A series of 2 amino 3 cyano 4 aryl 4H benzochromenes were synehesized by the reaction of malononitrile and 1 naphthol with corresponding aromatic aldehydes in ethanol in the presence of piperidine as catalyst. The str...A series of 2 amino 3 cyano 4 aryl 4H benzochromenes were synehesized by the reaction of malononitrile and 1 naphthol with corresponding aromatic aldehydes in ethanol in the presence of piperidine as catalyst. The structures of all compounds obtained were characterized by elemental analysis, IR, 1H NMR and single crystal X ray diffractometry. X ray crystal structure analysis indicates compound 4b crystallizes in monoclinic, with space group C2/c, a = 2 422 1(6) nm , b = 0 901 6(2) nm , c = 1 700 3(5) nm , β =93 16(1)°, V = 3 707 4(15) nm 3 , Z =8, D c= 1 284 g/cm 3 , I≥2σ(I) =2 141, R = 0 043 2 , wR = 0 108 5 . Compared to other methods, this method has the advantages of simple operation and good yields.展开更多
文摘A series of 2 amino 3 cyano 4 aryl 4H benzochromenes were synehesized by the reaction of malononitrile and 1 naphthol with corresponding aromatic aldehydes in ethanol in the presence of piperidine as catalyst. The structures of all compounds obtained were characterized by elemental analysis, IR, 1H NMR and single crystal X ray diffractometry. X ray crystal structure analysis indicates compound 4b crystallizes in monoclinic, with space group C2/c, a = 2 422 1(6) nm , b = 0 901 6(2) nm , c = 1 700 3(5) nm , β =93 16(1)°, V = 3 707 4(15) nm 3 , Z =8, D c= 1 284 g/cm 3 , I≥2σ(I) =2 141, R = 0 043 2 , wR = 0 108 5 . Compared to other methods, this method has the advantages of simple operation and good yields.
基金The national natural science foundation of China(30572239)The specialized research fund for the doctoralprogram of higher education(20050335045)The foundation of science and technology department of Zhejiang province ofChina(z303835)
