原子分子反应静力学及分子的离解极限

原子分子反应静力学及分子的离解极限王藩侯，钟彦平，程晓洪，朱正和１引言在宏观方面，化学动力学和化学热力学是两们相辅相存而又相互独立的重要学科。化学热力学仅对包括众多原子分子且具有统计行为的系统才是正确的。限于研究平衡态和平衡态移动的方向性。不含时间变...

Temporal Variations in Carbon Stock of Pinus roxburghii Sargent Forests of Himachal Pradesh,India

The present study was conducted in Solan Forest Division of Himachal Pradesh covering an area of about 57,158 ha. The aim was to estimate and assess the temporal change in carbon stock of the Chil Working Circle, in two forest ranges of the Division, Solan and Dharampur, over the period of 1956-2011. The inventory data of the working plans of Solan Forest Division from 1956-1957, 1984-1985 and 2002-2003 were used in the present study while field data for biomass estimation was collected for the year 2011.The results showed a declining trend in carbon stock over 1956-1984 period, however, an increasing trend over 1984-2002 was observed, which showed a further increase for the period 2002-2011. These fluctuating trends in the forest carbon stock can be related to increasing anthropogenic pressure on forests and the subsequent introduction of a ban on green felling envisaging efficient forest management, both of which affect the forest carbon pool significantly.

Joint Timing and Frequency Synchronization for OFDM based on Fractional Fourier Transform

In this paper a joint timing and frequency synchronization method based on Fractional Fourier Transform （FIFT） is proposed for Orthogonal Frequency-Division Multiplexing （OFDM） system. The combination of two chirp signals with opposite chirp rates are used as the training signal, the received training signal with timing and frequency offset is transformed by FrFT and the two peaks representing two chirps in FrFT domain are detected, then the position coordinates of the two peaks are precisely corrected and substituted into an equation group to calculate timing and frequency offset simultaneously. This method only needs one FrFT calculation to implement synchronization, the computational complexity is equal to that of FFT and less than that of correlation or maximum likelihood calculation of existing methods, and estimation range of frequency offset is Large, greater than half the signal bandwidth, while the simulation results show that even at low SNR it can accurately estimate timing and frequency offset and the estimation error is less than that of existing methods.

Exponential stability for networked control systems based on the model of nonlinear discrete-time system with time-varying delay

An uncertain nonlinear discrete-time system model with time-varying input delays for networked control systems (NCSs) is presented. The problem of exponential stability for the system is considered and some new criteria of exponential stability are obtained based on norm inequality methods. A numerical example is given todemonstrate that those criteria are useful to analyzing the stability of nonlinear NCSs.

Comparative Analysis of China Surface Air Temperature Series for the Past 100 Years

Temperature change plays a crucial role in global change sciences. In the past several decades, comprehensive find- ings have been achieved on temperature change in China for the past 100 years. Several time series have been created to illustrate the averaged surface air temperature for the country. The correlations of these series range from 0.73 to 0.97. It is also achieved in better data quality, wider spatial data coverage, improved homogeneity of time series, and enhanced reliability of findings. The results show an annual mean temperature increase by 0.78±0.27℃ per 100 years in China for the period 1906-2005. After prolonging the period till 2007, it is found that 2007 is rated as the warmest year in the past 100 years. Although all the series, except one, reflect temperature changes in the eastern part of China before the 1930s, they represent the general temperature change in most parts of the country after the 1930s.

Oil–water two-phase flow pattern analysis with ERT based measurement and multivariate maximum Lyapunov exponent

Oil–water two-phase flow patterns in a horizontal pipe are analyzed with a 16-electrode electrical resistance tomography(ERT) system. The measurement data of the ERT are treated as a multivariate time-series, thus the information extracted from each electrode represents the local phase distribution and fraction change at that location. The multivariate maximum Lyapunov exponent(MMLE) is extracted from the 16-dimension time-series to demonstrate the change of flow pattern versus the superficial velocity ratio of oil to water. The correlation dimension of the multivariate time-series is further introduced to jointly characterize and finally separate the flow patterns with MMLE. The change of flow patterns with superficial oil velocity at different water superficial velocities is studied with MMLE and correlation dimension, respectively, and the flow pattern transition can also be characterized with these two features. The proposed MMLE and correlation dimension map could effectively separate the flow patterns, thus is an effective tool for flow pattern identification and transition analysis.

