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蓖麻油改性两性聚氨酯复鞣剂的制备及应用 被引量:6
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作者 王学川 蓝晓梅 +2 位作者 朱兴 刘新华 孙思薇 《精细化工》 EI CAS CSCD 北大核心 2021年第6期1220-1226,1278,共8页
以异氟尔酮二异氰酸酯和聚四氢呋喃二醚醇为原料、2,2-二羟甲基丙酸为阴离子扩链剂、N-甲基二乙醇胺为阳离子扩链剂,制备了两性聚氨酯乳液,接着使用蓖麻油改性两性聚氨酯得到产物(COWPU)。通过FTIR对其进行了表征,采用纳米粒度及zeta电... 以异氟尔酮二异氰酸酯和聚四氢呋喃二醚醇为原料、2,2-二羟甲基丙酸为阴离子扩链剂、N-甲基二乙醇胺为阳离子扩链剂,制备了两性聚氨酯乳液,接着使用蓖麻油改性两性聚氨酯得到产物(COWPU)。通过FTIR对其进行了表征,采用纳米粒度及zeta电位仪对COWPU乳液的粒径及等电点进行了测试,采用TG对COWPU膜进行了热性能测试。随后将其用于有机无铬鞣剂TWS鞣制绵羊皮服装白湿革的复鞣工序。结果表明,COWPU已成功制备,具有显著的两性特征(等电点为6.29)和良好的生物降解性[5日生化需氧量(BOD_(5))与化学需氧量(COD)的比值为0.37],经COWPU复鞣后的坯革的撕裂强度为43.15 N/mm,抗张强度为9.99 MPa,均优于市售两性丙烯酸复鞣剂复鞣后的坯革。此外,COWPU还对坯革有一定的柔顺作用,有望实现复鞣-加脂一体工艺。 展开更多
关键词 蓖麻油 改性 两性聚氨酯 无铬鞣皮革 皮革化学品
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A Novel Approach to Clean Tanning Technology 被引量:5
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作者 Jing Li Lan Yan +1 位作者 Bi Shi Jing Zhang 《Journal of Chemistry and Chemical Engineering》 2013年第12期1203-1212,共10页
Traditional chrome tanning technology is still widely used today. In this technology, chrome shaving as well as chrome contained effluent in tanning and retanning processes is a big issue in the industry. Wet white ta... Traditional chrome tanning technology is still widely used today. In this technology, chrome shaving as well as chrome contained effluent in tanning and retanning processes is a big issue in the industry. Wet white tanning technology has been gaining in importance in recent years, but in general, the comprehensive performance of chrome-free tanned leather is not comparable with that of chrome tanned leather. In the present work, chrome-free tanning and chrome tanning are combined in a reversed procedure, which produces leather with chrome tanned leather quality without chrome tanned leather waste problems. In this procedure, a special amphoteric organic compound, no pickle, no salt chrome-free tanning agent TWT was used to tan delimed hides (no pickle) making wet white with shrinking temperature at 80-85 ~C. Then, new method called reversed tanning further process the wet white into chrome-tanned crust. In this reversed method, retanning, fatliquoring and coloring processes were carried out before chrome tanning. This technology eliminates chrome waste issue in tanning, shaving, post tanning processes. The chrome contained effluent is only concentrated in the last chrome tanning process. The leather made with this technology has complete conventional chrome-tanned leather quality. In this way, chrome leather quality without chrome waste problems was achieved. So, it is a new clean tanning technology. 展开更多
关键词 Chrome-free tanning wet-white reversed tanning process chrome tanning post tanning.
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