Amorphous Ti2?xMgxNi (x=0?0.3) alloys were prepared by mechanical milling of elemental powders. Charge and discharge test, linear polarization (LP) and potential-step measurement were carried out to investigate the el...Amorphous Ti2?xMgxNi (x=0?0.3) alloys were prepared by mechanical milling of elemental powders. Charge and discharge test, linear polarization (LP) and potential-step measurement were carried out to investigate the electrochemical hydrogen storage properties of the alloys before and after heat treatment. The results show that the maximum discharge capacity of heat-treated Ti2?xMgxNi alloy can reach 275.3 mA·h/g, which is 100 mA·h/g higher than that of the amorphous Ti2?xMgxNi alloy. The heat-treated Ti1.9Mg0.1Ni alloy presents the best cycling stability with a high discharge capacity of 210 mA·h/g after 30 cycles. The results of LP and potential-step measurement of the Ti1.9Mg0.1Ni alloy show that the exchange current density increases from 101.1 to 203.3 mA/g and the hydrogen diffusion coefficient increases from 3.20×10?11 to 2.70×10?10 cm2/s after the heat treatment, indicating that the heat treatment facilitates both the charge-transfer and hydrogen diffusion processes, resulting in an improvement in electrochemical hydrogen storage properties of Ti2?xMgxNi (x=0?0.3) alloys.展开更多
In a rectangular fluidized bed combustor, the tracer gas is injected continuously into the bed from a point source at the center of the distributor plate. In this study, a general governing equation is formulated for ...In a rectangular fluidized bed combustor, the tracer gas is injected continuously into the bed from a point source at the center of the distributor plate. In this study, a general governing equation is formulated for tracer gas dispersion in the bed. An analytical solution is derived to estimate the dispersion coefficients, Dxand Dy, in a horizontal plane. The concentration profiles at different sampling heights with various gas velocities are plotted.Subsequently, to estimate the dispersion coefficients, surface fitting of the obtained analytical solution to the experimental data is performed. The dispersion coefficients obtained from this model are compared with those of a conventional model. Additionally, the effect of walls, bed height and gas injection rate on the dispersion coefficients in a horizontal plane is investigated, and the effect of distributor design on the dispersion coefficients in a horizontal plane is investigated with different tracer positions. It is found that Dxand Dyare nearly equivalent at a lower tracer gas ratio of the injected gas to the total gas flow rate. It is also demonstrated that the effect of bed height on Dxis minor. This model is also able to estimate the dispersion coefficients in the case of a multihorizontal nozzle distributor.展开更多
A new insight into the constant current-constant voltage (CC-CV) charge protocol based on the spherical diffusion model was presented. From the model, the CV-charge process compensates, to a large extent, the capaci...A new insight into the constant current-constant voltage (CC-CV) charge protocol based on the spherical diffusion model was presented. From the model, the CV-charge process compensates, to a large extent, the capacity loss in the CC process, and the capacity loss increases with increasing the charging rate and decreases with increasing the lithium-ion diffusion coefficient and using a smaller r value (smaller particle-size and larger diffusion coefficient) and a lower charge rate will be helpful to decreasing the capacity loss. The results show that the CC and the CV charging processes, in some way, are complementary and the capacity loss during the CC charging process due to the large electrochemical polarization can be effectively compensated from the CV charging process.展开更多
The problem of oblique wave (internal wave) propagation over a small deformation in a channel flow consisting of two layers was considered. The upper fluid was assumed to be bounded above by a rigid lid, which is an...The problem of oblique wave (internal wave) propagation over a small deformation in a channel flow consisting of two layers was considered. The upper fluid was assumed to be bounded above by a rigid lid, which is an approximation for the free surface, and the lower one was bounded below by an impermeable bottom surface having a small deformation; the channel was unbounded in the horizontal directions. Assuming irrotational motion, the perturbation technique was employed to calculate the first-order corrections of the velocity potential in the two fluids by using Green's integral theorem suitably with the introduction of appropriate Green's functions. Those functions help in calculating the reflection and transmission coefficients in terms of integrals involving the shape ftmction c(x) representing the bottom deformation. Three-dimensional linear water wave theory was utilized for formulating the relevant boundary value problem. Two special examples of bottom deformation were considered to validate the results. Consideration of a patch of sinusoidal ripples (having the same wave number) shows that the reflection coefficient is an oscillatory function of the ratio of twice the x-component of the wave number to the ripple wave number. When this ratio approaches one, the theory predicts a resonant interaction between the bed and the interface, and the reflection coefficient becomes a multiple of the number of ripples. High reflection of incident wave energy occurs if this number is large. Similar results were observed for a patch of sinusoidal ripples having different wave numbers. It was also observed that for small angles of incidence, the reflected energy is greater compared to other angles of incidence up to π/ 4. These theoretical observations are supported by graphical results.展开更多
