Based on the analysis of the Boltzmann＇s distribution in an infinitely high temperature found degeneration of the thermodynamic system in a purely informational with independently of each particle on its energy level...Based on the analysis of the Boltzmann＇s distribution in an infinitely high temperature found degeneration of the thermodynamic system in a purely informational with independently of each particle on its energy level, thus providing them full visibility of and the ability to calculate the maximum entropy in the Boltzmann formula S∞ = R·InNA = 455.251 J/（mol.K）. This value, when expressed in terms of fundamental constants, is itself a physical and chemical constants and mole monatomic ideal gas is unsurpassed in any studied temperature range. For complex substances this limit increases in direct proportion to their atomic. The existence of two limits entropy change--lower, equal to zero according to the third law of thermodynamics, and the top, equal to S∞, makes possible the explicit expression of the temperature dependence of the entropy in the form of an exponentialS=S∞exp[-5030.31p 2/5 /（M3/5T）]（5/2）r e/s∞. rather than in the form of a logarithmic dependence of the infinite by the approximateformula Sakura-Tetrode with which this the dependence is almost identical in the studied temperature range （100-10,000 K）, but not absurd negative entropy in the extrapolation formula Sakura-Tetrode absolute zero to the region and especially in the area of T → ∞where it turns S →∞.展开更多
文摘Based on the analysis of the Boltzmann＇s distribution in an infinitely high temperature found degeneration of the thermodynamic system in a purely informational with independently of each particle on its energy level, thus providing them full visibility of and the ability to calculate the maximum entropy in the Boltzmann formula S∞ = R·InNA = 455.251 J/（mol.K）. This value, when expressed in terms of fundamental constants, is itself a physical and chemical constants and mole monatomic ideal gas is unsurpassed in any studied temperature range. For complex substances this limit increases in direct proportion to their atomic. The existence of two limits entropy change--lower, equal to zero according to the third law of thermodynamics, and the top, equal to S∞, makes possible the explicit expression of the temperature dependence of the entropy in the form of an exponentialS=S∞exp[-5030.31p 2/5 /（M3/5T）]（5/2）r e/s∞. rather than in the form of a logarithmic dependence of the infinite by the approximateformula Sakura-Tetrode with which this the dependence is almost identical in the studied temperature range （100-10,000 K）, but not absurd negative entropy in the extrapolation formula Sakura-Tetrode absolute zero to the region and especially in the area of T → ∞where it turns S →∞.
