The analysis on the feedstock pyrolysis characteristic and the impacts of process parameters on pyrolysis outcomes can assist in the designing,operating and optimizing pyrolysis processes.This work aims to utilize bot...The analysis on the feedstock pyrolysis characteristic and the impacts of process parameters on pyrolysis outcomes can assist in the designing,operating and optimizing pyrolysis processes.This work aims to utilize both experimental and modelling approaches to perform the analysis on three biomass feedstocks—wood sawdust,bamboo shred and Jatropha Curcas seed cake residue,and to provide insights for the design and operation of pyrolysis processes.For the experimental part,the study investigated the effect of heating rate,final pyrolysis temperature and sample size on pyrolysis using common thermal analysis techniques.For the modelling part,a transient mathematical model that integrates the feedstock characteristic from the experimental study was used to simulate the pyrolysis progress of selected biomass feedstock particles for reactor scenarios.The model composes of several sub-models that describe pyrolysis kinetic and heat flow,particle heat transfer,particle shrinking and reactor operation.With better understanding of the effects of process conditions and feedstock characteristics on pyrolysis through both experimental and modelling studies,this work discusses on the considerations of and interrelation between feedstock size,pyrolysis energy usage,processing time and product quality for the design and operation of pyrolysis processes.展开更多
Hardfill is a new type of artificially cemented material for dam construction works,with a wide application prospect.Its mechanical behavior lies between concrete and rockfill materials.A series of large-scale triaxia...Hardfill is a new type of artificially cemented material for dam construction works,with a wide application prospect.Its mechanical behavior lies between concrete and rockfill materials.A series of large-scale triaxial tests are performed on hardfill specimens at different ages,and the stress-strain behavior of hardfill is further discussed.The strength and stress-strain relationship of hardfill materials show both frictional mechanism and cohesive mechanism.An age-related constitutive model of hardfill is developed,which is a parallel model consisting of two components,rockfill component and cementation component.Moreover,a comparison is made between the simulated and the experimental results,which shows that the parallel model can reflect the mechanical characteristics of both rockfill-like nonlinearity and concrete-like age relativity.In addition,a simplified method for the determination of parameters is proposed.展开更多
Particle breakage has a significant influence on the stress-strain and strength behavior of rockfill material.A breakage critical state theory(BCST)was proposed to describe the evolution of particle breakage.The break...Particle breakage has a significant influence on the stress-strain and strength behavior of rockfill material.A breakage critical state theory(BCST)was proposed to describe the evolution of particle breakage.The breakage critical state line in the breakage critical state theory was correlated with the breakage factor,which was fundamentally different from that of the original critical state theory.A simple elastoplastic constitutive model was developed for rockfill in the frame of BCST.An associated flow rule was adopted in this model.Isotropic,contractive and distortional hardening rules were suggested in view of the particle breakage.It was observed that the proposed model could well represent the complex deformation behaviors of rockfill material,such as the strain hardening,post-peak strain softening,volumetric contraction,volumetric expansion,and particle breakage under different initial confining pressures.展开更多
A bounding surface model incorporating a unified nonlinear strength criterion is proposed.The proposed bounding surface model contains 9 model parameters,which can be determined from the conventional triaxial tests.Th...A bounding surface model incorporating a unified nonlinear strength criterion is proposed.The proposed bounding surface model contains 9 model parameters,which can be determined from the conventional triaxial tests.The bounding surface model can reproduce such behaviours as the strain hardening,the post-peak strain softening,and the volumetric strain contraction and expansion.Based on the comparisons between the predictions and the test results,the proposed strength criterion and model can well reproduce the experimental results of the strength and stress-strain behaviours of rockfill material in three-dimensional stress space.The strength behaviour of rockfill material is summarized as:(a) the failure stress ratio decreases with the initial confining pressure on the meridian plane;(b) the failure deviatoric stress decreases with the Lode angle from 0o to 60o on the deviatoric plane.The stress ratio decreases with increasing one of such factors as the initial void ratio,the intermediate principal stress ratio and the minor principal stress at the same strain when the other factors are given.展开更多
