[Objective] The aim was to identify the ploidy of sweet clover induced by colchicine. [Method] The sweet clover germinating seeds and colchicine solution were used for materials to research colchicine-induced Melilotu...[Objective] The aim was to identify the ploidy of sweet clover induced by colchicine. [Method] The sweet clover germinating seeds and colchicine solution were used for materials to research colchicine-induced Melilotus. [Result] The results showed that the concentration of 0.2% colchicine solution could induced double sweet clover which showed corresponding features of polyploidy plants as a whole showed great features. [Conclusion] Sweet clover induced by colchicine was polyploidy.展开更多
The commercialization of proton exchange membrane fuel cells(PEMFCs)could provide a cleaner energy society in the near future.However,the sluggish reaction kinetics and harsh conditions of the oxygen reduction reactio...The commercialization of proton exchange membrane fuel cells(PEMFCs)could provide a cleaner energy society in the near future.However,the sluggish reaction kinetics and harsh conditions of the oxygen reduction reaction affect the durability and cost of PEMFCs.Most previous reports on Pt-based electrocatalyst designs have focused more on improving their activity;however,with the commercialization of PEMFCs,durability has received increasing attention.In-depth insight into the structural evolution of Pt-based electrocatalysts throughout their lifecycle can contribute to further optimization of their activity and durability.The development of in situ electron microscopy and other in situ techniques has promoted the elucidation of the evolution mechanism.This mini review highlights recent advances in the structural evolution of Pt-based electrocatalysts.The mechanisms are adequately discussed,and some methods to inhibit or exploit the structural evolution of the catalysts are also briefly reviewed.展开更多
AIM:To investigate the biological features of hepatitis B virus(HBV)-transfected HepG2.2.15 cells. METHODS:The cell ultrastructure,cell cycle and apoptosis,and the abilities of proliferation and invasion of HBV-transf...AIM:To investigate the biological features of hepatitis B virus(HBV)-transfected HepG2.2.15 cells. METHODS:The cell ultrastructure,cell cycle and apoptosis,and the abilities of proliferation and invasion of HBV-transfected HepG2.2.15 and the parent HepG2 cells were examined by electron microscopy,flow cytometry, 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide and trans-well assay.Oncogenicity of the two cell lines was compared via subcutaneous injection and orthotopic injection or implantation in nude mice,and the pathological analysis of tumor formation was performed.Two cytoskeletal proteins were detected by Western blotting. RESULTS:Compared with HepG2 cells,HepG2.2.15 cells showed organelle degeneration and filopodia disappearance under electron microscope.HepG2.2.15 cells proliferated and migrated slowly in vitro,and hardly formed tumor and lung metastasis in nude mice.Flow cytometry showed that the majority of HepG2.2.15 cells were arrested in G1 phase,and apoptosis was minor in both cell lines.Furthermore,the levels of cytoskeletal proteins F-actin and Ezrin were decreased in HepG2.2.15 cells. CONCLUSION:HepG2.2.15 cells demonstrated a lower proliferation and invasion ability than the HepG2 cells due to HBV transfection.展开更多
In this paper,we give the explicit expressions of level k (r 1,r 2,…,r k) circulant matrices of order n 1n 2…n k,and the explicit expressions for the eigenvalues,the determinants and the inverse matrices of the kind...In this paper,we give the explicit expressions of level k (r 1,r 2,…,r k) circulant matrices of order n 1n 2…n k,and the explicit expressions for the eigenvalues,the determinants and the inverse matrices of the kind level k (r 1,r 2,…,r k) circulant matrices are derived,and it is also proved that the sort of matrices are diagonalizable.展开更多
The effect of laser beam welding(LBW) process on the microstructure-mechanical property relationship of a dissimilar weld between the copper(Cu) and stainless steel(SS) was investigated.Backscattered electron(BSE) bas...The effect of laser beam welding(LBW) process on the microstructure-mechanical property relationship of a dissimilar weld between the copper(Cu) and stainless steel(SS) was investigated.Backscattered electron(BSE) based scanning electron microscopy(SEM) imaging was used to characterize the highly heterogeneous microstructural features across the LBW(Cu-SS) weld.The BSE analysis thoroughly evidenced the complex microstructures produced at dissimilar weld interfaces and fusion zone along with the compositional information.Widely different grain growths from coarse columnar grains to equiaxed ultrafine grains were also evident along the Cu-weld interface.A highresolution electron backscattered diffraction(EBSD) analysis confirmed the existence of the grain refinement mechanism at the Cu-weld interface.Both tensile and impact properties of the dissimilar weld were found to be closely aligned with the property of Cu base metal.Microhardness gradients were spatially evident in the non-homogeneous material composition zones such as fusion zone and the Cu-weld interface regions.The heterogeneous nucleation spots across the weld sub-regions were clearly identified and interlinked with their microhardness measurements for a holistic understanding of structure-property relationships of the local weld sub-regions.The findings were effectively correlated to achieve an insight into the local microstructural gradients across the weld.展开更多
Near-liquidus cast ingot was reheated to semi-solid firstly, and then a bracket of motor was prepared by die casting the semi-solid ingot into mould. The microstructural characteristics of AZ91D alloy in these process...Near-liquidus cast ingot was reheated to semi-solid firstly, and then a bracket of motor was prepared by die casting the semi-solid ingot into mould. The microstructural characteristics of AZ91D alloy in these processes were investigated. In the process of near-liquidus casting, primary α-Mg grains tend to be rosette-like because of the increase of plentiful quasi-solid atom clusters in molten alloy with the decrease of pouring temperature. These rosette-like a-Mg grains in ingots fabricated by near-liquidus casting are fused off and refined into near-globular structure owing to the solute diffusion mechanism and the minimum surface energy mechanism during reheating. After semi-solid die-casting, a-Mg grains, located in biscuit, impact and connect with each other; α-Mg grains, located in inner gate, congregate together; while α-Mg grains, located in component, distribute uniformly and become into globularity or strip. Because the inner gate limits the flowing of semi-solid slurry, and the pressure acted on the semi-solid slurry decreases gradually along the filling direction of semi-solid slurry in Cavity, microstructural segregation of unmelted a-Mg grains appears along this direction. