The effect of two alkylpyridinium ionic liquids (py-iLs) including N-butylpyridinium hydrogen sulfate (BpyHSO4) and N-hexylpyridinium hydrogen sulfate (HpyHSO4) on the kinetics of copper electrodeposition from a...The effect of two alkylpyridinium ionic liquids (py-iLs) including N-butylpyridinium hydrogen sulfate (BpyHSO4) and N-hexylpyridinium hydrogen sulfate (HpyHSO4) on the kinetics of copper electrodeposition from acidic sulfate solution was investigated by cyclic voltammetry and potentiodynamic polarization measurements. Results from cyclic voltammetry indicate that these py-iLs have a pronounced inhibiting effect on CuE+ electroreduction and there exists a typical nucleation and growth process. Kinetic parameters such as Tafel slope, transfer coefficient and exchange current density obtained from Tafel plots, lead to the conclusion that py-iLs inhibit the charge transfer by slightly changing the copper electrodeposition mechanism through their adsorption on the cathodic surface. In addition, scanning electron microscope (SEM) and X-ray diffraction analyses reveal that the presence of these additives leads to more leveled and fine-grained cathodic deposits without changing the crystal structure of the electrodeposited copper but strongly affects the crystallographic orientation by significantly inhibiting the growth of (111), (200) and (311) planes.展开更多
A new algorithm to exploit the learning rates of gradient descent method is presented, based on the second-order Taylor expansion of the error energy function with respect to learning rate, at some values decided by &...A new algorithm to exploit the learning rates of gradient descent method is presented, based on the second-order Taylor expansion of the error energy function with respect to learning rate, at some values decided by "award-punish" strategy. Detailed deduction of the algorithm applied to RBF networks is given. Simulation studies show that this algorithm can increase the rate of convergence and improve the performance of the gradient descent method.展开更多
The indirect boundary element method (IBEM) is used to study three-dimensional scattering of obliquely incident plane SH waves by an alluvial valley embedded in a layered half-space. The free-field response of the l...The indirect boundary element method (IBEM) is used to study three-dimensional scattering of obliquely incident plane SH waves by an alluvial valley embedded in a layered half-space. The free-field response of the layered half-space is calculated by the direct stiffness method, and dynamic Green's functions of moving distributed loads acting on inclined lines in a layered half-space are calculated to simulate the scattering wave field. The presented method yields very accurate results since the three-dimensional dynamic stiffness matrix is exact and the moving distributed loads can act directly on the valley boundary without singularity. Numerical results and analyses are performed for amplification of obliquely incident plane SH waves around an alluvial valley in a uniform half-space and in single layer over half-space. The results show that the three-dimensional responses are distinctly different from the two-dimensional responses, and the displacement amplitudes around alluvial valleys in a uniform haft-space are obviously different from those in a layered half-space.展开更多
Gallium oxide (Ga203) films were deposited on singlecrystalline sapphire (0001) substrate by radio frequency (RF) magnetron sputtering technique in the temperature range of 300--500 ℃. The microstructure of the...Gallium oxide (Ga203) films were deposited on singlecrystalline sapphire (0001) substrate by radio frequency (RF) magnetron sputtering technique in the temperature range of 300--500 ℃. The microstructure of the fl-Ga203 films were investigated in detail using X-ray diffractometer (XRD) and scanning electron microscope (SEM). The results show that the film prepared at 500℃ exhibits the best crystallinity with a monoclinic structure (fl-Ga203). Structure analysis reveals a clear out-of-plane orientation offl-Ga203 (201) II A1203 (0001). The average transmittance of these films in the visible wavelength range exceeds 90%, and the optical band gap of the films varies from 4.68 eV to 4.94 eV which were measured by an ultraviolet-visible-near infrared (UV-vis-NIR) spectrophotometer. Therefore, it is hopeful that the fl-Ga203 film can be used in the UV optoelectronic devices.展开更多
