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含引发机制的A_f—A_g型缩聚反应固化理论—数量分布函数的不变性
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作者 刘广田 王海军 +1 位作者 巴信武 李楠 《胶体与聚合物》 2002年第4期16-19,共4页
讨论了含引发机制的Af-Ag型缩聚反应体系。应用概率分析方法,给出了该体系溶胶-凝胶分 配公式,并证明了该体系数量分布函数具有不变性,从而简化了凝胶点后各种平均高分子物理量的表征.
关键词 引发机制 Af-Ag型 缩聚反应 固化 数量分布函数 不变性 自由基缩聚 溶胶-凝胶分配
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Patchy粒子聚集的统计力学研究 被引量:3
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作者 洪晓钟 顾芳 +1 位作者 李江涛 王海军 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2014年第7期1579-1583,共5页
应用统计力学原理对AaBb型Patchy粒子的聚集过程进行研究,考察了典型平均物理量在聚集过程中的变化情况.首先基于配分函数导出体系的平衡自由能及描述Patchy粒子之间联接作用的质量作用定律,进而获得团簇的数量分布函数.进一步给出Patch... 应用统计力学原理对AaBb型Patchy粒子的聚集过程进行研究,考察了典型平均物理量在聚集过程中的变化情况.首先基于配分函数导出体系的平衡自由能及描述Patchy粒子之间联接作用的质量作用定律,进而获得团簇的数量分布函数.进一步给出Patchy团簇的数均和重均聚合度以及物理凝胶化条件,探讨了凝胶化区域与Patchy粒子数之间的依赖关系.同时给出Patchy团簇生长的微分动力学方程,并进行了相应的Monte Carlo模拟.本文旨在揭示Patchy粒子的内在和外在因素对体系聚集态结构的影响,为实现对Patchy粒子体系的有效调控提供理论依据. 展开更多
关键词 Patchy粒子 数量分布函数 物理凝胶化 MONTE Cado模拟
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含引发机制的A_f-A_g型缩聚反应Z-均回转半径研究 被引量:1
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作者 刘广田 赵敏 +2 位作者 栗明献 王海军 巴信武 《分子科学学报》 CAS CSCD 2001年第3期155-160,共6页
讨论了含引发机制的Af-Ag 型缩聚反应体系Z -均回转半径 .利用枝状高分子成键的统计分析 ,给出组合因子分解公式 ,并得到均方回转半径的表达式 ;进一步结合数量分布函数 ,定义k次高分子半径 ,并给出计算k次高分子回转半径的循环公式 ,... 讨论了含引发机制的Af-Ag 型缩聚反应体系Z -均回转半径 .利用枝状高分子成键的统计分析 ,给出组合因子分解公式 ,并得到均方回转半径的表达式 ;进一步结合数量分布函数 ,定义k次高分子半径 ,并给出计算k次高分子回转半径的循环公式 ,最后得到凝胶点前Z 展开更多
关键词 自由基缩聚 数量分布函数 回转半径 高分子
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支化高分子溶胶-凝胶相变的热力学 被引量:1
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作者 王海军 刘进军 巴信武 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2008年第12期2474-2478,共5页
以典型的Aa-Bb型缩聚反应为例,应用统计力学和热力学的基本原理对反应体系的一些平衡特征进行研究.基于从两种不同角度所构造的正则配分函数,导出反应体系的平衡自由能以及质量作用定律的解析形式,同时指出获得数量分布函数的新方法,并... 以典型的Aa-Bb型缩聚反应为例,应用统计力学和热力学的基本原理对反应体系的一些平衡特征进行研究.基于从两种不同角度所构造的正则配分函数,导出反应体系的平衡自由能以及质量作用定律的解析形式,同时指出获得数量分布函数的新方法,并通过计算反应体系的等温压缩系数从而得到反应体系的凝胶化条件.进一步利用数量分布函数的不变性,给出临界点后溶胶相和凝胶相的平衡自由能,探讨了溶胶-凝胶相变的相关问题. 展开更多
关键词 平衡自由能 质量作用定律 数量分布函数 溶胶-凝胶相变
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A_(a_1)B_(b_1)—A_(a_2)B_(b_2)缩聚反应的分布函数和高分子矩 被引量:2
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作者 巴信武 李泽生 +2 位作者 潘守甫 孙家钟 唐敖庆 《中国科学(B辑)》 CAS CSCD 北大核心 1993年第4期337-341,共5页
本文用概率统计方法,得到了A_(a1)B_(b1)—A_(a2)B_(b2)缩聚反应的分布函数。应用分布函数定义了高分子各类矩。用直接微商法,得到了计算矩的循环公式。解决了用矩表征这类反应的问题。本文也得到了凝胶化条件。
关键词 缩聚反应 数量分布函数 高分子矩
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含内环化与不含内环化固化理论间的对应关系
