水煤气无变换脱硫工艺中水解催化剂的选择和应用

我公司200 kt/a焦炉煤气配水煤气制甲醇装置的水煤气系统采用无变换精脱硫工艺,结合实际应用经验,对各种类型脱硫水解催化剂的选择和应用进行了总结和论述,对已采用或者拟采用同类型工艺的企业具有一定的参考价值。

Conserved quantities from Lie symmetries for nonholonomic systems

This paper presents a new method to seek the conserved quantity from a Lie symmetry without using either Lagrangians or Hamiltonians for nonholonomic systems. The differential equations of motion of the systems are established. The definition of the Lie symmetrical transformations of the systems is given, which only depends upon the infinitesimal transformations of groups for the generalized coordinates. The conserved quantity is directly constructed in terms of the Lie symmetry of the systems. The condition under which the Lie symmetry can lead to the conserved quantity and the form of the conserved quantity are obtained. Finally, an example is given to illustrate the application of the result.

SELF-DEPENDENT LOCALITY PRESERVING PROJECTION WITH TRANSFORMED SPACE-ORIENTED NEIGHBORHOOD GRAPH

Locality preserving projection （LPP） is a typical and popular dimensionality reduction （DR） method,and it can potentially find discriminative projection directions by preserving the local geometric structure in data. However,LPP is based on the neighborhood graph artificially constructed from the original data,and the performance of LPP relies on how well the nearest neighbor criterion work in the original space. To address this issue,a novel DR algorithm,called the self-dependent LPP （sdLPP） is proposed. And it is based on the fact that the nearest neighbor criterion usually achieves better performance in LPP transformed space than that in the original space. Firstly,LPP is performed based on the typical neighborhood graph; then,a new neighborhood graph is constructed in LPP transformed space and repeats LPP. Furthermore,a new criterion,called the improved Laplacian score,is developed as an empirical reference for the discriminative power and the iterative termination. Finally,the feasibility and the effectiveness of the method are verified by several publicly available UCI and face data sets with promising results.

Poststack reverse-time migration using a non-reflecting recursive algorithm on surface relief

Presently the research based on the accurate seismic imaging methods for surface relief, complex structure, and complicated velocity distributions is of great significance. Reverse-time migration is considered to be one of highly accurate methods. In this paper, we propose a new non-reflecting recursive algorithm for reverse-time migration by introducing the wave impedance function into the acoustic wave equation and the algorithm for the surface relief case is derived from the coordinate transformation principle. Using the exploding reflector principle and the zero-time imaging condition of poststack reverse- time migration, poststack numerical simulation and reverse-time migration with complex conditions can be realized. The results of synthetic and real data calculations show that the method effectively suppresses unwanted internal reflections and also deals with the seismic imaging problems resulting from surface relief. So, we prove that this method has strong adaptability and practicality.

New atom movement mechanism for tracking path on disordering AuCuI(A_8^(Au)A_4^(Cu)) compound

Taking experimental path on disordering AuCuI（AAuCu8A4）composed of A Au8 and ACu4 stem alloy genes as an example, three discoveries and a method were presented. The ability of Au Cu I（AAu Cu8 A4）to keep structure stabilization against changing temperature is attributed to the fact that the AAu8 and ACu4 potential well depths greatly surpass their vibration energies, which leads to the subequilibrium of experimental path. A new atom movement mechanism of AuCuI（AAuACu84）to change structure for suiting variation in temperature is the resonance activating-synchro alternating of alloy genes, which leads to heterogeneous and successive subequilibrium transitions. There exists jumping order degree, which leads to the existence of jumping Tj-temperature and an unexpected so-called ＂retro-effect＂ about jumping temperature retrograde shift to lower temperatures upon the increasing heating rate. A set of subequilibrium holographic network path charts were obtained by the experimental mixed enthalpy path method.

Biosorption of cadmium(Ⅱ) from aqueous solutions by industrial fungus Rhizopus cohnii

An important filamentous industrial fungus,Rhizopus cohnii(R.cohnii),was used as an efficient biosorbent for removing cadmium from wastewater.The sorption conditions,such as pH,the dose of biomass and the initial concentration of cadmium were examined.Two kinds of adsorption models were applied to simulate the biosorption data.The uptake of cadmium was higher in weak acid condition than in strong acid condition.Nearly no sorption of cadmium occurred when the pH value was lower than 2.0. Biosorption isothermal data could be well simulated by both Langmuir and Freundlich models.Langmuir simulation of the biosorption showed that the maximum uptake of cadmium was 40.5 mg/g(0.36 mmol/g)in the optimal conditions,which was higher than many other adsorbents,including biosorbents and activated carbon.In addition,the reusability results showed that after five times of sorption and desorption process,the sorption capacity of R.cohnii could still maintain nearly 80%,confirming its practical application in cadmium treatment.Fourier transform infrared spectrum revealed that carboxyl,amino and hydroxyl groups on biosorbent R.cohnii surface were responsible for the biosorption of cadmium.

