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去质子化剂活化的Novozym 435催化无定形蔗糖合成月桂酸蔗糖单酯 被引量:2
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作者 贺朦迪 张珂睿 +4 位作者 陈小龙 范永仙 陈翰驰 朱林江 陆跃乐 《食品与发酵工业》 CAS CSCD 北大核心 2021年第18期65-69,85,共6页
月桂酸蔗糖酯是一种重要的食品添加剂,可用作表面活性剂、乳化剂等,因其具有较高的安全性和抗淀粉老化作用,在食品、制糖等行业中具有广泛的应用。以Novozym 435为催化剂,以蔗糖和月桂酸乙烯酯作为底物,在叔戊醇中合成月桂酸蔗糖单酯。... 月桂酸蔗糖酯是一种重要的食品添加剂,可用作表面活性剂、乳化剂等,因其具有较高的安全性和抗淀粉老化作用,在食品、制糖等行业中具有广泛的应用。以Novozym 435为催化剂,以蔗糖和月桂酸乙烯酯作为底物,在叔戊醇中合成月桂酸蔗糖单酯。以无定形蔗糖作为底物,改善了蔗糖的溶解特性,进一步提升了月桂酸蔗糖单酯产量。对该酶催化体系进行反应条件优化,结果如下,在15 mL叔戊醇中,加入0.09 mol/L无定形蔗糖、0.15 mol/L月桂酸乙烯酯、16.7 g/L Novozym 435、2 g/L月桂酸钠及20 g/L分子筛,在75℃下反应60 h,月桂酸蔗糖单酯的质量浓度达到23.2 g/L,转化率达到49.2%,且未检测到二酯的生成。该研究可为今后酶法合成月桂酸蔗糖单酯的产业化奠定基础,也可为同类产品的开发提供新的思路。 展开更多
关键词 蔗糖 脂肪酶 去质子化剂 无定形蔗糖
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Crystallization inhibition of an amorphous sucrose system using raffinose 被引量:2
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作者 LEINEN K.M. LABUZA T.P. 《Journal of Zhejiang University-Science B(Biomedicine & Biotechnology)》 SCIE CAS CSCD 2006年第2期85-89,共5页
The shelf life of pure amorphous sucrose systems, such as cotton candy, can be very short. Previous studies have shown that amorphous sucrose systems held above the glass transition temperature will collapse and cryst... The shelf life of pure amorphous sucrose systems, such as cotton candy, can be very short. Previous studies have shown that amorphous sucrose systems held above the glass transition temperature will collapse and crystallize. One study, however, showed that adding a small percent of another type of sugar, such as trehalose, to sucrose can extend the shelf life of the amorphous system by slowing crystallization. This study explores the hypothesis that raffinose increases the stability of an amorphous sucrose system. Cotton candy at 5 wt% raffinose and 95 wt% sucrose was made and stored at room temperature and three different relative humidities (%RH) 11%RH, 33%RH, and 43%RH. XRD patterns, and glass transition temperatures were obtained to determine the stability as a function of %RH. The data collected showed that raffinose slows sucrose crystallization in a low moisture amorphous state above the glass transition temperature and therefore improves the stability of amorphous sucrose systems. 展开更多
关键词 CRYSTALLIZATION Amorphous sucrose system RAFFINOSE
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