The concept and research progress of functional feed were summarized. Compared with the basic nutrition, functional feed is a kind of new health care feed which contains functional ingredients, and can promote the gro...The concept and research progress of functional feed were summarized. Compared with the basic nutrition, functional feed is a kind of new health care feed which contains functional ingredients, and can promote the growth of animal health, enhance immunity, improve the quality of animal products, improve the level of ani- mal welfare, reduce environmental pollution, improve the ecological environment, as well as increase the economic benefits. Studies on the functional feed are mainly concentrated in the development of functional feed products, and but few to under- stand the compositions and compatibility mechanism of the functional components that have the function effects. Moreover, these functional components are low in plants, so the wide application in feed industry requires research on biological engi- neering and chemical synthesis, which will become the trend of future research.展开更多
Two anode catalysts with Pt, MoS2 and composite metal sulfides (MoS2+NiS), are investigated for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cell (SOFC) at temperatures 750-850℃. The catalysts co...Two anode catalysts with Pt, MoS2 and composite metal sulfides (MoS2+NiS), are investigated for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cell (SOFC) at temperatures 750-850℃. The catalysts comprising MoS2 and MoSa+NiS exhibited good electrical conductivity and catalytic activity. MoS2 and composite catalysts were found to be more active than Pt, a widely used catalyst for high temperature H2S/O2 fuel cell at 750-850℃. However, MoS2 itself sublimes above 450℃. In contrast, composite catalysts containing both Mo and transition metal (Ni) are shown to be stable and effective in promoting the oxidation of H2S in SOFC up to 850℃. However, electric contact is poor between the platinum current collecting layer and the composite metal sulfide layer, so that the cell performance becomes worse. This problem is overcome by adding conductive Ag powder into the anode layer (forming MoS2+NiS+Ag anode material) to increase anode electrical conductance instead of applying a thin layer of platinum on the top of anode.展开更多
Based on a method combined artificial neural network (ANN) with particle swarm optimization (PSO) algorithm, the thermo-mechanical fatigue reliability of plastic ball grid array (PBGA) solder joints was studied. The s...Based on a method combined artificial neural network (ANN) with particle swarm optimization (PSO) algorithm, the thermo-mechanical fatigue reliability of plastic ball grid array (PBGA) solder joints was studied. The simulation experiments of accelerated thermal cycling test were performed by ANSYS software. Based on orthogonal array experiments, a back-propagation artificial neural network (BPNN) was used to establish the nonlinear multivariate relationship between thermo-mechanical fatigue reliability and control factors. Then, PSO was applied to obtaining the optimal levels of control factors by using the output of BPNN as the affinity measure. The results show that the control factors, such as print circuit board (PCB) size, PCB thickness, substrate size, substrate thickness, PCB coefficient of thermal expansion (CTE), substrate CTE, silicon die CTE, and solder joint CTE, have a great influence on thermo-mechanical fatigue reliability of PBGA solder joints. The ratio of signal to noise of ANN-PSO method is 51.77 dB and its error is 33.3% less than that of Taguchi method. Moreover, the running time of ANN-PSO method is only 2% of that of the BPNN. These conclusions are verified by the confirmative experiments.展开更多
The electrochemical behavior of metallic passive film on rebar in concrete is characterized by its semiconductive nature. The charge distribution at the interface between a semiconductor and an electrolyte is often de...The electrochemical behavior of metallic passive film on rebar in concrete is characterized by its semiconductive nature. The charge distribution at the interface between a semiconductor and an electrolyte is often determined by measuring the capacitance of the space-charge layer (Csc) as a function of the electrode potential (E). When the space charge-layer serves as the depletion layer, the relation of Csc^-2 vs E resembles a Mott-Schottky plot (M-S plot). The semiconductive properties of the passive film on rebar in concrete were analyzed with M-S plots to study the effect of chloride ions and mineral admixtures on rebar passive films. Some rebar electrodes were immersed in simulated concrete pore solutions, while others were embedded in concrete with/without mineral admixtures. In saturated Ca(OH), solutions, the relation of Csc^-2-E of rebar electrodes shows linear MottSchottky relationship indicating that the passive film on rebar is a highly disordered n-type semiconductor, with donor density (ND) in the order of 10^26m^-3. After adding chloride ions (Cl wt%〈0.2%) in system solutions, the M-S plot slopes significantly decreased and ND increased, suggesting that chloride ion will cause passive film corrosion and breakdown. The M-S plots of the passive film on rebar electrodes embedded in concrete were similar to those immersed in simulated system solution. However, ND of those in concrete with mineral admixtures tended to be a little smaller, indicating that introducing proper quantity admixtures into concrete could make the rebar passive film have a thicker space-charge layer and therefore a thicker passive film layer.展开更多