L-Arginine is an important component of amino acid injection. Its diffusion in body fluid and blood is of key importance to understand drug diffusion and drug release. As a fundamental demand for study and being a con...L-Arginine is an important component of amino acid injection. Its diffusion in body fluid and blood is of key importance to understand drug diffusion and drug release. As a fundamental demand for study and being a considerably valuable reference for application, in this study, the diffusion coefficients of L-arginine in polyacrylamide(PAM) aqueous solution used as non-Newtonian fluid similar to blood and body fluid were measured using a holographic interferometer. The effects of interaction among molecules and solution concentration on diffusion were analyzed and discussed, respectively. Based on the obstruction-scaling model, a novel modified model was presented for predicting diffusivity of solute in non-Newtonian fluid. Good agreement was achieved between the calculated value and the experimental data.展开更多
Self-diffusion coefficients of exponential-six fluids are studied using equilibrium molecular dynamics simulation technique. Mean-square displacements and velocity autocorrelation functions are used to calculate self-...Self-diffusion coefficients of exponential-six fluids are studied using equilibrium molecular dynamics simulation technique. Mean-square displacements and velocity autocorrelation functions are used to calculate self-diffusion coefficients through Einstein equation and Green-Kubo formula. It has been found that simulation results are in good agreement with experimental data for liquid argon which is taken as exponential-six fluid. The effects of density, temperature and steepness factor for repulsive part of exponential-six potential on self-diffusion coefficients are also investigated. The simulation results indicate that the self-diffusion coefficient of exponential-six fluid increases as temperature increases and density decreases. In addition, the larger self-diffusion coefficients are obtained as the steepness factor increases at the same temperature and density condition.展开更多
There are many experimental approaches,field investigations and numerical calculations for movements of woods in a clear water and debris flow.However,kinematic conditions for accumulated logs and the interactions bet...There are many experimental approaches,field investigations and numerical calculations for movements of woods in a clear water and debris flow.However,kinematic conditions for accumulated logs and the interactions between a main flow and logs have not been fully evaluated.Mitigations for woods need taking into account the characteristics of tree species such as conifer and broad-leaf trees and of shapes such as root swells and crown.In the present study,we focus on the differences in specific weight of conifer and broad-leaf trees with some moisture in a sediment-water mixture flow with narrow flow width,and consider that conifer and broad-leaf tree are floating and submerged solid phase,respectively.Flume tests are conducted in steady flow of clear and debris flow over a rigid bed in order to evaluate conifer and broad-leaf tree movement in clear water and debris flow.Experimental data indicates that dimensionless transverse diffusion coefficient can be 0.1 to 0.4 and 0.3 to 0.9 in flow direction.Those diffusive characteristics seem to be independent of Reynolds number and Froude number,but dependent of bed slope,i.e.,gravity,though detailed considerations are needed to discuss about flow characteristics such as spatial eddy structures,momentum transfer induced by interactions of logs and so on.展开更多
Turbulent diffusion efficiently transports momentum,heat,and matter and affects their transfers between the atmosphere and the surface.As a key parameter in describing turbulent diffusion,the turbulent heat diffusivit...Turbulent diffusion efficiently transports momentum,heat,and matter and affects their transfers between the atmosphere and the surface.As a key parameter in describing turbulent diffusion,the turbulent heat diffusivity KH has rarely been studied in the context of frequent urban pollution in recent years.In this study,KH under urban pollution conditions was directly calculated based on K-theory.The authors found an obvious diurnal variation in K_(H),with variations also in the vertical distributions between each case and over time.Interestingly,the height corresponding to the high occurrence frequency of negative K_(H) rises gradually after sunrise,peaks at noon,falls near sunset,and concentrates around 140 m during most of the night.The KH magnitude and fluctuation are smaller in the pollutant accumulation stage(CS)at all levels than in the pollutant transport stage and pollutant removal stage.Turbulent diffusion may greatly affect PM_(2.5) concentrations at the CS because of the negative correlation between PM_(2.5) concentrations and the absolute value of KH at the CS accompanied by weak wind speeds.The applicability of K-theory is not very good during either day or at night.These problems are inherent in K-theory when characterizing complex systems,such as turbulent diffusion,and require new frameworks or parameterization schemes.These findings may provide valuable insight for establishing a new turbulence diffusion parameterization scheme for KH and promote the study of turbulent diffusion,air quality forecasting,and weather and climate modeling.展开更多
The scattering of plane surface waves by bottom undulations in channel flow consisting of two layers is investigated by assuming that the bed of the channel is composed of porous material. The upper surface of the flu...The scattering of plane surface waves by bottom undulations in channel flow consisting of two layers is investigated by assuming that the bed of the channel is composed of porous material. The upper surface of the fluid is bounded by a rigid lid and the channel is unbounded in the horizontal directions. There exists only one wave mode corresponding to an internal wave. For small undulations, a simplified perturbation analysis is used to obtain first order reflection and transmission coefficients in terms of integrals involving the shape function describing the bottom. For sinusoidal bottom undulations and exponentially decaying bottom topography, the first order coefficients are computed. In the case of sinusoidal bottom the first order transmission coefficient is found to vanish identically. The numerical results are depicted graphically in a number of figures.展开更多