Hybrid C a rrie r S prea d Based on 4-Weighted T ra nsform Spectrum System Fractional Fourier

Spread Spectrum （SS） is a promising technique to resist interference in wireless communication system In order to further improve this capability, this paper proposes a Hybrid Carrier （HC） SS system, combining 4-Weighted Fractional Fourier Transform （4-WFRFT） with SS technique. In this HC-SS system, due to the property of 4- WFRFT, the signal energy of proposed system is distributed on the time-frequency plane more evenly and symmmetrically, compared with the existing Single-Cartier （SC） and Multi-Carrier （MC） spread spectrum systems. In the selective channel, the proposed method can split the interference to a more broad range in order to reduce the influence, resulting in the better system perforrmnce. In addition, proposed system can be seen as the convergence of the existing SS techniques, which is a main feature in future.

Noether Symmetry and Noether Conserved Quantity of Nielsen Equation for Dynamical Systems of Relative Motion

Noether symmetry of Nielsen equation and Noether conserved quantity deduced directly from Noether symmetry for dynamical systems of the relative motion are studied. The definition and criteria of Noether symmetry of a Nielsen equation under the infinitesimal transformations of groups are given. Expression of Noether conserved quantity deduced directly from Noether symmetry of Nielsen equation for the system are obtained. Finally, an example is given to illustrate the application of the results.

Guaranteeing Wireless Communication Secrecy via a WFRFT-Based Cooperative System

In this paper, a weighted fractional Fourier transform(WFRFT) based cooperative overlay system, aiming to guarantee physical layer(PHY) security, is proposed. The paper elaborates how WFRFT and physical layer properties of the wireless medium are collaborated to guarantee the secrecy of wireless transmissions. In the proposed system, WFRFT is first preform on the secret data, such that the transmitted signal is distorted and can only be neutralized by inverse-WFRFT with the same parameter. And then two streams of the transformed sequences that bearing different messages are cooperatively and simultaneously transmitted to two legitimate receivers via a beamforming-liked method, respectively. In general, both the rapid spatial decorrelation property and the inherent security features of WFRFT are leveraged, such that only the eavesdropper's is degraded, and hence, the wireless communication secrecy is reliably guaranteed. Numerical simulations are conducted to evaluate the performance of the proposed system in terms of the average bit error rate and the secrecy capacity.

CONSTRUCTION OF FREQUENCY HOPPING SEQUENCES WITH NO HIT ZONE

In this paper,a property of Frequency Hopping (FH) sequence set with No Hit Zone (NHZ) is analyzed. Based on matrix transform and mapping methods,respectively,two classes of NHZ FH sequences are presented. These NHZ FH sequences have good Hamming auto-correlation and Hamming cross-correlation properties. FH Code-Division Multiple Access (FH-CDMA) communication systems employing such NHZ FH sequences will eliminate multiple-access interference if the maximum time delay is shorter than the length of the NHZ.

Infinite Sequence of Conservation Laws and Analytic Solutions for a Generalized Variable-Coefficient Fifth-Order Korteweg-de Vries Equation in Fluids

In this paper, an infinite sequence of conservation laws for a generalized variable-coefficient fifth-order Korteweg-de Vries equation in fluids are constructed based on the Backlund transformation. Hirota bilinear form and symbolic computation are applied to obtain three kinds of solutions. Variable coefficients can affect the conserved density, associated flux, and appearance of the characteristic lines. Effects of the wave number on the soliton structures are also discussed and types of soliton structures, e.g., the double-periodic soliton, parallel soliton and soliton complexes, are presented.

Conformal Invariance and a New Type of Conserved Quantities of Mechanical Systems with Variable Mass in Phase Space

Conformal invariance and a new type of conserved quantities of mechanical systems with variable mass in phase space are studied. Firstly, the definition and determining equation of conformal invariance are presented. The relationship between the conformal invariance and the Lie symmetry is given, and the necessary and sufficient condition that the conformal invarianee would be the Lie symmetry under the infinitesimal transformations is provided. Secondly, a new type of conserved quantities of the conformal invariance are obtained by using the Lie symmetry of the system. Lastly, an example is given to illustrate the application of the results.

Identification of the structure of Ni active sites for ethylene oligomerization on an amorphous silica-alumina supported nickel catalyst

The structure of Ni active sites supported on amorphous silica-alumina supports with different contents of Al_(2)O_(3)loadings in relation to their activities in ethylene oligomerization were investigated.Two kinds of Ni sites were detected by in situ FTIR-CO and H_(2)-TPR experiments,that are Ni^(2+)cations as grafted on weak acidic silanols and Ni^(2+)cations at ion-exchange positions.The ethylene oligomerization activities of these Ni/ASA catalysts were found an ascending tendency as the Al_(2)O_(3)loading decreased,which could be attributed to the enriched concentration of Ni^(2+)species on acidic silanols with a weaker interaction with the amorphous silica-alumina support.These Ni^(2+)species were more easily to be evolved into Ni^(+)species,which has been identified to be the active sites of ethylene oligomerization.Thus,it seems reasonable to conclude that Ni^(2+)species grafted on acidic silanols were the precursors of active sites.

