The paper focuses on removing catalyst solids from oil slurry using 10 mm hydrocyclones, and aims to test the feasibility of the solution. An industrial sidetrack tester of residual oil separation by hydrocyclones was...The paper focuses on removing catalyst solids from oil slurry using 10 mm hydrocyclones, and aims to test the feasibility of the solution. An industrial sidetrack tester of residual oil separation by hydrocyclones was set up in 1.8 Mt/a resid fluid catalytic cracking （RFCC） unit, the effect of pressure drop, separation efficiency and inlet flowrate were studied. It was observed that an increase in feed flowrate will decrease the pressure drop ratio, and with an increase in feed flowrate, separation efficiency increases gradually. Under the condition that feed fiowrate was ranging from 250L/h to 270L/h, the separation efficiency was 45.77%-82.80%, the recovery rate of catalyst solid panicles was increased from 10 20% of electrostatic catalyst separator to 50 80%. Thus, it is feasible to separate the slurry by using the miniature hydrocyclones in RFCC unit.展开更多
MXene is a variety of new two-dimensional(2D)materials with early transition metal carbides,nitrides,and carbonitrides.Quantum chemical studies have been carried out on the geometries,electronic structures,stability a...MXene is a variety of new two-dimensional(2D)materials with early transition metal carbides,nitrides,and carbonitrides.Quantum chemical studies have been carried out on the geometries,electronic structures,stability and catalytic properties of a non-noble metal single-atom catalyst(SAC)with single Co atom anchored on MXene materials of Mo_(2)CS_(2).The Co adatom anchored on top of the Mo atom of this MXene is found to be rather stable,and this SAC is appropriate for CO oxidation.The charge transfers from the surface to the adsorbed CO and O2 play a significant role in the activation of these molecules on Co_(1)/Mo_(2)CS_(2).With this catalyst,the Eley-Rideal(ER),Langmuir-Hinshelwood(LH),and Termolecular Eley-Rideal(TER)mechanisms are explored for CO oxidation.We find that,while all the three mechanisms are feasible at low temperature,Co_(1)/Mo_(2)CS_(2) possesses higher catalytic activity for CO oxidation through the TER mechanism that features an intriguing OC(OO)CO intermediate(IM)adsorbed on Co single atom.The calculated activation energy barriers of the rate-limiting step are 0.67 eV(TER),0.78 eV(LH)and 0.88 eV(ER),respectively.The present study illustrates that it is promising to develop and design low-cost,non-noble metal SACs using MXene types of 2D materials.展开更多
文摘The paper focuses on removing catalyst solids from oil slurry using 10 mm hydrocyclones, and aims to test the feasibility of the solution. An industrial sidetrack tester of residual oil separation by hydrocyclones was set up in 1.8 Mt/a resid fluid catalytic cracking （RFCC） unit, the effect of pressure drop, separation efficiency and inlet flowrate were studied. It was observed that an increase in feed flowrate will decrease the pressure drop ratio, and with an increase in feed flowrate, separation efficiency increases gradually. Under the condition that feed fiowrate was ranging from 250L/h to 270L/h, the separation efficiency was 45.77%-82.80%, the recovery rate of catalyst solid panicles was increased from 10 20% of electrostatic catalyst separator to 50 80%. Thus, it is feasible to separate the slurry by using the miniature hydrocyclones in RFCC unit.
基金the National Natural Science Foundation of China(21590792,91426302,and 21433005)Guangdong Provincial Key Laboratory of Catalysis(2020B121201002)+1 种基金the National Science Basic Research Program of Shaanxi Province(2019JM-226)the financial and technical support from the Research Center for Advanced Materials Science(RCAMS)at King Khalid University through the Grant(RCAMS/KKU/014-20)。
文摘MXene is a variety of new two-dimensional(2D)materials with early transition metal carbides,nitrides,and carbonitrides.Quantum chemical studies have been carried out on the geometries,electronic structures,stability and catalytic properties of a non-noble metal single-atom catalyst(SAC)with single Co atom anchored on MXene materials of Mo_(2)CS_(2).The Co adatom anchored on top of the Mo atom of this MXene is found to be rather stable,and this SAC is appropriate for CO oxidation.The charge transfers from the surface to the adsorbed CO and O2 play a significant role in the activation of these molecules on Co_(1)/Mo_(2)CS_(2).With this catalyst,the Eley-Rideal(ER),Langmuir-Hinshelwood(LH),and Termolecular Eley-Rideal(TER)mechanisms are explored for CO oxidation.We find that,while all the three mechanisms are feasible at low temperature,Co_(1)/Mo_(2)CS_(2) possesses higher catalytic activity for CO oxidation through the TER mechanism that features an intriguing OC(OO)CO intermediate(IM)adsorbed on Co single atom.The calculated activation energy barriers of the rate-limiting step are 0.67 eV(TER),0.78 eV(LH)and 0.88 eV(ER),respectively.The present study illustrates that it is promising to develop and design low-cost,non-noble metal SACs using MXene types of 2D materials.