Electrically conductive composite films ofpolyaniline and nylon-6.6 are prepared by diffusing aniline followed by oxidative polymerization of aniline into nylon-6.6 matrix. In order to determine the diffusion coeffici...Electrically conductive composite films ofpolyaniline and nylon-6.6 are prepared by diffusing aniline followed by oxidative polymerization of aniline into nylon-6.6 matrix. In order to determine the diffusion coefficient for the chloride ion diffusion into the composite matrix electrochemically, galvanostatic pulse method is used and the diffusion coefficient is estimated to be -6.48× 10^-17 cm^2s^-1. The results are discussed in view of them being potential replacement materials for battery. electrodes and sensors devices.展开更多
An analysis of the solute dispersion in the liquid flowing through a pipe by means of Aris–Barton's ‘method of moments', under the joint effect of some finite yield stress and irreversible absorption into th...An analysis of the solute dispersion in the liquid flowing through a pipe by means of Aris–Barton's ‘method of moments', under the joint effect of some finite yield stress and irreversible absorption into the wall is presented in this paper. The liquid is considered as a three-layer liquid where the center region is Casson liquid surrounded by Newtonian liquid layer. A significant change from previous modelling exercises in the study of hydrodynamic dispersion, different molecular diffusivity has been considered for the different region yet to be constant. For all time period, finite difference implicit scheme has been adopted to solve the integral moment equation arising from the unsteady convective diffusion equation. The purpose of the study is to find the dependency of solute transport coefficients on absorption parameter, yield stress, viscosity ratio, peripheral layer variation and in addition with various diffusivity coefficients in different liquid layers. This kind of study may be useful for understanding the dispersion process in the blood flow analysis.展开更多
Based on high-resolution,Array for Real-time Geostrophic Oceanography(Argo)profiles and Sea Level Anomaly(SLA)data,this study statistically analyzes and compares turbulent diapycnal mixing profiles inside and outside ...Based on high-resolution,Array for Real-time Geostrophic Oceanography(Argo)profiles and Sea Level Anomaly(SLA)data,this study statistically analyzes and compares turbulent diapycnal mixing profiles inside and outside mesoscale eddies in the Gulf Stream region.The result indicates that average diapycnal diffusivity at 300–540 m depths in anticyclonic eddies reaches4.0×10-5 m2 s-1.This is significantly higher than the 1.6×10-5 m2 s-1 outside eddies and 0.8×10-5 m2 s-1 in cyclonic eddies.Probabilities of diapycnal diffusivity greater than 10-4 m2 s-1 within anticyclonic and cyclonic eddies and outside eddies are29%,5%and 12%,respectively.However,magnitudes of average diapycnal diffusivity at 540–900 m depths in these three cases are of the same order,10-5 m2 s-1.Twenty-four of a total 38 anticyclonic eddies had enhanced mixing in the ocean interior,and 22 were observed during or shortly after strong winds.The coincidence between enhanced mixing and strong wind stress indicates that more wind-induced,near-inertial wave energy propagates downward in anticyclonic eddies.The deeper part of 12 profiles(below 540 m)in anticyclonic eddies had vertical overturns with Thorpe scale exceeding 5 m,among which three profiles had overturns reaching 20 m.Enhanced mixing may have occurred in deep layers of some profiles,although it was not evident in average conditions.展开更多
This paper is devoted to investigate the influences of thermal dispersion and magnetic field on a hot semi-infinite vertical porous plate embedded in a saturated Darcy-Forchheimer-Brinkman porous medium. The coefficie...This paper is devoted to investigate the influences of thermal dispersion and magnetic field on a hot semi-infinite vertical porous plate embedded in a saturated Darcy-Forchheimer-Brinkman porous medium. The coefficient of thermal diffusivity has been assumed to be the sum of the molecular diffusivity and the dynamic diffusivity due to mechanical dispersion. The effects of transverse magnetic field parameter (Hartmann number Ha), Reynolds number Re (different velocities), Prandtl number Pr (different types of fluids) and dispersion parameter on the wall shear stress and the heat transfer rate are discussed.展开更多
In this paper,we investigate the thermal convection flow which is driven by a heat-releasing concentration field.Different from our previous work on the internally heated double diffusive convection(IHDDC),in the curr...In this paper,we investigate the thermal convection flow which is driven by a heat-releasing concentration field.Different from our previous work on the internally heated double diffusive convection(IHDDC),in the current internally heated Rayleigh-Bénard convection(IHRBC),the fluid density depends solely on the temperature field and the concentration field only serves as the internal heat source.Linear stability analyses reveal that the most unstable mode is always the stationary one.The critical Rayleigh number,which measures the strength of the unstable driving force,decreases with the Schmidt number(the ratio between the viscosity and the molecular diffusivity of concentration field),but increases with the Prandtl number(the ratio between the viscosity and the thermal molecular diffusivity).Fully developed flows are then studied by three-dimensional direct numerical simulations.The unifying model developed for IHDDC can also be used to describe the transport properties for the current flow.The characteristic widths are smaller for the plumes descending from the top plate than those ascending from the bottom one.展开更多