The properties of the warp knitted spacer fabrics for pressure reduction are experimentally investigated and compared to other materials.The influences of the different parameters, such as thickness, spacer yarn diame...The properties of the warp knitted spacer fabrics for pressure reduction are experimentally investigated and compared to other materials.The influences of the different parameters, such as thickness, spacer yarn diameter and connecting form are also analyzed and discussed. The results have shown that the spacer fabrics have very good properties for pressure reduction when they are used as soles, mattress or cushions.展开更多
A numerical model is presented to investigate the performance of homogeneous charge compression ignition(HCCI) engines fueled with ethanol. Two approaches are studied. On one hand, two-step reaction mechanisms with Ar...A numerical model is presented to investigate the performance of homogeneous charge compression ignition(HCCI) engines fueled with ethanol. Two approaches are studied. On one hand, two-step reaction mechanisms with Arrhenius reaction rates are implemented in combustion chemistry modeling. On the other hand, a reduced mechanism containing important reactions of ethanol involving heat release rate and reaction rates compatible with experimental data is employed. Since controls of combustion phenomenon and ignition timing are the main issues of these engines, the effects of inlet temperature and equivalence ratio as the controlling factors on the operating parameters such as ignition timing, burn duration, in-cylinder temperature and pressure of HCCI engines are explored. The results show that the maximum predicted pressures for thermodynamic model are about 71.3×10~5 Pa and 79.79×10~5 Pa, and for chemical kinetic model, they are about 71.48×10~5 Pa and 78.123×10~5 Pa, fairly comparable with corresponding experimental values of 72×10~5 Pa and 78.7×10~5 Pa. It is observed that increasing the initial temperature advances the ignition timing, decreases the burn duration and increases the peak temperature and pressure. Moreover, the maximum temperature and pressure are associated with richer mixtures.展开更多
The exciting outcomes of national regional trials have led to production and industrialization of China oilseed rape to a larger extent. To understand current trends of yield and quality traits of new varieties, data ...The exciting outcomes of national regional trials have led to production and industrialization of China oilseed rape to a larger extent. To understand current trends of yield and quality traits of new varieties, data of national winter oilseed rape trials from 2001 to 2015 in 4 districts (upper, middle, lower Yangtze River and Huang-Huai River) was comprehensively analyzed. Results showed that average yield of new varieties of winter oilseed rape increased during the study period. In 2013, average yield of each district reached its highest level. Number of pod per plant reached its peak in 2011 and then declined rapidly in the next 4 years. Average number of seeds per pod did not signif-cantly changed in any districts. Moreover, 1,000 seeds weight increased most obviously in Huang-Huai River district. After 2007, new oilseed rape varieties encountered the dou-ble-low quality (i.e., low erucic acid and low glucosinolate). In addition, oil content of new oilseed rape varieties increased over 15 years period and average oil content of all tested varieties during 2006-2015 was 42.96%, which was 2.38% higher than in 2005. Future breeding goals should be set to further improve yield, oil content, oil quality (such as high oleic acid and low saturated fatty acids), achieve full mechanization of oilseed rape pro-duction process and develop ideotypes.展开更多
Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promisi...Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promising low-carbon alternative to traditional Portland cement-based concrete(OPC).GPC-bonded reinforcing bars offer a promising alternative for concrete structures,boasting excellent geopolymer binder/reinforcement bonding and superior corrosion and high-temperature resistance compared to Portland cement.However,due to differences in the production process of GPC,there are distinct engineering property variations,including bonding characteristics.This literature review provides an examination of the manufacturing procedures of GPC,encompassing source materials,mix design,curing regimes,and other factors directly influencing concrete properties.Additionally,it delves into the bond mechanism,bond tests,and corresponding results that represent the bond characteristics.The main conclusions are that GPC generally has superior mechanical properties and bond performance compared to ordinary Portland cement concrete(OPC).However,proper standardization is needed for its production and performance tests to limit the contradictory results in the lab and on site.展开更多
