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Inorganic Phosphorus Fractions and Phosphorus Availability in a Calcareous Soil Receiving 21-Year Superphosphate Application 被引量:16
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作者 WANG Jun LIU Wen-Zhao +1 位作者 MU Han-Feng DANG Ting-Hui 《Pedosphere》 SCIE CAS CSCD 2010年第3期304-310,共7页
A long-term (21-year) field experiment was performed to study the responses of soil inorganic P fractions and P availability to annual fertilizer P application in a calcareous soil on the Loess Plateau of China. Soi... A long-term (21-year) field experiment was performed to study the responses of soil inorganic P fractions and P availability to annual fertilizer P application in a calcareous soil on the Loess Plateau of China. Soil Olsen-P contents increased by 3.7, 5.2, 11.2 and 20.6 mg P kg-1 after 21-year annual fertilizer P application at 20, 39, 59, and 79 kg P ha-1, respectively. Long-term fertilizer P addition also increased soil total P and inorganic P (Pi) contents significantly. The contents of inorganic P fractions were in the order of Ca10-P 〉 Cas-P 〉 Fe-P 〉 A1-P 〉 occluded P 〉 Ca2-P in the soil receiving annual fertilizer P application. Fertilizer P application increased Cas-P, A1-P and Ca2-P contents as well as their percentages relative to Pi. Pi application increased Fe-P and occluded P contents but nor their percentages. Soil Ca10- P content remained unchanged after fertilizer P application while its percentage relative to Pi declined with increasing fertilizer P rate. All Pi fractions but Ca10-P were correlated with Olsen-P significantly. 90% of variations in Olsen-P could be explained by Pi fractions, and the direct contribution of Cas-P was predominant. Long-term annual superphosphate application would facilitate the accumulation of soil Cas-P, and thus improve soil P availability. 展开更多
关键词 long-term experiment OLSEN-P path analysis Loess Plateau
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D-赖氨酸盐酸盐的制备研究 被引量:1
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作者 彭加平 韦平和 +1 位作者 周锡樑 王平 《中国新药杂志》 CAS CSCD 北大核心 2013年第22期2698-2701,共4页
目的:从L-赖氨酸盐酸盐制备D-赖氨酸盐酸盐。方法:经L-赖氨酸盐酸盐消旋制得的DL-赖氨酸,以L-酒石酸为手性拆分剂,生成D-赖氨酸-L-酒石酸盐,再经无机酸钙沉淀L-酒石酸,制得D-赖氨酸盐酸盐。结果:DL-赖氨酸与L-酒石酸反应适宜的摩尔比为1... 目的:从L-赖氨酸盐酸盐制备D-赖氨酸盐酸盐。方法:经L-赖氨酸盐酸盐消旋制得的DL-赖氨酸,以L-酒石酸为手性拆分剂,生成D-赖氨酸-L-酒石酸盐,再经无机酸钙沉淀L-酒石酸,制得D-赖氨酸盐酸盐。结果:DL-赖氨酸与L-酒石酸反应适宜的摩尔比为1∶0.8,反应温度为60~70℃。碳酸钙、氢氧化钙和氧化钙分离D-赖氨酸的收率分别为34.6%,34.0%和33.9%,含量分别为85.7%,90.3%和90.6%。纯化后的D-赖氨酸盐酸盐产品,其含量和光学纯度均达99%以上。结论:用L-酒石酸拆分DL-赖氨酸是可行的,用无机酸钙分离D-赖氨酸与L-酒石酸是有效的。 展开更多
关键词 DL-赖氨酸 D-赖氨酸盐酸盐 L-酒石酸 无机酸钙
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