The constructal optimizations of T-shaped fin with two-dimensional heat transfer model are carried out by finite element method and taking the minimization of equivalent thermal resistance based on entransy dissipatio...The constructal optimizations of T-shaped fin with two-dimensional heat transfer model are carried out by finite element method and taking the minimization of equivalent thermal resistance based on entransy dissipation and the minimization of maximum thermal resistance as optimization objectives, respectively. The effects of the global parameter a (integrating the coefficient of convective heat transfer, the overall area occupied by fin and its thermal conductivity) and the volume fraction ? of fin on the minimums of equivalent thermal resistance and maximum thermal resistance as well as their corresponding optimal configurations are analyzed. The comparison of the results based on the above two optimization objectives is conducted. The results show that the optimal structures based on the two optimization objectives are obviously different from each other. Compared with the optimization result by taking the minimization of maximum thermal resistance as the objective, the optimization result by taking the equivalent thermal resistance minimization as the objective can reduce the average temperature difference in the fin obviously. The increases of a and ? can all improve the working status of local hot spot and the global heat transfer performance of the system. But the improvement effects of the increases of a and ? on the minimization of equivalent thermal resistance are different from those on the minimization of maximum thermal resistance. For either objective, the effect of a is different from that of ?. The T-shaped fin with minimum equivalent thermal resistance is much taller than that with minimum maximum thermal resistance; for either optimization objective, the stem of fin is thicker than the branches of fin, and the stem thickness is relatively close to branch thickness when the minimization of equivalent thermal resistance is taken as the optimization objective. The T-shaped fin with flat stem and slender branches can benefit the reduction of the maximum thermal resistance.展开更多
A numerical investigation on the aerodynamic effects of impeller-diffuser axial misalignment in the low-flow-coefficient centrifugal compressor is conducted through three-dimensional CFD analysis.The results show that...A numerical investigation on the aerodynamic effects of impeller-diffuser axial misalignment in the low-flow-coefficient centrifugal compressor is conducted through three-dimensional CFD analysis.The results show that the flow,especially near the diffuser inlet,is influenced by the axial misalignment obviously.When the impeller offsets to one side,the pressure at diffuser inlet close to this side will descend,and the vortex in the cavity on the other side will partially enter the diffuser and then result in the back flow.The performances of the stage and its components also change with the impeller-diffuser axial misalignment.There exists an optimum offset making the efficiency maximum at a given operating point.Furthermore,the effect of impeller-diffuser axial misalignment on the axial thrust is pronounced.The axial thrust is nearly increased linearly with the increase of axial misalignment.The aerodynamic effects of impeller-diffuser axial misalignment in the low-flow-coefficient centrifugal compressor behaves more remarkably at the large flow rate.To alleviate the aerodynamic effects of impeller-diffuser misalignment,a rounding in the meridional plane at the diffuser inlet can be applied.展开更多
Fracture analysis of a plane crack problem under chemo-mechanical loading is presented based on a linear chemo-elasticity model.The flux conductivity is introduced to characterize the influence of the crack defect on ...Fracture analysis of a plane crack problem under chemo-mechanical loading is presented based on a linear chemo-elasticity model.The flux conductivity is introduced to characterize the influence of the crack defect on the diffusion process.Using Fourier transform and the dislocation density functions,the crack problem is reduced to a set of singular integral equations,which are solved numerically by the Lobatto-Chebyshev method.Parametric studies are conducted to reveal the effects of flux conductivity,geometric configuration,chemical and mechanical loads on the crack tip field.The numerical results show that the stress singularity at the crack tip is usually a mixture of mode Ⅰ and mode Ⅱ types.展开更多
An experimental study of compressible mixing layers(CMLs)was conducted using planar laser Mie scattering(PLMS)visualizations from condensed ethanol droplets in the flow.Large ensembles of digital images were collected...An experimental study of compressible mixing layers(CMLs)was conducted using planar laser Mie scattering(PLMS)visualizations from condensed ethanol droplets in the flow.Large ensembles of digital images were collected for two flow conditions at convective Mach numbers Mc=0.11 and 0.47.The coherent vortices,braids and eruptions in the mixing zone were observed,interpreted as evidence of multi-scale,three-dimensional structures at a high Reynolds number.The mixing layers with a large visualized range present two stages along the streamwise direction,corresponding to the initial mixing and the well-developed stage.A new method,the gray level ensemble average method(GLEAM),by virtue of the similarity of the mixing layer,was applied to measure the growth rate of the CML thickness.New evidence for a nonlinear growth of CML is reported,providing an interpretation of previous observations of the scattering of the growth rate.展开更多