High-entropy ceramics (HECs) have attracted much attention due to their huge composition space,unique microstructure,and desirable properties.In contrast to previous studies,which have primarily focused on HECs with o...High-entropy ceramics (HECs) have attracted much attention due to their huge composition space,unique microstructure,and desirable properties.In contrast to previous studies,which have primarily focused on HECs with one anion,herein,we report a new family of ceramics with both multi-cationic and-anionic structures,i.e.,high-entropy carbide-nitrides (Ti0.33Zr0.33Hf0.33)(C0.5N0.5),(Ti0.25Zr0.25Hf0.25-Nb0.25)(C0.5N0.5) and (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)(C0.5N0.5).These as-synthesized HECs are mainly comprised of a face-centered cubic solid-solution phase accompanied by minor inevitable oxide phases.The formation mechanism of the solid-solution phase is discussed in terms of the lattice size difference and thermodynamic competition between configurational entropy and mixing enthalpy.It is found that the increment in the configurational entropy can effectively lower the sintering temperature and increase the fracture toughness.Particularly,the newly developed (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)(C0.5N0.5) exhibits a decent fracture toughness of 8.4 MPa m1/2and a low sintering temperature of 1750°C,making it promising for ultra-high temperature applications.Our work not only enriches knowledge regarding the HECs categories,but also opens a new pathway for developing HECs with multi-cationic and-anionic structures.展开更多
Titanium alloys have been used extensively in industry fields including aviation,aerospace and automobile due to their excellent comprehensive properties.Research and development of advanced plastic forming technology...Titanium alloys have been used extensively in industry fields including aviation,aerospace and automobile due to their excellent comprehensive properties.Research and development of advanced plastic forming technology are of great importance to manufacturing titanium products of high performance and lightweight with low cost and short cycle.This paper analyzes the development tendencies of titanium alloy forming technology.Recent achievements in precision forming,microstructure control and multi-scale simulation of titanium alloys are reviewed.The forming techniques of large-sale integral complex components are presented.展开更多
基金Supported by the Action Planning Project of the Service Businesses of Scientific Research Institutions in Guizhou Province(Qiankehe[2016]5713)(2016-2019)~~
文摘The concept and research progress of functional feed were summarized. Compared with the basic nutrition, functional feed is a kind of new health care feed which contains functional ingredients, and can promote the growth of animal health, enhance immunity, improve the quality of animal products, improve the level of ani- mal welfare, reduce environmental pollution, improve the ecological environment, as well as increase the economic benefits. Studies on the functional feed are mainly concentrated in the development of functional feed products, and but few to under- stand the compositions and compatibility mechanism of the functional components that have the function effects. Moreover, these functional components are low in plants, so the wide application in feed industry requires research on biological engi- neering and chemical synthesis, which will become the trend of future research.
文摘Two anode catalysts with Pt, MoS2 and composite metal sulfides (MoS2+NiS), are investigated for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cell (SOFC) at temperatures 750-850℃. The catalysts comprising MoS2 and MoSa+NiS exhibited good electrical conductivity and catalytic activity. MoS2 and composite catalysts were found to be more active than Pt, a widely used catalyst for high temperature H2S/O2 fuel cell at 750-850℃. However, MoS2 itself sublimes above 450℃. In contrast, composite catalysts containing both Mo and transition metal (Ni) are shown to be stable and effective in promoting the oxidation of H2S in SOFC up to 850℃. However, electric contact is poor between the platinum current collecting layer and the composite metal sulfide layer, so that the cell performance becomes worse. This problem is overcome by adding conductive Ag powder into the anode layer (forming MoS2+NiS+Ag anode material) to increase anode electrical conductance instead of applying a thin layer of platinum on the top of anode.