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作者 黄旭日 肖兴才 +2 位作者 李泽生 孙家鍾 唐敖庆 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1996年第5期812-814,共3页
含内环化与不含内环化固化理论间的对应关系黄旭日,肖兴才,李泽生,孙家,唐敖庆(吉林大学理论化学研究所,长春,130023)关键词内环化,非线性缩聚反应,数量分布函数,高分子矩在研究非线性缩聚反应体系的固化问题时,Fl... 含内环化与不含内环化固化理论间的对应关系黄旭日,肖兴才,李泽生,孙家,唐敖庆(吉林大学理论化学研究所,长春,130023)关键词内环化,非线性缩聚反应,数量分布函数,高分子矩在研究非线性缩聚反应体系的固化问题时,Flory和Stockmayer等[1... 展开更多
关键词 内环化 缩聚反应 数量分布函数 固化理论
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采用铝脱氧后超低碳钢中非金属夹杂物的变化
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作者 Myung - Duk SEO 张怀军 兰岳光 《现代冶金(内蒙古)》 2017年第3期74-80,共7页
为了研究脱氧后非金属夹杂物的行为,提出了以PDF(数量密度函数)为基础的新方法。与采用夹杂物尺寸直方图传统的分析相比,应用PDF可能获得更多有用的信息以了解夹杂物的变化,例如,夹杂物形成的时期以及夹杂物长大的机理。本文研究... 为了研究脱氧后非金属夹杂物的行为,提出了以PDF(数量密度函数)为基础的新方法。与采用夹杂物尺寸直方图传统的分析相比,应用PDF可能获得更多有用的信息以了解夹杂物的变化,例如,夹杂物形成的时期以及夹杂物长大的机理。本文研究了碳含量为20×10^-6的超低碳钢种中氧化铝夹杂物的PDF,在采用锅脱氧后的三个不同时期提取棒状试样,这三个阶段分别为RH工艺脱气结束的试样、浇铸过程中的中间包试样以及凝固后的板坯试样。除了一个污染的试样以外,其它所有试样的PDF均呈现出分形分布。脱氧后,RH真空脱气7—13min接近结束时的分形分布指数为-3.54,与先前的研究报道值相似。相比之下,中间包和板坯的指数分别为-2.76和-2.38。不同的分形分布表达式可归因于熔融钢水流动条件的变化。PDF的应用也提供了熔融钢水异常二次氧化的定量变化。来自参考分布的PDF偏差与熔融钢水再氧化的其它证据相一致,象氮含量的增加和溶解铝的减少。 展开更多
关键词 非金属夹杂物 炼钢 数量分布函数 再氧化
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A New Statistical Tool: Scalar Score Function
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作者 Zdenek Fabian 《Computer Technology and Application》 2011年第2期109-116,共8页
The basic inference function of mathematical statistics, the score function, is a vector function. The author has introduced the scalar score, a scalar inference function, which reflects main features of a continuous ... The basic inference function of mathematical statistics, the score function, is a vector function. The author has introduced the scalar score, a scalar inference function, which reflects main features of a continuous probability distribution and which is simple. Its simplicity makes it possible to introduce new relevant numerical characteristics of continuous distributions. The t-mean and score variance are descriptions of distributions without the drawbacks of the mean and variance, which may not exist even in cases of regular distributions. Their sample counterparts appear to be alternative descriptions of the observed data. The scalar score itself appears to be a new mathematical tool, which could be used in solving traditional statistical problems for models far from the normal one, skewed and heavy-tailed. 展开更多
关键词 STATISTICS inference function data characteristics point estimates heavy tails.