This paper aims to look into the determination of effective area-average concentration and dispersion coefficient associated with unsteady flow through a small-diameter tube where a solute undergoes first-order chemic...This paper aims to look into the determination of effective area-average concentration and dispersion coefficient associated with unsteady flow through a small-diameter tube where a solute undergoes first-order chemical reaction both within the fluid and at the boundary. The reaction consists of a reversible component due to phase exchange between the flowing fluid and the wall layer, and an irreversible component due to absorption into the wall. To understand the dispersion, the governing equations along with the reactive boundary conditions are solved numerically using the Finite Difference Method. The resultant equation shows how the dispersion coefficient is influenced by the first-order chemical reaction. The effects of various dimensionless parameters e.g. Da (the Damkohler number), a (phase partitioning number) and F (dimensionless absorption number) on dispersion are discussed. One of the results exposes that the dispersion coefficient may approach its steady-state limit in a short time at a high value of Damkohler number (say Da 〉 10) and a small but nonzero value of absorption rate (say P 〈0.5).展开更多
基金Project(51201089)supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions of China
文摘Amorphous Ti2?xMgxNi (x=0?0.3) alloys were prepared by mechanical milling of elemental powders. Charge and discharge test, linear polarization (LP) and potential-step measurement were carried out to investigate the electrochemical hydrogen storage properties of the alloys before and after heat treatment. The results show that the maximum discharge capacity of heat-treated Ti2?xMgxNi alloy can reach 275.3 mA·h/g, which is 100 mA·h/g higher than that of the amorphous Ti2?xMgxNi alloy. The heat-treated Ti1.9Mg0.1Ni alloy presents the best cycling stability with a high discharge capacity of 210 mA·h/g after 30 cycles. The results of LP and potential-step measurement of the Ti1.9Mg0.1Ni alloy show that the exchange current density increases from 101.1 to 203.3 mA/g and the hydrogen diffusion coefficient increases from 3.20×10?11 to 2.70×10?10 cm2/s after the heat treatment, indicating that the heat treatment facilitates both the charge-transfer and hydrogen diffusion processes, resulting in an improvement in electrochemical hydrogen storage properties of Ti2?xMgxNi (x=0?0.3) alloys.
基金The financial support from the Ministry of Science and Technology under Grant MOST 105-3113-E-033-001
文摘In a rectangular fluidized bed combustor, the tracer gas is injected continuously into the bed from a point source at the center of the distributor plate. In this study, a general governing equation is formulated for tracer gas dispersion in the bed. An analytical solution is derived to estimate the dispersion coefficients, Dxand Dy, in a horizontal plane. The concentration profiles at different sampling heights with various gas velocities are plotted.Subsequently, to estimate the dispersion coefficients, surface fitting of the obtained analytical solution to the experimental data is performed. The dispersion coefficients obtained from this model are compared with those of a conventional model. Additionally, the effect of walls, bed height and gas injection rate on the dispersion coefficients in a horizontal plane is investigated, and the effect of distributor design on the dispersion coefficients in a horizontal plane is investigated with different tracer positions. It is found that Dxand Dyare nearly equivalent at a lower tracer gas ratio of the injected gas to the total gas flow rate. It is also demonstrated that the effect of bed height on Dxis minor. This model is also able to estimate the dispersion coefficients in the case of a multihorizontal nozzle distributor.
基金Projects(20676152, 20876178) supported by the National Natural Science Foundation of China
文摘A new insight into the constant current-constant voltage (CC-CV) charge protocol based on the spherical diffusion model was presented. From the model, the CV-charge process compensates, to a large extent, the capacity loss in the CC process, and the capacity loss increases with increasing the charging rate and decreases with increasing the lithium-ion diffusion coefficient and using a smaller r value (smaller particle-size and larger diffusion coefficient) and a lower charge rate will be helpful to decreasing the capacity loss. The results show that the CC and the CV charging processes, in some way, are complementary and the capacity loss during the CC charging process due to the large electrochemical polarization can be effectively compensated from the CV charging process.
文摘The problem of oblique wave (internal wave) propagation over a small deformation in a channel flow consisting of two layers was considered. The upper fluid was assumed to be bounded above by a rigid lid, which is an approximation for the free surface, and the lower one was bounded below by an impermeable bottom surface having a small deformation; the channel was unbounded in the horizontal directions. Assuming irrotational motion, the perturbation technique was employed to calculate the first-order corrections of the velocity potential in the two fluids by using Green's integral theorem suitably with the introduction of appropriate Green's functions. Those functions help in calculating the reflection and transmission coefficients in terms of integrals involving the shape ftmction c(x) representing the bottom deformation. Three-dimensional linear water wave theory was utilized for formulating the relevant boundary value problem. Two special examples of bottom deformation were considered to validate the results. Consideration of a patch of sinusoidal ripples (having the same wave number) shows that the reflection coefficient is an oscillatory function of the ratio of twice the x-component of the wave number to the ripple wave number. When this ratio approaches one, the theory predicts a resonant interaction between the bed and the interface, and the reflection coefficient becomes a multiple of the number of ripples. High reflection of incident wave energy occurs if this number is large. Similar results were observed for a patch of sinusoidal ripples having different wave numbers. It was also observed that for small angles of incidence, the reflected energy is greater compared to other angles of incidence up to π/ 4. These theoretical observations are supported by graphical results.
