Aromatic bromides are important chemicals in nature and chemical industries.However,their tra‐ditional synthesis routes suffer from low atomic economy and pollutant formation.Herein,we show that organic-inorganic hyb...Aromatic bromides are important chemicals in nature and chemical industries.However,their tra‐ditional synthesis routes suffer from low atomic economy and pollutant formation.Herein,we show that organic-inorganic hybrid perovskite methylammonium lead bromide(MAPbBr_(3))nanocrystals stabilized in aqueous HBr solution can achieve simultaneous aromatic bromination and hydrogen evolution using HBr as the bromine source under visible light irradiation.By hybridizing MAPbBr_(3) with Pt/Ta_(2)O_(5) and poly(3,4‐ethylenedioxythiophene)polystyrene sulfonate as electron‐and hole‐transporting motifs,aromatic bromides were achieved from aromatic compounds with high yield(up to 99%)and selectivity(up to 99%)with the addition of N,N‐dimethylformamide or its analogs.The mechanistic studies revealed that the bromination proceeds via an electrophilic attack pathway and that HOBr may be the key intermediate in the bromination reaction.展开更多
Surface passivation with organic materials is one of the most effective and popular strategies to improve the stability and efficiency of perovskite solar cells(PSCs). However, the secondary bonding formed between org...Surface passivation with organic materials is one of the most effective and popular strategies to improve the stability and efficiency of perovskite solar cells(PSCs). However, the secondary bonding formed between organic molecules and perovskite layers is still not strong enough to protect the perovskite absorber from degradation initialized by oxygen and water attacking at defects. Recently, passivation with inorganic materials has gradually been favored by researchers due to the effectiveness of chemical and mechanical passivation. Lead-containing substances, alkali metal halides, transition elements, oxides,hydrophobic substances, etc. have already been applied to the surface and interfacial passivation of PSCs.These inorganic substances mainly manipulate the nucleation and crystallization process of perovskite absorbers by chemically passivating defects along grain boundaries and surface or forming a mechanically protective layer simultaneously to prevent the penetration of moisture and oxygen, thereby improving the stability and efficiency of the PSCs. Herein, we mainly summarize inorganic passivating materials and their individual passivation principles and methods. Finally, this review offers a personal perspective for future research trends in the development of passivation strategies through inorganic materials.展开更多
文摘Aromatic bromides are important chemicals in nature and chemical industries.However,their tra‐ditional synthesis routes suffer from low atomic economy and pollutant formation.Herein,we show that organic-inorganic hybrid perovskite methylammonium lead bromide(MAPbBr_(3))nanocrystals stabilized in aqueous HBr solution can achieve simultaneous aromatic bromination and hydrogen evolution using HBr as the bromine source under visible light irradiation.By hybridizing MAPbBr_(3) with Pt/Ta_(2)O_(5) and poly(3,4‐ethylenedioxythiophene)polystyrene sulfonate as electron‐and hole‐transporting motifs,aromatic bromides were achieved from aromatic compounds with high yield(up to 99%)and selectivity(up to 99%)with the addition of N,N‐dimethylformamide or its analogs.The mechanistic studies revealed that the bromination proceeds via an electrophilic attack pathway and that HOBr may be the key intermediate in the bromination reaction.
基金financially supported by the Natural Science Foundation of China (61874167 and 61674084)the National Key R&D Program of China (2018YFB1500105)+5 种基金the Fundamental Research Funds for Central Universitiesthe Natural Science Foundation of Tianjin City (17JCYBJC41400)the Open Fund of the Key Laboratory of Optical Information Science & Technology of Ministry of Education of China (2017KFKT014)the 111 Project (B16027)the International Cooperation Base (2016D01025)Tianjin International Joint Research and Development Center。
文摘Surface passivation with organic materials is one of the most effective and popular strategies to improve the stability and efficiency of perovskite solar cells(PSCs). However, the secondary bonding formed between organic molecules and perovskite layers is still not strong enough to protect the perovskite absorber from degradation initialized by oxygen and water attacking at defects. Recently, passivation with inorganic materials has gradually been favored by researchers due to the effectiveness of chemical and mechanical passivation. Lead-containing substances, alkali metal halides, transition elements, oxides,hydrophobic substances, etc. have already been applied to the surface and interfacial passivation of PSCs.These inorganic substances mainly manipulate the nucleation and crystallization process of perovskite absorbers by chemically passivating defects along grain boundaries and surface or forming a mechanically protective layer simultaneously to prevent the penetration of moisture and oxygen, thereby improving the stability and efficiency of the PSCs. Herein, we mainly summarize inorganic passivating materials and their individual passivation principles and methods. Finally, this review offers a personal perspective for future research trends in the development of passivation strategies through inorganic materials.