Time Varying Gravitational Constant G via Entropic Force

If the uncertainty principle applies to the Verlinde entropic idea, it leads to a new term in the Newton＇s second law of mechanics in the Planck＇s scale. This curious velocity dependent term inspires a frictional feature of the gravity. In this short letter we address that this new term modifies the effective mass and the Newtonian constant as the time dependent quantities. Thus we must have a running on the value of the effective mass on the particle mass m near the holographic screen and the G. This result has a nigh relation with the Dirac hypothesis about the large numbers hypothesis （L.N.H.）. We propose that the corrected entropie terms via Verlinde idea can be brought as a holographic evidence for the authenticity of the Dirac idea.

Vegetation Change of Ecotone in West of Northeast China Plain Using Time-series Remote Sensing Data

Multi-temporal series of satellite SPOT-VEGETATION normalized difference vegetation index (NDVI) and normalized difference water index (NDWI) data from 1998 to 2007 were used for analyzing vegetation change of the ecotone in the west of the Northeast China Plain. The yearly and monthly maximal values,anomalies and change rates of NDVI and NDWI were calculated to reveal the interannual and seasonal changes in vegetation cover and vegetation water content. Linear regression method was adopted to characterize the trends in vegetation change. The yearly maximal NDVI decreased from 0.41 in 1998 to 0.37 in 2007,implying the decreasing trend of vegetation activity. There was a significant decrease of maximal NDVI in spring and summer over the study period,while an increase trend was observed in autumn. The vegetation-improved regions and vegetation-degraded regions occupied 17.03% and 20.30% of the study area,respectively. The maximal NDWI over growing season dropped by 0.027 in 1998–2007,and about 15.15% of the study area showed a decreasing trend of water content. Vegetation water stress in autumn was better than that in spring. Vegetation cover and water content variations were sensitive to annual precipitation,autumn precipitation and summer temperature. The vegetation degradation trend in this ecotone might be induced by the warm-drying climate especially continuous spring and summer drought in the recent ten years.

Long-term variability of the sharp thermocline in the Yellow and East China Seas

Based on observed temperature data since the 1950s, long-term variability of the summer sharp thermocline in the Yellow Sea Cold Water Mass （YSCWM） and East China Sea Cold Eddy （ECSCE） areas is examined. Relationships between the thermocline and atmospheric and oceanic forcing were investigated using multiyear wind, Kuroshio discharge and air temperature data. Results show that： 1） In the YSCWM area, thermocline strength shows about 4-year and 16-year period oscillations. There is high correlation between summer thermocline strength and local atmospheric temperature in summer and the previous winter; 2） In the ECSCE area, interannual oscillation of thermocline strength with about a 4-year period （stronger in El Nifio years） is strongly correlated with that of local wind stress. A transition from weak to strong thermocline during the mid 1970s is consistent with a 1976/1977 climate shift and Kuroshio volume transport; 3） Long-term changes of the thermocline in both regions are mainly determined by deep layer water, especially on the decadal timescale. However, surface water can modify the thermocline on an interannual timescale in the YSCWM area.

Airborne Pollen Grains Of Afyon, Turkey

The airborne pollen grains of Afyon have been studied for a two_year period (1999-2000) with a Durham sampler. A total of 14 367 pollen grains belonging to 40 taxa have been identified and recorded with some unidentified ones. Of them, 6 732 were identified in 1999 and 7 635 in 2000. Of the total pollen grains, 69.67% were arboreal, 26.64% non_arboreal and 3.68 % unidentified. The majority of the investigated pollen grains were from Pinus, Gramineae, Cupressaceae, Platanus , Chenopodiaceae/Amaranthaceae, Quercus, Ailanthus, Moraceae, Juglans , Salix, Cedrus and Rosaceae. The highest level of pollen grains was in May.