基金Supported by the National Natural Science Foundation of China (20476073).
文摘L-Arginine is an important component of amino acid injection. Its diffusion in body fluid and blood is of key importance to understand drug diffusion and drug release. As a fundamental demand for study and being a considerably valuable reference for application, in this study, the diffusion coefficients of L-arginine in polyacrylamide(PAM) aqueous solution used as non-Newtonian fluid similar to blood and body fluid were measured using a holographic interferometer. The effects of interaction among molecules and solution concentration on diffusion were analyzed and discussed, respectively. Based on the obstruction-scaling model, a novel modified model was presented for predicting diffusivity of solute in non-Newtonian fluid. Good agreement was achieved between the calculated value and the experimental data.
基金Supported by the National Natural Science Foundation of China(No.29736170).
文摘Self-diffusion coefficients of exponential-six fluids are studied using equilibrium molecular dynamics simulation technique. Mean-square displacements and velocity autocorrelation functions are used to calculate self-diffusion coefficients through Einstein equation and Green-Kubo formula. It has been found that simulation results are in good agreement with experimental data for liquid argon which is taken as exponential-six fluid. The effects of density, temperature and steepness factor for repulsive part of exponential-six potential on self-diffusion coefficients are also investigated. The simulation results indicate that the self-diffusion coefficient of exponential-six fluid increases as temperature increases and density decreases. In addition, the larger self-diffusion coefficients are obtained as the steepness factor increases at the same temperature and density condition.
基金supported by Research Budget from Research and Development Center,NIPPON KOEI Co.,Ltd (Research theme:Modeling for debris flow with woods and their applicability)
文摘There are many experimental approaches,field investigations and numerical calculations for movements of woods in a clear water and debris flow.However,kinematic conditions for accumulated logs and the interactions between a main flow and logs have not been fully evaluated.Mitigations for woods need taking into account the characteristics of tree species such as conifer and broad-leaf trees and of shapes such as root swells and crown.In the present study,we focus on the differences in specific weight of conifer and broad-leaf trees with some moisture in a sediment-water mixture flow with narrow flow width,and consider that conifer and broad-leaf tree are floating and submerged solid phase,respectively.Flume tests are conducted in steady flow of clear and debris flow over a rigid bed in order to evaluate conifer and broad-leaf tree movement in clear water and debris flow.Experimental data indicates that dimensionless transverse diffusion coefficient can be 0.1 to 0.4 and 0.3 to 0.9 in flow direction.Those diffusive characteristics seem to be independent of Reynolds number and Froude number,but dependent of bed slope,i.e.,gravity,though detailed considerations are needed to discuss about flow characteristics such as spatial eddy structures,momentum transfer induced by interactions of logs and so on.
基金jointly supported by the National Natural Science Foundation of China[grant numbers 41975018 and 41675012]the National Key Research and Development Program of China[grant number 2017YFC0209605]。
文摘Turbulent diffusion efficiently transports momentum,heat,and matter and affects their transfers between the atmosphere and the surface.As a key parameter in describing turbulent diffusion,the turbulent heat diffusivity KH has rarely been studied in the context of frequent urban pollution in recent years.In this study,KH under urban pollution conditions was directly calculated based on K-theory.The authors found an obvious diurnal variation in K_(H),with variations also in the vertical distributions between each case and over time.Interestingly,the height corresponding to the high occurrence frequency of negative K_(H) rises gradually after sunrise,peaks at noon,falls near sunset,and concentrates around 140 m during most of the night.The KH magnitude and fluctuation are smaller in the pollutant accumulation stage(CS)at all levels than in the pollutant transport stage and pollutant removal stage.Turbulent diffusion may greatly affect PM_(2.5) concentrations at the CS because of the negative correlation between PM_(2.5) concentrations and the absolute value of KH at the CS accompanied by weak wind speeds.The applicability of K-theory is not very good during either day or at night.These problems are inherent in K-theory when characterizing complex systems,such as turbulent diffusion,and require new frameworks or parameterization schemes.These findings may provide valuable insight for establishing a new turbulence diffusion parameterization scheme for KH and promote the study of turbulent diffusion,air quality forecasting,and weather and climate modeling.
文摘The scattering of plane surface waves by bottom undulations in channel flow consisting of two layers is investigated by assuming that the bed of the channel is composed of porous material. The upper surface of the fluid is bounded by a rigid lid and the channel is unbounded in the horizontal directions. There exists only one wave mode corresponding to an internal wave. For small undulations, a simplified perturbation analysis is used to obtain first order reflection and transmission coefficients in terms of integrals involving the shape function describing the bottom. For sinusoidal bottom undulations and exponentially decaying bottom topography, the first order coefficients are computed. In the case of sinusoidal bottom the first order transmission coefficient is found to vanish identically. The numerical results are depicted graphically in a number of figures.