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The CDF and its sensitivity analysis of stochastic structure with stochastic excitation by advanced stratified line sampling 被引量:4
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作者 SONG ShuFang LU ZhenZhou +2 位作者 ZHANG WeiWeiNational Key Laboratory of Aerodynamic Design and Research Northwestern Polytechnical University YE ZhengYin 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2013年第8期1559-1567,共9页
For the stochastic structure with stochastic excitation, an advanced stratified line sampling (SLS) method is presented to obtain the cumulative distribution function (CDF) of the structural response and its sensitivi... For the stochastic structure with stochastic excitation, an advanced stratified line sampling (SLS) method is presented to obtain the cumulative distribution function (CDF) of the structural response and its sensitivity. The advanced stratified line sampling method introduces a set of middle failure subsets firstly. And for each subset, the conventional line sampling can be used to obtain the corresponding value of the response's CDF. At the same time, the sensitivity estimations of each failure subset can also be computed by modifying the important direction and corresponding reliability coefficients. The properties of CDF sensitivity are proved while the performance function is linear with normal random variables. After two simple examples are used to demonstrate the properties of CDF sensitivity and the feasibility of the presented method, the method employed to analyze the CDF and corresponding sensitivity of root bending moment (RBM) responses for the stochastic BAH is wing with gust excitation to a square-edged gust and to a Dryden gust. The results show that the parameters of the second and the fifth order modals exert more influence on the CDF of response than the other ones, and the presented SLS method can more significantly reduce the computational cost compared with Monte Carlo simulation (MCS). 展开更多
关键词 stochastic excitation line sampling cumulative distribution function (CDF) sensitivity analysis root bending moment (RBM) gust response analysis
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MINIMAX INVARIANT ESTIMATOR OF CONTINUOUS DISTRIBUTION FUNCTION UNDER LINEX LOSS
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作者 Jianhui NING Minyu XIE 《Journal of Systems Science & Complexity》 SCIE EI CSCD 2007年第1期119-126,共8页
In this paper we consider the problem of estimation of a continuous distribution function under the LINEX loss function. The best invariant estimator is obtained and proved to be minimax for any sample size n ≥ 1.
关键词 Invariant estimator LINEX loss function non-parametric estimation.
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350 μm map of the Ophiuchus molecular cloud: core mass function
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作者 ZHANG GuoYin LI Di +3 位作者 HYDE Ashley K QIAN Lei LYU HuaLei WU ZhongZu 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2015年第2期114-124,共11页
Stars are born in dense cores of molecular clouds. The core mass function (CMF), which is the mass distribution of dense cores, is important for understanding the stellar initial mass function (IMF). We obtained ... Stars are born in dense cores of molecular clouds. The core mass function (CMF), which is the mass distribution of dense cores, is important for understanding the stellar initial mass function (IMF). We obtained 350μm dust continuum data using the SHARC-II camera at the Caltech Submillimeter Observatory (CSO) telescope. A 350μm map covering 0.25 deg2 of the Ophiuchus molecular cloud was created by mosaicing 56 separate scans. The CSO telescope had an angular resolution of 9", corresponding to 1.2 ×103 AU at the distance of the Ophiuchus molecular cloud (131 pc). The data was reduced using the Comprehensive Reduction Utility for SHARC-II (CRUSH). The flux density map was analyzed using the GaussClumps algorithm, within which 75 cores has been identified. We used the Spitzer c2d catalogs to separate the cores into 63 starless cores and 12 protostellar cores. By locating Jeans instabilities, 55 prestellar cores (a subcategory of starless cores) were also identified. The excitation temperatures, which were derived from FCRAO 12CO data, help to improve the accuracy of the masses of the cores. We adopted a Monte Carlo approach to analyze the CMF with two types of functional forms; power law and log-normal. The whole and prestellar CMF are both well fitted by a log-normal distribution, with p = -1. 18 ±0.10, σ = 0.58 ± 0.05 and μ= 1.40 + 0.10, σ= 0.50 + 0.05 respectively. This finding suggests that turbulence influences the evolution of the Ophiuchus molecular cloud. 展开更多
关键词 1SM molecular clouds OPHIUCHUS CMF
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Asymptotic properties of plug-in level set estimators for right censored data
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作者 WANG YangFeng YANG Ying 《Science China Mathematics》 SCIE 2014年第6期1257-1274,共18页
We assume T1,..., Tn are i.i.d. data sampled from distribution function F with density function f and C1,...,Cn are i.i.d. data sampled from distribution function G. Observed data consists of pairs (Xi, δi), em= 1,... We assume T1,..., Tn are i.i.d. data sampled from distribution function F with density function f and C1,...,Cn are i.i.d. data sampled from distribution function G. Observed data consists of pairs (Xi, δi), em= 1,..., n, where Xi = min{Ti,Ci}, δi = I(Ti 6 Ci), I(A) denotes the indicator function of the set A. Based on the right censored data {Xi, δi}, em=1,..., n, we consider the problem of estimating the level set {f 〉 c} of an unknown one-dimensional density function f and study the asymptotic behavior of the plug-in level set estimators. Under some regularity conditions, we establish the asymptotic normality and the exact convergence rate of the λg-measure of the symmetric difference between the level set {f ≥ c} and its plug-in estimator {fn ≥ c}, where f is the density function of F, and fn is a kernel-type density estimator of f. Simulation studies demonstrate that the proposed method is feasible. Illustration with a real data example is also provided. 展开更多
关键词 level set asymptotic normality highest density region convergence rate right censored data
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