Infinite Sequence Soliton-Like Exact Solutions of (2 + 1)-Dimensional Breaking Soliton Equation

To seek new infinite sequence soliton-like exact solutions to nonlinear evolution equations （NEE（s））, by developing two characteristics of construction and mechanization on auxiliary equation method, the second kind of elliptie equation is highly studied and new type solutions and Backlund transformation are obtained. Then （2＋ l ）-dimensional breaking soliton equation is chosen as an example and its infinite sequence soliton-like exact solutions are constructed with the help of symbolic computation system Mathematica, which include infinite sequence smooth soliton-like solutions of Jacobi elliptic type, infinite sequence compact soliton solutions of Jacobi elliptic type and infinite sequence peak soliton solutions of exponential function type and triangular function type.

Infinitely Many Conservation Laws of a Differential-difference Equation and Backlund Transformation

In this paper, with the help of the Lax representation, we show the existence of infinitely many conservation laws for a differential-difference equation,which is one of the Ladic-Ablowitz hierarchy, and the conservation density and the associated flux are given formularlly. We also demonstrate the relation between a continuous partial differential equation and the differential-difference equation, and give Backlund transformation for the former.

Influence of Na^+,K^+,Mg^(2+),Ca^(2+),and Fe^(3+) on filterability and settleability of drilling sludge

Solid–liquid separation is a vital step in drilling sludge disposal, and the filterability and settleability of drilling sludge are the main evaluating indicators for the separation process. The influence of Na^+,K^+,Mg^(2+),Ca^(2+),and Fe^(3+) on drilling sludge filterability and settleability was investigated in our research. The water content,filtration rate, supernatant volume and supernatant turbidity were measured to evaluate the filterability and settleability of drilling sludge. Meanwhile, the zeta potential, specific surface area of sludge flocs, particle size distribution and Fourier-transformed infrared spectra were employed to clarify the influencing mechanism.The experimental results showed that the filterability and settleability of drilling sludge were related to concentration and types of cations. Mg^(2+),Ca^(2+),and Fe^(3+) performed better than Na^+, K^+, and the cations with smaller hydrated radius got superior solid–liquid separation behavior at same valence. Finally, the spectra indicated that no chemical adsorption occurred between inorganic cations and drilling sludge flocs. The variation of surface charge and flocs growth after adding different inorganic cations were the reasons for the changes of the filterability and settleability.

Direction of Arrivals Estimation for Correlated Broadband Radio Signals by MVDR Algorithm Using Wavelet

A theoretical relationship between the wavelet transform and the fast fourier transformation(FFT) methods in broadband wireless signal is proposed for solving the direction of arrivals(DOAs) estimation problem. This leads naturally to the derivation of minimum variance distortionless response(MVDR) algorithm, which combines the benefits of subspace methods with those of wavelet, and spatially smoothed versions are utilized which exhibits good performance against correlated signals. We test the method's performance by simulating and comparing the performance of proposed algorithm, FFT MVDR and MVDR with correlated signals, and an improved performance is obtained.

Calculation of Infinite Series Through Polygamma Functions＇ Algorithms and Laplace Transforms

Here is introduced some novel algorithms which made use of polygarnma functions to get the exact limits of a broad class of infinite series. Moreover, Laplace transform is used to find the sum of many convergent infinite series. These exact limits are found in different branches of physics for some special cases series and are in complete agreement with the values found by other authors. Moreover, the methods presented here are generalized and applied to other wide variety of sums, including alternating series. Finally, these methods are simple and quite powerful to calculate the limits of many convergent series as you can see from the examples included.

A Novel Algorithm Based on 3D-MUSIC Algorithm for Localizing Near-Field Source

A novel 3-D MUSIC algorithm based on the classical 3D-MUSIC algorithm for the location of near-field source was presented. Under the far-field assumption of actual near-field, two algebraic relations of the location parameters between the actual near-field sources and the far-field ones were derived. With Fourier transformation and polynomial-root methods, the elevation and the azimuth of the far-field were obtained, the tracking paths can be developed, and the location parameters of the near-field source can be determined, then the more accurate results can be estimated using an optimization method. The computer simulation results prove that the algorithm for the location of the near-fields is more accurate, effective and suitable for real-time applications.

Wavelet Transform-Based Distributed Compressed Sensing in Wireless Sensor Networks

Wireless Sensor Networks(WSN) are mainly characterized by a potentially large number of distributed sensor nodes which collectively transmit information about sensed events to the sink.In this paper,we present a Distributed Wavelet Basis Generation(DWBG) algorithm performing at the sink to obtain the distributed wavelet basis in WSN.And on this basis,a Wavelet Transform-based Distributed Compressed Sensing(WTDCS) algorithm is proposed to compress and reconstruct the sensed data with spatial correlation.Finally,we make a detailed analysis of relationship between reconstruction performance and WTDCS algorithm parameters such as the compression ratio,the channel Signal-to-Noise Ratio(SNR),the observation noise power and the correlation decay parameter by simulation.The simulation results show that WTDCS can achieve high performance in terms of energy and reconstruction accuracy,as compared to the conventional distributed wavelet transform algorithm.