Stabilization of a class of nonlinear discrete time systems with time varying delay

The stability and stabilization of a class of nonlinear discrete time delayed systems(NDTDS) with time-varying delay and norm-bounded nonlinearity are investigated. Based on discrete time Lyapunov–Krasovskii functional method, a sufficient delaydependent condition for asymptotic stability of nonlinear systems is offered. Then, this condition is used to design a new efficient delayed state feedback controller(DSFC) for stabilization of such systems. These conditions are in the linear matrix inequality(LMI) framework. Illustrative examples confirm the improvement of the proposed approach over the similar cases. Furthermore, the obtained stability and stabilization conditions will be extended to uncertain discrete time delayed systems(UDTDS) with polytopic parameter uncertainties and also with norm-bounded parameter uncertainties.

Nonlinear Time Series Prediction Using LS-SVM with Chaotic Mutation Evolutionary Programming for Parameter Optimization

Nonlinear time series prediction is studied by using an improved least squares support vector machine （LSSVM） regression based on chaotic mutation evolutionary programming （CMEP） approach for parameter optimization. We analyze how the prediction error varies with different parameters （σ, γ） in LS-SVM. In order to select appropriate parameters for the prediction model, we employ CMEP algorithm. Finally, Nasdaq stock data are predicted by using this LS-SVM regression based on CMEP, and satisfactory results are obtained.

Separation of Variable Treatment for Solving Time—Dependent Potentials

We use the separation of variable treatment to treat some time-dependent systems, and point out that the condition of separability is the same as the condition of existence of invariant, and the separation of variable treatment is interrelated with the quantum-invariant method and the propagator method. We directly use the separation of variable treatment to obtain the wavefunctions of the time-dependent Coulomb potential and the time-dependent Hulthén potential.

Optimizing bus services with variable directional and temporal demand using genetic algorithm

As a major mode choice of commuters for daily travel, bus transit plays an important role in many urban and metropolitan areas. This work proposes a mathematical model to optimize bus service by minimizing total cost and considering a temporally and directionally variable demand. An integrated bus service, consisting of all-stop and stop-skipping services is proposed and optimized subject to directional frequency conservation, capacity and operable fleet size constraints. Since the research problem is a combinatorial optimization problem, a genetic algorithm is developed to search for the optimal result in a large solution space. The model was successfully implemented on a bus transit route in the City of Chengdu, China, and the optimal solution was proved to be better than the original operation in terms of total cost. The sensitivity of model parameters to some key attributes/variables is analyzed and discussed to explore further the potential of accruing additional benefits or avoiding some of the drawbacks of stop-skipping services.

The Benefits of Using Google Cloud Computing for Developing Distributed Applications

IT as a dynamic filed changes very rapidly; efficient management of such systems for the most of the companies requires handling tremendous complex situations in terms of hardware and software setup. Hardware and software itself changes quickly with the time and keeping them updated is a difficult problem for the most of the companies; the problem is more emphasized for the companies having large infrastructure of IT facilities such as data centers which are expensive to be maintained. Many applications run on the company premises which require well prepared staff for successfully maintaining them. With the inception of Cloud Computing many companies have transferred their applications and data into cloud computing based platforms in order to have reduced maintaining cost, easier maintenance in terms of hardware and software, reliable and securely accessible services. The benefits of building distributed applications using Google infrastructure are conferred in this paper.

Progress in Research on Homogenization of Climate Data

The observation data from ground surface meteorological stations is an important basis on which climate change research is carried out, while the homogenization of the data is necessary for improving the quality and homogeneity of the time series. This paper reviews recent advances in the techniques of identifying and adjusting inhomogeneity in climate series. We briefly introduce the results of applying two commonly accepted and well-developed methods (RHtest and MASH) to surface climate observations such as temperature and wind speed in China. We then summarize current progress and problems in this field, and propose ideas for future studies in China. Along with collecting more detailed metadata, more research on homogenization technology should be done in the future. On the basis of comparing and evaluating advantages and disadvantages of different homogenization methods, the homogenized climate data series of the last hundred years should be rebuilt.

