Abstract： An alloy steel/alumina composite was successfully fabricated by pressureless infiltration of X10CrNil8-8 steel melt on 30% （mass fraction） Ni-containing alumina based composite ceramic （Ni/Al2O3） at 1 6...Abstract： An alloy steel/alumina composite was successfully fabricated by pressureless infiltration of X10CrNil8-8 steel melt on 30% （mass fraction） Ni-containing alumina based composite ceramic （Ni/Al2O3） at 1 600 ℃. The infiltration quality and interfacial bonding behavior were investigated by SEM, EDS, XRD and tensile tests. The results show that there is an obvious interfacial reaction layer between the alloying steel and the Ni/Al2O3 composite ceramic. The interfacial reactive products are （FexAly）3O4 intermetallic phase and （AlxCry）2O3 solid solution. The interracial bonding strength is as high as about 67.5 MPa. The bonding mechanism of X10CrNi 18-8 steel with the composite ceramic is that Ni inside the ceramic bodies dissolves into the alloy melt and transforms into liquid channels, consequently inducing the steel melt infiltrating and filling in the pores and the liquid channels. Moreover, the metallurgical bonding and interfacial reactive bonding also play a key role on the stability of the bonding interface.展开更多
Currently commercialized coronary stents are mainly made of the medical 316L stainless steel and cobalt-based alloy(L605) due to their good combination of properties,especially excellent mechanical properties.However,...Currently commercialized coronary stents are mainly made of the medical 316L stainless steel and cobalt-based alloy(L605) due to their good combination of properties,especially excellent mechanical properties.However,the presence of high quantity of nickel and/or cobalt elements,the agents known to trigger the toxic and allergic responses,in these materials has caused many clinic concerns.The potential adverse effect of nickel ions release has prompted the development of high nitrogen nickel-free austenitic stainless steels for medical application.Nitrogen in steel is not only to replace the nickel but also improve the properties of steel.In this paper,the harmfulness and release of nickel from metallic stents,and the advantages in mechanical properties and hemocompatibility of high nitrogen nickel-free stainless steels for coronary stents are reviewed.Apart from the highlight of nickel-free,the superiority of high strength and better hemocompatibility of high nitrogen nickel-free stainless steels can guarantee to manufacture thinner strut coronary stents with remarkable anticoagulation ability.High nitrogen nickel-free stainless steels as a promising coronary stents material will attract more and more clinical doctors and stents makers to bring them into clinical application.展开更多
基金Project(2009ZM0296) supported by the Fundamental Research Funds for the Central Universities in China
文摘Abstract： An alloy steel/alumina composite was successfully fabricated by pressureless infiltration of X10CrNil8-8 steel melt on 30% （mass fraction） Ni-containing alumina based composite ceramic （Ni/Al2O3） at 1 600 ℃. The infiltration quality and interfacial bonding behavior were investigated by SEM, EDS, XRD and tensile tests. The results show that there is an obvious interfacial reaction layer between the alloying steel and the Ni/Al2O3 composite ceramic. The interfacial reactive products are （FexAly）3O4 intermetallic phase and （AlxCry）2O3 solid solution. The interracial bonding strength is as high as about 67.5 MPa. The bonding mechanism of X10CrNi 18-8 steel with the composite ceramic is that Ni inside the ceramic bodies dissolves into the alloy melt and transforms into liquid channels, consequently inducing the steel melt infiltrating and filling in the pores and the liquid channels. Moreover, the metallurgical bonding and interfacial reactive bonding also play a key role on the stability of the bonding interface.
基金supported by the National Natural Science Foundation of China (Grant No. 31000428)the National Basic Research Program of China ("973" Program) (Grant No. 2012CB619101)
文摘Currently commercialized coronary stents are mainly made of the medical 316L stainless steel and cobalt-based alloy(L605) due to their good combination of properties,especially excellent mechanical properties.However,the presence of high quantity of nickel and/or cobalt elements,the agents known to trigger the toxic and allergic responses,in these materials has caused many clinic concerns.The potential adverse effect of nickel ions release has prompted the development of high nitrogen nickel-free austenitic stainless steels for medical application.Nitrogen in steel is not only to replace the nickel but also improve the properties of steel.In this paper,the harmfulness and release of nickel from metallic stents,and the advantages in mechanical properties and hemocompatibility of high nitrogen nickel-free stainless steels for coronary stents are reviewed.Apart from the highlight of nickel-free,the superiority of high strength and better hemocompatibility of high nitrogen nickel-free stainless steels can guarantee to manufacture thinner strut coronary stents with remarkable anticoagulation ability.High nitrogen nickel-free stainless steels as a promising coronary stents material will attract more and more clinical doctors and stents makers to bring them into clinical application.