基金Project(60371046) supported by the National Natural Science Foundation of ChinaProject(9140C0301060C03001) supported by the National Defense Science and Technology Foundation of Key Laboratory, China
文摘Based on a method combined artificial neural network (ANN) with particle swarm optimization (PSO) algorithm, the thermo-mechanical fatigue reliability of plastic ball grid array (PBGA) solder joints was studied. The simulation experiments of accelerated thermal cycling test were performed by ANSYS software. Based on orthogonal array experiments, a back-propagation artificial neural network (BPNN) was used to establish the nonlinear multivariate relationship between thermo-mechanical fatigue reliability and control factors. Then, PSO was applied to obtaining the optimal levels of control factors by using the output of BPNN as the affinity measure. The results show that the control factors, such as print circuit board (PCB) size, PCB thickness, substrate size, substrate thickness, PCB coefficient of thermal expansion (CTE), substrate CTE, silicon die CTE, and solder joint CTE, have a great influence on thermo-mechanical fatigue reliability of PBGA solder joints. The ratio of signal to noise of ANN-PSO method is 51.77 dB and its error is 33.3% less than that of Taguchi method. Moreover, the running time of ANN-PSO method is only 2% of that of the BPNN. These conclusions are verified by the confirmative experiments.
基金Project (No. 502019) supported by the Natural Science Foundationof Zhejiang Province, China
文摘The electrochemical behavior of metallic passive film on rebar in concrete is characterized by its semiconductive nature. The charge distribution at the interface between a semiconductor and an electrolyte is often determined by measuring the capacitance of the space-charge layer (Csc) as a function of the electrode potential (E). When the space charge-layer serves as the depletion layer, the relation of Csc^-2 vs E resembles a Mott-Schottky plot (M-S plot). The semiconductive properties of the passive film on rebar in concrete were analyzed with M-S plots to study the effect of chloride ions and mineral admixtures on rebar passive films. Some rebar electrodes were immersed in simulated concrete pore solutions, while others were embedded in concrete with/without mineral admixtures. In saturated Ca(OH), solutions, the relation of Csc^-2-E of rebar electrodes shows linear MottSchottky relationship indicating that the passive film on rebar is a highly disordered n-type semiconductor, with donor density (ND) in the order of 10^26m^-3. After adding chloride ions (Cl wt%〈0.2%) in system solutions, the M-S plot slopes significantly decreased and ND increased, suggesting that chloride ion will cause passive film corrosion and breakdown. The M-S plots of the passive film on rebar electrodes embedded in concrete were similar to those immersed in simulated system solution. However, ND of those in concrete with mineral admixtures tended to be a little smaller, indicating that introducing proper quantity admixtures into concrete could make the rebar passive film have a thicker space-charge layer and therefore a thicker passive film layer.
文摘The properties of the warp knitted spacer fabrics for pressure reduction are experimentally investigated and compared to other materials.The influences of the different parameters, such as thickness, spacer yarn diameter and connecting form are also analyzed and discussed. The results have shown that the spacer fabrics have very good properties for pressure reduction when they are used as soles, mattress or cushions.
文摘A numerical model is presented to investigate the performance of homogeneous charge compression ignition(HCCI) engines fueled with ethanol. Two approaches are studied. On one hand, two-step reaction mechanisms with Arrhenius reaction rates are implemented in combustion chemistry modeling. On the other hand, a reduced mechanism containing important reactions of ethanol involving heat release rate and reaction rates compatible with experimental data is employed. Since controls of combustion phenomenon and ignition timing are the main issues of these engines, the effects of inlet temperature and equivalence ratio as the controlling factors on the operating parameters such as ignition timing, burn duration, in-cylinder temperature and pressure of HCCI engines are explored. The results show that the maximum predicted pressures for thermodynamic model are about 71.3×10~5 Pa and 79.79×10~5 Pa, and for chemical kinetic model, they are about 71.48×10~5 Pa and 78.123×10~5 Pa, fairly comparable with corresponding experimental values of 72×10~5 Pa and 78.7×10~5 Pa. It is observed that increasing the initial temperature advances the ignition timing, decreases the burn duration and increases the peak temperature and pressure. Moreover, the maximum temperature and pressure are associated with richer mixtures.