Discrete element simulations of one-dimensional compression of breakable granular assemblies were performed to investigate the capability of the exponential compression equation suggested by Bauer.The relationship bet...Discrete element simulations of one-dimensional compression of breakable granular assemblies were performed to investigate the capability of the exponential compression equation suggested by Bauer.The relationship between the so-called solid hardness and the particle strength was studied so as to provide a physical background for the introduction of a time-dependent solid hardness.A hyperbolic flow rule,describing the relationship between the inclination of the strain path and the stress ratio during wetting,was proposed based on typical triaxial wetting experiments on two different rockfill materials.The flow rule was then extended and incorporated into the transformed stress based hypoplastic model to capture the direction of creep strains.Meanwhile,a new density factor was introduced to the extended model to take into account the dependence of the magnitude of creep strains on the packing density.The stiffness tensor given by the extended model was discussed and the flowchart for the integration of the constitutive equation was designed.The extended model was then embedded into a finite element program and used to simulate the triaxial compression and wetting experiments performed on the aforementioned rockfill materials.Good agreement between the model predictions and the measured results lends sufficient credibility to the extended model in reproducing the stress-stain behaviour under loading and the creep behaviour during wetting.The extended model and the finite element program were also used to investigate the deformation behaviour of an earth-rock dam at the end of construction and during first impounding.The familiar phenomena such as the wetting induced settlement of the upstream shell and the movement of the dam crest towards the upstream were successfully captured by the numerical model,which confirms the feasibility of applying the extended model to dam engineering in the future.展开更多
A 3D bounding surface model is established for rockfill materials,which can be applied to appropriately predict the deformation and the stabilization of rockfill dams.Firstly,an associated plastic flow rule for rockfi...A 3D bounding surface model is established for rockfill materials,which can be applied to appropriately predict the deformation and the stabilization of rockfill dams.Firstly,an associated plastic flow rule for rockfill materials is investigated based on the elaborate data from the large-style triaxial compression tests and the true triaxial tests.Secondly,the constitutive equations of the 3D bounding surface model are established by several steps.These steps include the bounding surface incorporating the general nonlinear strength criterion,stress-dilatancy equations,the evolution of the bounding surface and the bounding surface plasticity.Finally,the 3D bounding surface model is used to predict the mechanical behaviors of rockfill materials from the large-style triaxial compression tests and the true triaxial tests.Consequently,the proposed 3D bounding surface model can well capture such behaviors of rockfill materials as the strain hardening,the post-peak strain softening,and the volumetric strain contraction and expansion in both two-and three-dimensional stress spaces.展开更多
The particle breakage during specimen compaction had more significant influence on the position of the breakage critical-state line(BCSL)of Tacheng rockfill material(TRM)in the e-lnp’plane than the particle breakage ...The particle breakage during specimen compaction had more significant influence on the position of the breakage critical-state line(BCSL)of Tacheng rockfill material(TRM)in the e-lnp’plane than the particle breakage during shearing,based on the large-scale triaxial compression tests on TRM in a wide range of densities and pressures.The state-dependent dilatancy and the plastic modulus were correlated to the breakage index,based on the formulations of the BCSL of TRM in the e-lnp’plane.The state-dependent model considering particle breakage was proposed for TRM within the framework of the generalized plasticity theory.The proposed model contained fourteen material constants.The test data of TRM from Group A were adopted to determine these material constants,while the test data from Group B were used independently to validate the model predictive capacity.The comparisons between model simulations and test data illustrated that the model with consideration of particle breakage could well represent the stress-strain behaviors of TRM,e.g.,the strain hardening and volumetric contraction behaviors at a loose state and the strain softening and volumetric expansion behaviors at a dense state,and also the particle breakage behaviors of TRM.展开更多
基金Supported by Hong Kong RGC research grant(613808,614307)Hong Kong PhD Fellowship Scheme for Oyedun Adetoyese Olajire(PF09-05997)the Global Power and Energy Company Limited
文摘The analysis on the feedstock pyrolysis characteristic and the impacts of process parameters on pyrolysis outcomes can assist in the designing,operating and optimizing pyrolysis processes.This work aims to utilize both experimental and modelling approaches to perform the analysis on three biomass feedstocks—wood sawdust,bamboo shred and Jatropha Curcas seed cake residue,and to provide insights for the design and operation of pyrolysis processes.For the experimental part,the study investigated the effect of heating rate,final pyrolysis temperature and sample size on pyrolysis using common thermal analysis techniques.For the modelling part,a transient mathematical model that integrates the feedstock characteristic from the experimental study was used to simulate the pyrolysis progress of selected biomass feedstock particles for reactor scenarios.The model composes of several sub-models that describe pyrolysis kinetic and heat flow,particle heat transfer,particle shrinking and reactor operation.With better understanding of the effects of process conditions and feedstock characteristics on pyrolysis through both experimental and modelling studies,this work discusses on the considerations of and interrelation between feedstock size,pyrolysis energy usage,processing time and product quality for the design and operation of pyrolysis processes.
