mechanism of CP is electrostatic patch aggregation during the PFSC05 systems.展开更多
Scattering phase function is assumed to be one of the most significant factors in the inherent optical properties (lOPs) of natural water. According to three criteria proposed for assessment, several commonly used e...Scattering phase function is assumed to be one of the most significant factors in the inherent optical properties (lOPs) of natural water. According to three criteria proposed for assessment, several commonly used empirical phase functions are compared with their related practical or theoretical scattering distributions in terms of fitting errors under the circumstances of typical seawater and single-component polydisperse systems. The optimal factors corresponding to the minimum fitting errors are also calculated. It is found that both the one-term Henyey-Greenstein (OTHG) and two-term Henyey-Greenstein (TTHG) phase functions agree well with the theoretical ones for small particles, while the Fouriner-Forand (FF) phase function can be used in the case of suspensions with large suspended particles. The fitting accuracy of OTHG is the worst, FF is better and TTHG is the best.展开更多
We investigate theoretically single photon transport properties in coupled-resonator waveguide coupling with a nanocavity interacting with an external mirror. By using the discrete coordinates approach, transmission a...We investigate theoretically single photon transport properties in coupled-resonator waveguide coupling with a nanocavity interacting with an external mirror. By using the discrete coordinates approach, transmission and reflection amplitudes of the propagating single photon in the waveguide are obtained. The influence of the coupling strength between the nanocavity and the external mirror on the single photon scattering spectra is discussed. We also extend the results to the waveguide with linear and quadratic form dispersion relations.展开更多
Airborne light detection and ranging (LIDAR) can detect the three-dimensional structure of forest canopies by transmitting laser pulses and receiving returned waveforms which contain backscatter from branches and leav...Airborne light detection and ranging (LIDAR) can detect the three-dimensional structure of forest canopies by transmitting laser pulses and receiving returned waveforms which contain backscatter from branches and leaves at different heights.We established a solid scatterer model to explain the widened durations found in analyzing the relationship between laser pulses and forest canopies,and obtained the corresponding rule between laser pulse duration and scatterer depth.Based on returned waveform characteristics,scatterers were classified into three types:simple,solid and complex.We developed single-peak derivative and multiple-peak derivative analysis methods to retrieve waveform features and discriminate between scatterer types.Solid scatterer simulations showed that the returned waveforms were widened as scatterer depth increased,and as space between sub-scatterers increased the returned waveforms developed two peaks which subsequently developed into two separate sub-waveforms.There were slight differences between the durations of simulated and measured waveforms.LIDAR waveform data are able to describe the backscatter characteristics of forest canopies,and have potential to improve the estimation accuracy of forest parameters.展开更多
文摘Aim To study the relationships between average molecular mass and intrinsic viscosity of polyanhydrides. Methods With chloroform as solvent and petroleum ether as the precipitating agent polyanhydride was separated into a series of grades with different average molecular mass. The absolute average molecular mass (M) and intrinsic viscosity ([]) of every grade were measured. Results and Conclusion The relationships between [] and M of three typical polyanhydrides were obtained from bi-logarithm coordinate plotting of [] versus M.
基金Supported by the National Natural Science Foundation of China under Grant Nos.91021011,10975054,11004069,and 10874050the Doctoral Foundation of the Ministry of Education of China under Grant Nos.200804870051,20100142120081the Innovation Foundation from Huazhong University of Science and Technology under Grant No.2010MS074
文摘The probe absorption-dispersion spectra of a radio-frequency (RF)-driven five-level atom embedded in a photonic crystal are investigated by considering the isotropic double-band photonic-bandogap (PBG) reservoir. In the model used, the two transitions are, respectively, coupled by leading to some curious phenomena. Numerical simulations the upper and lower bands in such a PBG material, thus are performed for the optical spectra. It is found that when one transition frequency is inside the band gap and the other is outside the gap, there emerge three peaks in the absorption spectra. However, for the case that two transition frequencies lie inside or outside the band gap, the spectra display four absorption profiles. Especially, there appear two sharp peaks in the spectra when both transition frequencies exist inside the band gap. The influences of the intensity and frequency of the RF-driven field on the absorptive and dispersive response are analyzed under different band-edge positions. It is found that a transparency window appears in the absorption spectra and is accompanied by a very steep variation of the dispersion profile by adjusting system parameters. These results show that the absorption-dispersion properties of the system depend strongly on the RF-induced quantum interference and the density of states (DOS) of the PBG reservoir.