基金supported by National key R&D program(2017 YFD0102000)
文摘The exciting outcomes of national regional trials have led to production and industrialization of China oilseed rape to a larger extent. To understand current trends of yield and quality traits of new varieties, data of national winter oilseed rape trials from 2001 to 2015 in 4 districts (upper, middle, lower Yangtze River and Huang-Huai River) was comprehensively analyzed. Results showed that average yield of new varieties of winter oilseed rape increased during the study period. In 2013, average yield of each district reached its highest level. Number of pod per plant reached its peak in 2011 and then declined rapidly in the next 4 years. Average number of seeds per pod did not signif-cantly changed in any districts. Moreover, 1,000 seeds weight increased most obviously in Huang-Huai River district. After 2007, new oilseed rape varieties encountered the dou-ble-low quality (i.e., low erucic acid and low glucosinolate). In addition, oil content of new oilseed rape varieties increased over 15 years period and average oil content of all tested varieties during 2006-2015 was 42.96%, which was 2.38% higher than in 2005. Future breeding goals should be set to further improve yield, oil content, oil quality (such as high oleic acid and low saturated fatty acids), achieve full mechanization of oilseed rape pro-duction process and develop ideotypes.
基金supported by the ongoing projects provided by the National Key Research and Development Program(2021YFB2600704)the National Natural Science Foundation of China(52108223,U22A20244)+3 种基金the Outstanding Youth Fund of Shandong Province(ZR2021JQ17)the Natural Science Foundation of Shandong Province(ZR2020QE249)the 111 Project(D16006)the First-Class Discipline Project funded by the Education Department of Shandong Province are gratefully acknowledged.
文摘Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promising low-carbon alternative to traditional Portland cement-based concrete(OPC).GPC-bonded reinforcing bars offer a promising alternative for concrete structures,boasting excellent geopolymer binder/reinforcement bonding and superior corrosion and high-temperature resistance compared to Portland cement.However,due to differences in the production process of GPC,there are distinct engineering property variations,including bonding characteristics.This literature review provides an examination of the manufacturing procedures of GPC,encompassing source materials,mix design,curing regimes,and other factors directly influencing concrete properties.Additionally,it delves into the bond mechanism,bond tests,and corresponding results that represent the bond characteristics.The main conclusions are that GPC generally has superior mechanical properties and bond performance compared to ordinary Portland cement concrete(OPC).However,proper standardization is needed for its production and performance tests to limit the contradictory results in the lab and on site.
基金supported by the National Natural Science Foundation of China (51671021,51961160729,1179029,51871016 and 51971017)the Funds for Creative Research Groups of China (51921001)+3 种基金111 Project (B07003)the Program for Changjiang Scholars and Innovative Research Team in University of China (IRT14R05)the Project of SKLAMM-USTB (2019Z-01)the Project supported by the State Key Laboratory of Powder Metallurgy,Central South University,Changsha,China。
文摘High-entropy ceramics (HECs) have attracted much attention due to their huge composition space,unique microstructure,and desirable properties.In contrast to previous studies,which have primarily focused on HECs with one anion,herein,we report a new family of ceramics with both multi-cationic and-anionic structures,i.e.,high-entropy carbide-nitrides (Ti0.33Zr0.33Hf0.33)(C0.5N0.5),(Ti0.25Zr0.25Hf0.25-Nb0.25)(C0.5N0.5) and (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)(C0.5N0.5).These as-synthesized HECs are mainly comprised of a face-centered cubic solid-solution phase accompanied by minor inevitable oxide phases.The formation mechanism of the solid-solution phase is discussed in terms of the lattice size difference and thermodynamic competition between configurational entropy and mixing enthalpy.It is found that the increment in the configurational entropy can effectively lower the sintering temperature and increase the fracture toughness.Particularly,the newly developed (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)(C0.5N0.5) exhibits a decent fracture toughness of 8.4 MPa m1/2and a low sintering temperature of 1750°C,making it promising for ultra-high temperature applications.Our work not only enriches knowledge regarding the HECs categories,but also opens a new pathway for developing HECs with multi-cationic and-anionic structures.
基金supported by the National Natural Science Foundation for Key Program of China(Grant No.50935007)the National Basic Re-search Program of China("973"Program)(Grant No.2010CB731701)the 111 Project(B08040)
文摘Titanium alloys have been used extensively in industry fields including aviation,aerospace and automobile due to their excellent comprehensive properties.Research and development of advanced plastic forming technology are of great importance to manufacturing titanium products of high performance and lightweight with low cost and short cycle.This paper analyzes the development tendencies of titanium alloy forming technology.Recent achievements in precision forming,microstructure control and multi-scale simulation of titanium alloys are reviewed.The forming techniques of large-sale integral complex components are presented.