基金supported partially by the National Natural Science Foundation of China (Grant No. 10932012)the China-Europe Science and Technology Cooperation Program (Grant No. 0820)European Commission (Grant No. FP7-NMP-2007-LARGE-1)
文摘Hardfill is a new type of artificially cemented material for dam construction works,with a wide application prospect.Its mechanical behavior lies between concrete and rockfill materials.A series of large-scale triaxial tests are performed on hardfill specimens at different ages,and the stress-strain behavior of hardfill is further discussed.The strength and stress-strain relationship of hardfill materials show both frictional mechanism and cohesive mechanism.An age-related constitutive model of hardfill is developed,which is a parallel model consisting of two components,rockfill component and cementation component.Moreover,a comparison is made between the simulated and the experimental results,which shows that the parallel model can reflect the mechanical characteristics of both rockfill-like nonlinearity and concrete-like age relativity.In addition,a simplified method for the determination of parameters is proposed.
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.106112015CDJXY200008)China Scholarship Council(Grant No.201306710022)
文摘Particle breakage has a significant influence on the stress-strain and strength behavior of rockfill material.A breakage critical state theory(BCST)was proposed to describe the evolution of particle breakage.The breakage critical state line in the breakage critical state theory was correlated with the breakage factor,which was fundamentally different from that of the original critical state theory.A simple elastoplastic constitutive model was developed for rockfill in the frame of BCST.An associated flow rule was adopted in this model.Isotropic,contractive and distortional hardening rules were suggested in view of the particle breakage.It was observed that the proposed model could well represent the complex deformation behaviors of rockfill material,such as the strain hardening,post-peak strain softening,volumetric contraction,volumetric expansion,and particle breakage under different initial confining pressures.
基金supported by the National Natural Science Foundation of China for Distinguished Young Scholar (Grant No. 50825901)the Public Service Sector R&D Project of Ministry of Water Resource of China(Grant No. 200801014)+1 种基金the Fundamental Research Funds for the Central Universities (Grant No. 2011B14514)Jiangsu Civil Engineering Graduate Center for Innovation and Academic Communication Foundation
文摘A bounding surface model incorporating a unified nonlinear strength criterion is proposed.The proposed bounding surface model contains 9 model parameters,which can be determined from the conventional triaxial tests.The bounding surface model can reproduce such behaviours as the strain hardening,the post-peak strain softening,and the volumetric strain contraction and expansion.Based on the comparisons between the predictions and the test results,the proposed strength criterion and model can well reproduce the experimental results of the strength and stress-strain behaviours of rockfill material in three-dimensional stress space.The strength behaviour of rockfill material is summarized as:(a) the failure stress ratio decreases with the initial confining pressure on the meridian plane;(b) the failure deviatoric stress decreases with the Lode angle from 0o to 60o on the deviatoric plane.The stress ratio decreases with increasing one of such factors as the initial void ratio,the intermediate principal stress ratio and the minor principal stress at the same strain when the other factors are given.