文摘Electrically conductive composite films ofpolyaniline and nylon-6.6 are prepared by diffusing aniline followed by oxidative polymerization of aniline into nylon-6.6 matrix. In order to determine the diffusion coefficient for the chloride ion diffusion into the composite matrix electrochemically, galvanostatic pulse method is used and the diffusion coefficient is estimated to be -6.48× 10^-17 cm^2s^-1. The results are discussed in view of them being potential replacement materials for battery. electrodes and sensors devices.
文摘An analysis of the solute dispersion in the liquid flowing through a pipe by means of Aris–Barton's ‘method of moments', under the joint effect of some finite yield stress and irreversible absorption into the wall is presented in this paper. The liquid is considered as a three-layer liquid where the center region is Casson liquid surrounded by Newtonian liquid layer. A significant change from previous modelling exercises in the study of hydrodynamic dispersion, different molecular diffusivity has been considered for the different region yet to be constant. For all time period, finite difference implicit scheme has been adopted to solve the integral moment equation arising from the unsteady convective diffusion equation. The purpose of the study is to find the dependency of solute transport coefficients on absorption parameter, yield stress, viscosity ratio, peripheral layer variation and in addition with various diffusivity coefficients in different liquid layers. This kind of study may be useful for understanding the dispersion process in the blood flow analysis.
基金supported by the National Natural Science Foundation of China(Grant Nos.41106012,41176008,91028008)a grant from Sanya Institute of Deep-Sea Science and Engineering(Grant No.SIDSSE-201207)
文摘Based on high-resolution,Array for Real-time Geostrophic Oceanography(Argo)profiles and Sea Level Anomaly(SLA)data,this study statistically analyzes and compares turbulent diapycnal mixing profiles inside and outside mesoscale eddies in the Gulf Stream region.The result indicates that average diapycnal diffusivity at 300–540 m depths in anticyclonic eddies reaches4.0×10-5 m2 s-1.This is significantly higher than the 1.6×10-5 m2 s-1 outside eddies and 0.8×10-5 m2 s-1 in cyclonic eddies.Probabilities of diapycnal diffusivity greater than 10-4 m2 s-1 within anticyclonic and cyclonic eddies and outside eddies are29%,5%and 12%,respectively.However,magnitudes of average diapycnal diffusivity at 540–900 m depths in these three cases are of the same order,10-5 m2 s-1.Twenty-four of a total 38 anticyclonic eddies had enhanced mixing in the ocean interior,and 22 were observed during or shortly after strong winds.The coincidence between enhanced mixing and strong wind stress indicates that more wind-induced,near-inertial wave energy propagates downward in anticyclonic eddies.The deeper part of 12 profiles(below 540 m)in anticyclonic eddies had vertical overturns with Thorpe scale exceeding 5 m,among which three profiles had overturns reaching 20 m.Enhanced mixing may have occurred in deep layers of some profiles,although it was not evident in average conditions.
文摘This paper is devoted to investigate the influences of thermal dispersion and magnetic field on a hot semi-infinite vertical porous plate embedded in a saturated Darcy-Forchheimer-Brinkman porous medium. The coefficient of thermal diffusivity has been assumed to be the sum of the molecular diffusivity and the dynamic diffusivity due to mechanical dispersion. The effects of transverse magnetic field parameter (Hartmann number Ha), Reynolds number Re (different velocities), Prandtl number Pr (different types of fluids) and dispersion parameter on the wall shear stress and the heat transfer rate are discussed.
基金the Major Research Plan of National Natural Science Foundation of China(Grant Nos.91852107 and 91752202)Mengqi Zhang acknowledges the financial support from the Ministry of Education,Singapore(MOE WBS No.R-265-000-689-114).
文摘In this paper,we investigate the thermal convection flow which is driven by a heat-releasing concentration field.Different from our previous work on the internally heated double diffusive convection(IHDDC),in the current internally heated Rayleigh-Bénard convection(IHRBC),the fluid density depends solely on the temperature field and the concentration field only serves as the internal heat source.Linear stability analyses reveal that the most unstable mode is always the stationary one.The critical Rayleigh number,which measures the strength of the unstable driving force,decreases with the Schmidt number(the ratio between the viscosity and the molecular diffusivity of concentration field),but increases with the Prandtl number(the ratio between the viscosity and the thermal molecular diffusivity).Fully developed flows are then studied by three-dimensional direct numerical simulations.The unifying model developed for IHDDC can also be used to describe the transport properties for the current flow.The characteristic widths are smaller for the plumes descending from the top plate than those ascending from the bottom one.
