Using potassium permanganate and acetic manganese as the reactants,amorphous manganese oxide was prepared with mechanochemical method. XRD was used for microstructure characterization,while cyclic voltammetry and cons...Using potassium permanganate and acetic manganese as the reactants,amorphous manganese oxide was prepared with mechanochemical method. XRD was used for microstructure characterization,while cyclic voltammetry and constant current charge-discharge were used for electrochemical performance testing. The positive electrode(PE) and negative electrode(NE) were investigated respectively in amorphous manganese oxide supercapacitor,aiming to find their different performances in charging-discharging. The results show that the crystalline structure is destroyed in both the PE and NE material during charge-discharge process. Thereinto,the NE suffers a bit more seriously. When cycling,the PE potential scope diminishes while the NE potential scope enlarges. The increased inner resistance makes the NE curves almost bended to be a right angle,but not the PE curves. The cell's equivalent series resistance(ESR) is more dependent on the NE,and the capacitance is mainly determined by the rapid descent of the NE potential range. The capacitances of the NE are highly rate-dependent,decreasing from 121.3 to 53.1 F/g,by 56.2%,over the range of 5-25 mV/s. However,the PE appears to be weakly dependent and its capacitance is only dropped by 22.1%.展开更多
文摘Using potassium permanganate and acetic manganese as the reactants,amorphous manganese oxide was prepared with mechanochemical method. XRD was used for microstructure characterization,while cyclic voltammetry and constant current charge-discharge were used for electrochemical performance testing. The positive electrode(PE) and negative electrode(NE) were investigated respectively in amorphous manganese oxide supercapacitor,aiming to find their different performances in charging-discharging. The results show that the crystalline structure is destroyed in both the PE and NE material during charge-discharge process. Thereinto,the NE suffers a bit more seriously. When cycling,the PE potential scope diminishes while the NE potential scope enlarges. The increased inner resistance makes the NE curves almost bended to be a right angle,but not the PE curves. The cell's equivalent series resistance(ESR) is more dependent on the NE,and the capacitance is mainly determined by the rapid descent of the NE potential range. The capacitances of the NE are highly rate-dependent,decreasing from 121.3 to 53.1 F/g,by 56.2%,over the range of 5-25 mV/s. However,the PE appears to be weakly dependent and its capacitance is only dropped by 22.1%.
