Hydrogen diffusion in Zr_(35)Ni_(55)V_(10) amorphous alloy was measured by chronopotentiometry. The results show that at lower molar ratio of hydrogen (x<0.06, x=n(H)/n(M)), the diffusivity of hydrogen increases ra...Hydrogen diffusion in Zr_(35)Ni_(55)V_(10) amorphous alloy was measured by chronopotentiometry. The results show that at lower molar ratio of hydrogen (x<0.06, x=n(H)/n(M)), the diffusivity of hydrogen increases rapidly with increasing the molar ratio of hydrogen. However, when x(H)>0.1, the diffusivity of hydrogen decreases slightly with increasing the molar ratio of hydrogen, which is similar to the change in crystalline alloy. It is proposed that hydrogen atoms mainly occupy the sites corresponding to tetrahedra with 4 Zr atoms at lower molar ratio of hydrogen. When the molar ratio of hydrogen is higher, the additional hydrogen atoms are in sites with higher energy and these sites in amorphous state are similar to these in crystalline states.展开更多
基金Project(0452NM002) supported by the Science and Technology Committee of Shanghai, ChinaProject(02ZE14033) supported by the Natural Science Foundation of Shanghai, China
文摘Hydrogen diffusion in Zr_(35)Ni_(55)V_(10) amorphous alloy was measured by chronopotentiometry. The results show that at lower molar ratio of hydrogen (x<0.06, x=n(H)/n(M)), the diffusivity of hydrogen increases rapidly with increasing the molar ratio of hydrogen. However, when x(H)>0.1, the diffusivity of hydrogen decreases slightly with increasing the molar ratio of hydrogen, which is similar to the change in crystalline alloy. It is proposed that hydrogen atoms mainly occupy the sites corresponding to tetrahedra with 4 Zr atoms at lower molar ratio of hydrogen. When the molar ratio of hydrogen is higher, the additional hydrogen atoms are in sites with higher energy and these sites in amorphous state are similar to these in crystalline states.
