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养殖废水中磷鸟粪石结晶法回收潜力及影响因子研究 被引量:1
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作者 Erick K.Mutai 王选 马林 《中国生态农业学报(中英文)》 CAS CSCD 北大核心 2022年第8期1346-1354,共9页
磷作为生命所必需的营养物质因其不可再生性、资源消耗和浪费导致的环境水体富营养化而引起人们的广泛关注。大量研究通过鸟粪石结晶技术从无机合成废水和真实废水中进行磷素回收,降低水体富营养化风险,并形成磷酸镁铵肥料。然而,鸟粪... 磷作为生命所必需的营养物质因其不可再生性、资源消耗和浪费导致的环境水体富营养化而引起人们的广泛关注。大量研究通过鸟粪石结晶技术从无机合成废水和真实废水中进行磷素回收,降低水体富营养化风险,并形成磷酸镁铵肥料。然而,鸟粪石结晶过程只涉及无机磷,而真实废水中有机磷含量高达总磷的30%~40%,导致鸟粪石结晶技术在实际应用中磷素回收率变异极大。目前,鸟粪石结晶法在真实废水与无机合成废水中磷回收率差距的量化分析缺乏,导致差异产生的机制和影响因子不明。本研究从103篇文献中收集了1186项观测数据,定量分析了在真实废水与无机合成废水中鸟粪石结晶磷回收率,解析了磷回收差距的潜在影响因子。结果表明,鸟粪石结晶法对无机合成废水中总磷的去除率(83.6%)高于真实废水(76.9%)。在真实废水中,鸟粪石结晶对pH和钙等外来离子更敏感,导致其总磷去除率变异较大,在20.4%和99.9%之间。镁离子和钙离子是影响鸟粪石结晶的重要因子,当Mg∶P比在1和2之间时,镁离子对鸟粪石结晶有积极的影响,而钙离子的存在对鸟粪石的形成有抑制作用。磷结晶沉淀作为一种非生物过程,有机磷矿化是总磷回收的限制因素。因此,曝气在有机磷矿化过程中起着重要作用,额外提供6 L∙min^(−1)的曝气流量有利于提高总磷和无机磷的回收率。提高镁磷比并不是提高磷回收率的关键因素,但对鸟粪石的组成和纯度具有显著影响。 展开更多
关键词 回收 鸟粪石 无机合成废水 真实废水
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Reuse of Anaerobic Sludge for Treating Synthetic Wastewater Containing Organic and Inorganic Pollutants in Fixed Bed Adsorber
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作者 Abbas Hameed Sulaymon Dheyaa Wajid Abbood Ahmed Hassoon Alit 《Journal of Environmental Science and Engineering(A)》 2012年第2期150-159,共10页
Dried anaerobic granular sludge (DAGS) for removing phenol (organic) and lead (inorganic) pollutants from synthetic wastewater was examined in a fixed bed system. A general rate multi-component model has been bu... Dried anaerobic granular sludge (DAGS) for removing phenol (organic) and lead (inorganic) pollutants from synthetic wastewater was examined in a fixed bed system. A general rate multi-component model has been built to predict the fixed bed breakthrough curves for single and dual-component system. This model considers both external and internal mass transfer resistances as well as axial dispersion with non-liner multi-component isotherm. The equilibrium isotherm model parameters such as isotherm model constants (qm and b), pore diffusion coefficients (Dp) were obtained from batch experiments, while the external mass transfer coefficients and axial dispersion (kf, Dz) were calculated from empirical correlations. The results show that the general rate multi-component model was found suitable for describing the biosorption process of the dynamic behavior of the DAGS adsorber column and that DAGS can be used efficiently to remove organic and inorganic pollutants. 展开更多
关键词 DAGS PHENOL LEAD BIOSORPTION fixed bed.
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