基金Projects(51204080, 51274108) supported by the National Natural Science Foundation of ChinaProject(2011FA009) supported by the Natural Science Foundation of Yunnan Province, ChinaProject(2011FZ020) supported by the Application Research Foundation of Yunnan Province, China
文摘The effect of two alkylpyridinium ionic liquids (py-iLs) including N-butylpyridinium hydrogen sulfate (BpyHSO4) and N-hexylpyridinium hydrogen sulfate (HpyHSO4) on the kinetics of copper electrodeposition from acidic sulfate solution was investigated by cyclic voltammetry and potentiodynamic polarization measurements. Results from cyclic voltammetry indicate that these py-iLs have a pronounced inhibiting effect on CuE+ electroreduction and there exists a typical nucleation and growth process. Kinetic parameters such as Tafel slope, transfer coefficient and exchange current density obtained from Tafel plots, lead to the conclusion that py-iLs inhibit the charge transfer by slightly changing the copper electrodeposition mechanism through their adsorption on the cathodic surface. In addition, scanning electron microscope (SEM) and X-ray diffraction analyses reveal that the presence of these additives leads to more leveled and fine-grained cathodic deposits without changing the crystal structure of the electrodeposited copper but strongly affects the crystallographic orientation by significantly inhibiting the growth of (111), (200) and (311) planes.
基金Open Foundation of State Key Lab of Transmission of Wide-Band FiberTechnologies of Communication Systems
文摘A new algorithm to exploit the learning rates of gradient descent method is presented, based on the second-order Taylor expansion of the error energy function with respect to learning rate, at some values decided by "award-punish" strategy. Detailed deduction of the algorithm applied to RBF networks is given. Simulation studies show that this algorithm can increase the rate of convergence and improve the performance of the gradient descent method.
基金sponsored by Project of Natural Science Foundation of China(50908156,50978183)the Application Basis and Front Technology Research Progamme of Tianjin Municipality under Grant 12JCZDJC29000
文摘The indirect boundary element method (IBEM) is used to study three-dimensional scattering of obliquely incident plane SH waves by an alluvial valley embedded in a layered half-space. The free-field response of the layered half-space is calculated by the direct stiffness method, and dynamic Green's functions of moving distributed loads acting on inclined lines in a layered half-space are calculated to simulate the scattering wave field. The presented method yields very accurate results since the three-dimensional dynamic stiffness matrix is exact and the moving distributed loads can act directly on the valley boundary without singularity. Numerical results and analyses are performed for amplification of obliquely incident plane SH waves around an alluvial valley in a uniform half-space and in single layer over half-space. The results show that the three-dimensional responses are distinctly different from the two-dimensional responses, and the displacement amplitudes around alluvial valleys in a uniform haft-space are obviously different from those in a layered half-space.
基金supported by the National Natural Science Foundation of China(Nos.61274113,61404091,61505144,51502203 and 51502204)the Opening Fund of Key Laboratory of Silicon Device Technology in Chinese Academy of Sciencesthe Tianjin Natural Science Foundation(Nos.14JCZDJC31500 and 14JCQNJC00800)
文摘Gallium oxide (Ga203) films were deposited on singlecrystalline sapphire (0001) substrate by radio frequency (RF) magnetron sputtering technique in the temperature range of 300--500 ℃. The microstructure of the fl-Ga203 films were investigated in detail using X-ray diffractometer (XRD) and scanning electron microscope (SEM). The results show that the film prepared at 500℃ exhibits the best crystallinity with a monoclinic structure (fl-Ga203). Structure analysis reveals a clear out-of-plane orientation offl-Ga203 (201) II A1203 (0001). The average transmittance of these films in the visible wavelength range exceeds 90%, and the optical band gap of the films varies from 4.68 eV to 4.94 eV which were measured by an ultraviolet-visible-near infrared (UV-vis-NIR) spectrophotometer. Therefore, it is hopeful that the fl-Ga203 film can be used in the UV optoelectronic devices.