Long-term stability analysis of large-scale underground plant of Xiangjiaba hydro-power station

Numerical analysis of the optimal supporting time and long-term stability index of the surrounding rocks in the underground plant of Xiangjiaba hydro-power station was carried out based on the rheological theory. Firstly,the mechanical parameters of each rock group were identified from the experimental data; secondly,the rheological calculation and analysis for the cavern in stepped excavation without supporting were made; finally,the optimal time for supporting at the characteristic point in a typical section was obtained while the creep rate and displacement after each excavation step has satisfied the criterion of the optimal supporting time. Excavation was repeated when the optimal time for supporting was identified,and the long-term stability creep time and the maximum creep deformation of the characteristic point were determined in accordance with the criterion of long-term stability index. It is shown that the optimal supporting time of the characteristic point in the underground plant of Xiangjiaba hydro-power station is 5-8 d,the long-term stability time of the typical section is 126 d,and the corresponding largest creep deformation is 24.30 mm. While the cavern is supported,the cavern deformation is significantly reduced and the stress states of the surrounding rock masses are remarkably improved.

Influence of Auxiliary Equation on Wave Functions for Time-Dependent Pauli Equation in Presence of Aharonov-Bohm Effect

Invariant operator method for discrete or continuous spectrum eigenvalue and unitary transformation approach are employed to study the two-dimensional time-dependent Pauli equation in presence of the Aharonov-Bohm effect （AB） and external scalar potential. For the spin particles the problem with the magnetic field is that it introduces a singularity into wave equation at the origin. A physical motivation is to replace the zero radius flux tube by one of radius R, with the additional condition that the magnetic field be confined to the surface of the tube, and then taking the limit R → 0 at the end of the computations. We point that the invariant operator must contain the step function θ（r - R）. Consequently, the problem becomes more complicated. In order to avoid this dimculty, we replace the radius R by ρ（t）R, where ρ（t） is a positive time-dependent function. Then at the end of calculations we take the limit R →0. The qualitative properties for the invariant operator spectrum are described separately for the different values of the parameter C appearing in the nonlinear auxiliary equation satisfied by p（t）, i.e., C 〉 0, C = 0, and C 〈0. Following the C＇s values the spectrum of quantum states is discrete （C 〉 0） or continuous （C ≤ 0）.

The Project Siberian High in CMIP5 Models

The Siberian high(SH)experienced a decline from the 1970s to 1990s and a recovery in recent years.The evolution of the SH under global warming is unclear.In this study,41 Coupled Model Intercomparison Project Phase 5(CMIP5)climate models are evaluated in terms of their ability to simulate the temporal evolution of the SH in the 19th and 20th centuries and the spatial pattern of the SH during 1981–2005.The results show that 12models can capture the temporal evolution of the SH center intensity(SHCI)for 1872–2005.The linear correlation coefficient between the SHCI from the Twentieth Century Reanalysis and the simulated SHCI from the multi-model ensemble(MME)of the 12 models is 0.3 on annual and inter-annual scales(above the 99%confidence level).On decadal and multi-decadal time scales,the MME also captures the pronounced reduction(between 1981–2000and 1881–1900 period)and the recovery(during1991–2005)of the SH intensity.Finally,the future evolution of the SH is investigated using the MME of the 12models under the+4.5 and+8.5 W m-2 Representative Concentration Pathway(RCP)scenarios(RCP4.5 and RCP8.5).It is shown that the SHCI,similar to the SHCI in the 20th century,has no significant long-term trend in the 21st century under global warming(RCP8.5 scenario).At the end of 21st century(2081–2100),the SH shows stronger interannual variability than the SH at the end of20th century(1981–2000).The increased interannual variability likely favors the increased interannual variability in winter air temperature over midlatitude Eurasia at the end of 21st century.

Form-Preserving Transformations of Time-Dependent Schrodinger Equation withTime- and Position-Dependent Mass

We study space-time transformations of the time-dependent Schrodingerequation (TDSE) with time- and position-dependent (effective) mass. We obtain the most generalspace-time transformation that maps such a TDSE onto another one of its kind. The transformedpotential is given in explicit form.