A facile and efficient method has been developed for microencapsulation of metal oxide nanoparticles in polyurea via interfacial polymerization of toluene-2,4-diisocyanate and H20 through the atomizing emulsification ...A facile and efficient method has been developed for microencapsulation of metal oxide nanoparticles in polyurea via interfacial polymerization of toluene-2,4-diisocyanate and H20 through the atomizing emulsification approach. The resultant microcapsules were well-shaped and uniform sphere with diameter ranging from 2 to 6 um. Thermogravimetry （TG） and differential scanning calorimetry （DSC） curves revealed that the microcapsules showed good thermal stability （no decomposition observed under 245℃）. Besides, the microencapsulated TiC2 has been used as an efficient catalyst for photocatalytic degradation of methyl orange. Furthermore, the photocatalysis of immobilized TiC2 could be enhanced by introducing UV absorbing agent to the wall of microcapsules.展开更多
An optimal method for prediction and adjustment on byproduct gasholder level and self-provided power plant gas supply was proposed.This work raises the HP-ENN-LSSVM model based on the Hodrick-Prescott filter,Elman neu...An optimal method for prediction and adjustment on byproduct gasholder level and self-provided power plant gas supply was proposed.This work raises the HP-ENN-LSSVM model based on the Hodrick-Prescott filter,Elman neural network and least squares support vector machines.Then,according to the prediction,the optimal adjustment process came up by a novel reasoning method to sustain the gasholder within safety zone and the self-provided power plant boilers in economic operation,and prevent unfavorable byproduct gas emission and equipment trip as well.The experiments using the practical production data show that the proposed method achieves high accurate predictions and the optimal byproduct gas distribution,which provides a remarkable guidance for reasonable scheduling of byproduct gas.展开更多
基金Supported by the National Natural Science Foundation of China （20576045） and the Program for New Century Excellent Talents in University （NCET-06-740）.
文摘A facile and efficient method has been developed for microencapsulation of metal oxide nanoparticles in polyurea via interfacial polymerization of toluene-2,4-diisocyanate and H20 through the atomizing emulsification approach. The resultant microcapsules were well-shaped and uniform sphere with diameter ranging from 2 to 6 um. Thermogravimetry （TG） and differential scanning calorimetry （DSC） curves revealed that the microcapsules showed good thermal stability （no decomposition observed under 245℃）. Besides, the microencapsulated TiC2 has been used as an efficient catalyst for photocatalytic degradation of methyl orange. Furthermore, the photocatalysis of immobilized TiC2 could be enhanced by introducing UV absorbing agent to the wall of microcapsules.
基金Project(51066002/E060701) supported by the National Natural Science Foundation of ChinaProject(U0937604) supported by the NSFC-Yunnan Joint Fund of China
文摘An optimal method for prediction and adjustment on byproduct gasholder level and self-provided power plant gas supply was proposed.This work raises the HP-ENN-LSSVM model based on the Hodrick-Prescott filter,Elman neural network and least squares support vector machines.Then,according to the prediction,the optimal adjustment process came up by a novel reasoning method to sustain the gasholder within safety zone and the self-provided power plant boilers in economic operation,and prevent unfavorable byproduct gas emission and equipment trip as well.The experiments using the practical production data show that the proposed method achieves high accurate predictions and the optimal byproduct gas distribution,which provides a remarkable guidance for reasonable scheduling of byproduct gas.