基金supported by the National Natural Science Foundation of China (Grant No. 10905093)the Program for New Century Excellent Talents in University of China (Grant No. NCET-04-1006)+1 种基金the Foundation for the Author of National Excellent Doctoral Dissertation of China (Grant No. 200136)the Natural Science Foundation for Youngsters of Naval University of Engineering (Grant No. HGDQNJJ10017)
文摘The constructal optimizations of T-shaped fin with two-dimensional heat transfer model are carried out by finite element method and taking the minimization of equivalent thermal resistance based on entransy dissipation and the minimization of maximum thermal resistance as optimization objectives, respectively. The effects of the global parameter a (integrating the coefficient of convective heat transfer, the overall area occupied by fin and its thermal conductivity) and the volume fraction ? of fin on the minimums of equivalent thermal resistance and maximum thermal resistance as well as their corresponding optimal configurations are analyzed. The comparison of the results based on the above two optimization objectives is conducted. The results show that the optimal structures based on the two optimization objectives are obviously different from each other. Compared with the optimization result by taking the minimization of maximum thermal resistance as the objective, the optimization result by taking the equivalent thermal resistance minimization as the objective can reduce the average temperature difference in the fin obviously. The increases of a and ? can all improve the working status of local hot spot and the global heat transfer performance of the system. But the improvement effects of the increases of a and ? on the minimization of equivalent thermal resistance are different from those on the minimization of maximum thermal resistance. For either objective, the effect of a is different from that of ?. The T-shaped fin with minimum equivalent thermal resistance is much taller than that with minimum maximum thermal resistance; for either optimization objective, the stem of fin is thicker than the branches of fin, and the stem thickness is relatively close to branch thickness when the minimization of equivalent thermal resistance is taken as the optimization objective. The T-shaped fin with flat stem and slender branches can benefit the reduction of the maximum thermal resistance.
基金supported by the National Natural Science Foundation of China(Grant No.51236006)China Postdoctoral Science Foundation(Grant No.2012M521771)
文摘A numerical investigation on the aerodynamic effects of impeller-diffuser axial misalignment in the low-flow-coefficient centrifugal compressor is conducted through three-dimensional CFD analysis.The results show that the flow,especially near the diffuser inlet,is influenced by the axial misalignment obviously.When the impeller offsets to one side,the pressure at diffuser inlet close to this side will descend,and the vortex in the cavity on the other side will partially enter the diffuser and then result in the back flow.The performances of the stage and its components also change with the impeller-diffuser axial misalignment.There exists an optimum offset making the efficiency maximum at a given operating point.Furthermore,the effect of impeller-diffuser axial misalignment on the axial thrust is pronounced.The axial thrust is nearly increased linearly with the increase of axial misalignment.The aerodynamic effects of impeller-diffuser axial misalignment in the low-flow-coefficient centrifugal compressor behaves more remarkably at the large flow rate.To alleviate the aerodynamic effects of impeller-diffuser misalignment,a rounding in the meridional plane at the diffuser inlet can be applied.
基金supported by the National Natural Science Foundation of China(Grant Nos.11932005 and 11772106).
文摘Fracture analysis of a plane crack problem under chemo-mechanical loading is presented based on a linear chemo-elasticity model.The flux conductivity is introduced to characterize the influence of the crack defect on the diffusion process.Using Fourier transform and the dislocation density functions,the crack problem is reduced to a set of singular integral equations,which are solved numerically by the Lobatto-Chebyshev method.Parametric studies are conducted to reveal the effects of flux conductivity,geometric configuration,chemical and mechanical loads on the crack tip field.The numerical results show that the stress singularity at the crack tip is usually a mixture of mode Ⅰ and mode Ⅱ types.
基金supported by the National Natural Science Foundation of China(Grant Nos.11172006,10572004 and 90716008)by the National Basic Research Program of China(Grant No.2009CB724100)
文摘An experimental study of compressible mixing layers(CMLs)was conducted using planar laser Mie scattering(PLMS)visualizations from condensed ethanol droplets in the flow.Large ensembles of digital images were collected for two flow conditions at convective Mach numbers Mc=0.11 and 0.47.The coherent vortices,braids and eruptions in the mixing zone were observed,interpreted as evidence of multi-scale,three-dimensional structures at a high Reynolds number.The mixing layers with a large visualized range present two stages along the streamwise direction,corresponding to the initial mixing and the well-developed stage.A new method,the gray level ensemble average method(GLEAM),by virtue of the similarity of the mixing layer,was applied to measure the growth rate of the CML thickness.New evidence for a nonlinear growth of CML is reported,providing an interpretation of previous observations of the scattering of the growth rate.
文摘This paper aims to look into the determination of effective area-average concentration and dispersion coefficient associated with unsteady flow through a small-diameter tube where a solute undergoes first-order chemical reaction both within the fluid and at the boundary. The reaction consists of a reversible component due to phase exchange between the flowing fluid and the wall layer, and an irreversible component due to absorption into the wall. To understand the dispersion, the governing equations along with the reactive boundary conditions are solved numerically using the Finite Difference Method. The resultant equation shows how the dispersion coefficient is influenced by the first-order chemical reaction. The effects of various dimensionless parameters e.g. Da (the Damkohler number), a (phase partitioning number) and F (dimensionless absorption number) on dispersion are discussed. One of the results exposes that the dispersion coefficient may approach its steady-state limit in a short time at a high value of Damkohler number (say Da 〉 10) and a small but nonzero value of absorption rate (say P 〈0.5).