基金supported by the National Natural Science Foundation of China (61271353 and 60908033)the Natural Science Foundation of Anhui Province (1408085MKL47)
文摘Bioaerosol, an important constituent of the atmosphere, can directly affect light radiation characteristics due to absorption and scattering effects. Current research lacks a reasonable explanation for the extinction abilities of bioaerosols in a broadband. Herein, we measured the reflectance spectra of 12 com m on biomaterials and calculated their complex refractive indexes. The peaks of the imaginary part of the complex refractive indexes are located at wavelengths of approximately 0.7, 2.7, 6.1 and 9.5μm. Based on photographs of the floating structures of bioaerosols, we constructed a model for calculating the extinction abilities of bioaerosols in the wavelength range of 240 nm to 14 (im. Taking AN02 spores as an example, absorption was found to account for more than 90% of the total extinction. In addition, the theoretical calculations and experimental data of transmittance corresponding to the smoke box show that bioaerosol exhibits significant broadband extinction ability from UV to IR bands, which provides new directions for the development of broadband light attenuation materials.
基金supported by the National Natural Science Foundation of China(51108441)the National Key Technologies R&D Program of China(2011BAC06B09)the Special Foundation of the President of the Chinese Academy of Sciences
文摘In this paper, composite coagulants (PFS, PFSC05, PFSC1 and PFSC5), prepared by mixing polyferric sulfate (PFS) and cationic polyelectrolyte (CP) coagulants with different weight percent (Wv) of CP (Wp = 0%, 0.5%, 1% and 5%, respectively), were adopted to treat cyanide-containing wastewater. PFSC5 exhibited superior coagulation performances at optimal conditions: the removal of total cyanide (TCN) and chemical oxygen demand (COD) was 95%-97% and 50%-55%, respectively. The effects of CP on the properties and structure of flocs were investigated by laser diffraction instrument and small-angle laser light scattering (SALLS), respectively. The results show that the flocs of PFSC5 have higher growth rate, higher strength factor and lower recovery factor than other flocs. They are also much denser and more uniform owing to the higher fractal dimension (DO and less microflocs (10-100μm). Furthermore, the dense structure of the PFSC5 flocs can be restored after shear and is more resistant to hydraulic conditions. Particularly, detailed morphology evolution of the flocs was in-situ detected by on-line particle imaging. Due to strong ionic strength in wastewater, the CP in PFSC5 plays a significant role of adsorption, while the main mechanism of CP is electrostatic patch aggregation during the PFSC05 systems.
基金supported by the National "863" Program (No. 2006AA09Z207)
文摘Scattering phase function is assumed to be one of the most significant factors in the inherent optical properties (lOPs) of natural water. According to three criteria proposed for assessment, several commonly used empirical phase functions are compared with their related practical or theoretical scattering distributions in terms of fitting errors under the circumstances of typical seawater and single-component polydisperse systems. The optimal factors corresponding to the minimum fitting errors are also calculated. It is found that both the one-term Henyey-Greenstein (OTHG) and two-term Henyey-Greenstein (TTHG) phase functions agree well with the theoretical ones for small particles, while the Fouriner-Forand (FF) phase function can be used in the case of suspensions with large suspended particles. The fitting accuracy of OTHG is the worst, FF is better and TTHG is the best.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11105001 and 61472282the Anhui Provincial Natural Science Foundation under Grant Nos.1408085QA22,1608085MA09,and 1508085MF129
文摘We investigate theoretically single photon transport properties in coupled-resonator waveguide coupling with a nanocavity interacting with an external mirror. By using the discrete coordinates approach, transmission and reflection amplitudes of the propagating single photon in the waveguide are obtained. The influence of the coupling strength between the nanocavity and the external mirror on the single photon scattering spectra is discussed. We also extend the results to the waveguide with linear and quadratic form dispersion relations.
基金supported by the National Basic Research Program of China(Grant No.2007CB714404)the Central PublicInterest Scientific Institution Basal Research Fund of China(Grant No.IFRIT200803)the National HiTech Research and Development Program of China(Grant No.2009AA12Z1461)
文摘Airborne light detection and ranging (LIDAR) can detect the three-dimensional structure of forest canopies by transmitting laser pulses and receiving returned waveforms which contain backscatter from branches and leaves at different heights.We established a solid scatterer model to explain the widened durations found in analyzing the relationship between laser pulses and forest canopies,and obtained the corresponding rule between laser pulse duration and scatterer depth.Based on returned waveform characteristics,scatterers were classified into three types:simple,solid and complex.We developed single-peak derivative and multiple-peak derivative analysis methods to retrieve waveform features and discriminate between scatterer types.Solid scatterer simulations showed that the returned waveforms were widened as scatterer depth increased,and as space between sub-scatterers increased the returned waveforms developed two peaks which subsequently developed into two separate sub-waveforms.There were slight differences between the durations of simulated and measured waveforms.LIDAR waveform data are able to describe the backscatter characteristics of forest canopies,and have potential to improve the estimation accuracy of forest parameters.