基金supported by the National Natural Science Foundation of China (Grant Nos. 51179059,90815024)the Fund for Young Scientists in Nanjing Hydraulic Research Institute (Grant No. Y312004)
文摘Discrete element simulations of one-dimensional compression of breakable granular assemblies were performed to investigate the capability of the exponential compression equation suggested by Bauer.The relationship between the so-called solid hardness and the particle strength was studied so as to provide a physical background for the introduction of a time-dependent solid hardness.A hyperbolic flow rule,describing the relationship between the inclination of the strain path and the stress ratio during wetting,was proposed based on typical triaxial wetting experiments on two different rockfill materials.The flow rule was then extended and incorporated into the transformed stress based hypoplastic model to capture the direction of creep strains.Meanwhile,a new density factor was introduced to the extended model to take into account the dependence of the magnitude of creep strains on the packing density.The stiffness tensor given by the extended model was discussed and the flowchart for the integration of the constitutive equation was designed.The extended model was then embedded into a finite element program and used to simulate the triaxial compression and wetting experiments performed on the aforementioned rockfill materials.Good agreement between the model predictions and the measured results lends sufficient credibility to the extended model in reproducing the stress-stain behaviour under loading and the creep behaviour during wetting.The extended model and the finite element program were also used to investigate the deformation behaviour of an earth-rock dam at the end of construction and during first impounding.The familiar phenomena such as the wetting induced settlement of the upstream shell and the movement of the dam crest towards the upstream were successfully captured by the numerical model,which confirms the feasibility of applying the extended model to dam engineering in the future.
基金supported by the National Natural Science Foundation for Distinguished Young Scholar (Grant No. 50825901)the Key Project of National Natural Science Foundation of China and Yalongjiang Hydro-electric Development Joint Research Fund (Grant No. 50639050)+2 种基金the Public Service Sector R&D Project of Ministry of Water Resource of China(Grant No. 200801014)the Fundamental Research Funds for the Central Universities (Grant No. 2010B15014)Scientific Innovation Research Scheme for Jiangsu University Graduate (Grant No. CX10B_207Z)
文摘A 3D bounding surface model is established for rockfill materials,which can be applied to appropriately predict the deformation and the stabilization of rockfill dams.Firstly,an associated plastic flow rule for rockfill materials is investigated based on the elaborate data from the large-style triaxial compression tests and the true triaxial tests.Secondly,the constitutive equations of the 3D bounding surface model are established by several steps.These steps include the bounding surface incorporating the general nonlinear strength criterion,stress-dilatancy equations,the evolution of the bounding surface and the bounding surface plasticity.Finally,the 3D bounding surface model is used to predict the mechanical behaviors of rockfill materials from the large-style triaxial compression tests and the true triaxial tests.Consequently,the proposed 3D bounding surface model can well capture such behaviors of rockfill materials as the strain hardening,the post-peak strain softening,and the volumetric strain contraction and expansion in both two-and three-dimensional stress spaces.
基金supported by the National Natural Science Foundation for Distinguished Young Scholar(Grant No.50825901)the 111 Project(Grant No.B13024)+2 种基金the Program for Changjiang Scholars and Innovative Research Team in University(Grant No.IRT1125)the Project supported by the National Natural Science Foundation of China(Grant No.51379067)the Fundamental Research Funds for the Central Universities(Grant No.2011B14514)
文摘The particle breakage during specimen compaction had more significant influence on the position of the breakage critical-state line(BCSL)of Tacheng rockfill material(TRM)in the e-lnp’plane than the particle breakage during shearing,based on the large-scale triaxial compression tests on TRM in a wide range of densities and pressures.The state-dependent dilatancy and the plastic modulus were correlated to the breakage index,based on the formulations of the BCSL of TRM in the e-lnp’plane.The state-dependent model considering particle breakage was proposed for TRM within the framework of the generalized plasticity theory.The proposed model contained fourteen material constants.The test data of TRM from Group A were adopted to determine these material constants,while the test data from Group B were used independently to validate the model predictive capacity.The comparisons between model simulations and test data illustrated that the model with consideration of particle breakage could well represent the stress-strain behaviors of TRM,e.g.,the strain hardening and volumetric contraction behaviors at a loose state and the strain softening and volumetric expansion behaviors at a dense state,and also the particle breakage behaviors of TRM.