The H+H2 reaction is the simplest chemical reaction system and has long been the prototype model in the study of reaction dynamics. Here we report a high resolution experimental investigation of the state-to-state rea...The H+H2 reaction is the simplest chemical reaction system and has long been the prototype model in the study of reaction dynamics. Here we report a high resolution experimental investigation of the state-to-state reaction dynamics in the H+HD→H2+D reaction by using the crossed molecular beams method and velocity map ion imaging technique at the collision energy of 1.17 eV. D atom products in this reaction were probed by the near threshold 1+1'(vacuum ultraviolet+ultraviolet) laser ionization scheme. The ion image with both high angular and energy resolution were acquired. State-to-state differential cross sections was accurately derived. Fast forward scattering oscillations, relating with interference effects in the scattering process, were clearly observed for H2 products at H2(v'=0,j'=1) and H2(v'=0,j'=3) rovibrational levels. This study further demonstrates the importance of measuring high-resolution differential cross sections in the study of state-to-state reaction dynamics in the gas phase.展开更多
In Jaynes-Cummings model,by using the modulation of the coupling coefficient formed by the atom,medium and scattering optical,atomic inversion evolution of arbitrary forms has been worked out.Its feasibility has been ...In Jaynes-Cummings model,by using the modulation of the coupling coefficient formed by the atom,medium and scattering optical,atomic inversion evolution of arbitrary forms has been worked out.Its feasibility has been proved,and the curvature of the atomic inversion evolution of the arbitrary forms is obtained.It announces that the atom and coupling medium system are to express the operators of the atom and optical field quantum in Jaynes-Cummings model.These operators can express arbitrary medium system.In these systems,the coupling coefficient can be changed and exactly controlled in the longer coherent times.展开更多
基金supported by the National Key R&D Program of China (No.2016YFF0200500)the National Natural Science Foundation of China (No.21473173, No.21590802, No.21403207, No.21503206)the Strategic Priority Research Program of Chinese Academy of Sciences (No.XDB17000000)
文摘The H+H2 reaction is the simplest chemical reaction system and has long been the prototype model in the study of reaction dynamics. Here we report a high resolution experimental investigation of the state-to-state reaction dynamics in the H+HD→H2+D reaction by using the crossed molecular beams method and velocity map ion imaging technique at the collision energy of 1.17 eV. D atom products in this reaction were probed by the near threshold 1+1'(vacuum ultraviolet+ultraviolet) laser ionization scheme. The ion image with both high angular and energy resolution were acquired. State-to-state differential cross sections was accurately derived. Fast forward scattering oscillations, relating with interference effects in the scattering process, were clearly observed for H2 products at H2(v'=0,j'=1) and H2(v'=0,j'=3) rovibrational levels. This study further demonstrates the importance of measuring high-resolution differential cross sections in the study of state-to-state reaction dynamics in the gas phase.
基金Natural Science Basic Research Project for Education Depart ment of Henan Province(2007140010)
文摘In Jaynes-Cummings model,by using the modulation of the coupling coefficient formed by the atom,medium and scattering optical,atomic inversion evolution of arbitrary forms has been worked out.Its feasibility has been proved,and the curvature of the atomic inversion evolution of the arbitrary forms is obtained.It announces that the atom and coupling medium system are to express the operators of the atom and optical field quantum in Jaynes-Cummings model.These operators can express arbitrary medium system.In these systems,the coupling coefficient can be changed and exactly controlled in the longer coherent times.
