A new estimation method was proposed by combining the corresponding state principle with the group contribution method through introducing the concept of assumed-critical properties. Combining it with the Reidel equat...A new estimation method was proposed by combining the corresponding state principle with the group contribution method through introducing the concept of assumed-critical properties. Combining it with the Reidel equation, a new acentric factor correlation equation (CSGC-Reidel) was developed. Contribution values of 70 groups were obtained by correlating acentric factor data of 228 organic compounds of 14 type substances including saturated hydrocarbons, unsaturated hydrocarbons, cyclanes, aromatics, oxygen compounds, nitrogen compounds,halohydrocarbons, etc. The average error of acentric factor is 3.52% between the literature data and the predicated with the new estimation method.展开更多
The flash points of organic compounds were estimated using a hybrid method that includes a simple group contribution method (GCM) implemented in an artificial neural network (ANN) with particle swarm optimization (PSO...The flash points of organic compounds were estimated using a hybrid method that includes a simple group contribution method (GCM) implemented in an artificial neural network (ANN) with particle swarm optimization (PSO). Different topologies of a multilayer neural network were studied and the optimum architecture was determined. Property data of 350 compounds were used for training the network. To discriminate different substances the molecular structures defined by the concept of the classical group contribution method were given as input variables. The capabilities of the network were tested with 155 substances not considered in the training step. The study shows that the proposed GCM+ANN+PSO method represent an excellent alternative for the estimation of flash points of organic compounds with acceptable accuracy (AARD = 1.8%; AAE = 6.2 K).展开更多
To scientifically evaluate the equipment system of systems(SoS)contribution rate,a contribution rate calculation method based on a structural equation model(SEM)is proposed in this paper.The connotation and evaluation...To scientifically evaluate the equipment system of systems(SoS)contribution rate,a contribution rate calculation method based on a structural equation model(SEM)is proposed in this paper.The connotation and evaluation process of the equipment SoS contribution rate were redefined and standardized.To solve the existing problems in the application of the original contribution rate formula,a modified contribution rate calculation formula is proposed.Finally,the contribution rate evaluation index was divided into latent and explicit variables.The measurement and structural equations in the SEM were used to calculate and analyze the latent variables.The simulation results show that the number of defense lines of air defense weapon equipment has a greater impact on the linear configuration than the group configuration.When the number of K-type air defense weapons is sufficient,the two-layer linear configuration should be adopted with 20 air defense weapon systems.When the number of K-type air defense weapons is insufficient,the single-layer group configuration should be adopted with 12 air defense weapon systems.展开更多
文摘A new estimation method was proposed by combining the corresponding state principle with the group contribution method through introducing the concept of assumed-critical properties. Combining it with the Reidel equation, a new acentric factor correlation equation (CSGC-Reidel) was developed. Contribution values of 70 groups were obtained by correlating acentric factor data of 228 organic compounds of 14 type substances including saturated hydrocarbons, unsaturated hydrocarbons, cyclanes, aromatics, oxygen compounds, nitrogen compounds,halohydrocarbons, etc. The average error of acentric factor is 3.52% between the literature data and the predicated with the new estimation method.
文摘The flash points of organic compounds were estimated using a hybrid method that includes a simple group contribution method (GCM) implemented in an artificial neural network (ANN) with particle swarm optimization (PSO). Different topologies of a multilayer neural network were studied and the optimum architecture was determined. Property data of 350 compounds were used for training the network. To discriminate different substances the molecular structures defined by the concept of the classical group contribution method were given as input variables. The capabilities of the network were tested with 155 substances not considered in the training step. The study shows that the proposed GCM+ANN+PSO method represent an excellent alternative for the estimation of flash points of organic compounds with acceptable accuracy (AARD = 1.8%; AAE = 6.2 K).
基金The National Social Science Foundation Military Science Project(No.16GJ003-068).
文摘To scientifically evaluate the equipment system of systems(SoS)contribution rate,a contribution rate calculation method based on a structural equation model(SEM)is proposed in this paper.The connotation and evaluation process of the equipment SoS contribution rate were redefined and standardized.To solve the existing problems in the application of the original contribution rate formula,a modified contribution rate calculation formula is proposed.Finally,the contribution rate evaluation index was divided into latent and explicit variables.The measurement and structural equations in the SEM were used to calculate and analyze the latent variables.The simulation results show that the number of defense lines of air defense weapon equipment has a greater impact on the linear configuration than the group configuration.When the number of K-type air defense weapons is sufficient,the two-layer linear configuration should be adopted with 20 air defense weapon systems.When the number of K-type air defense weapons is insufficient,the single-layer group configuration should be adopted with 12 air defense weapon systems.
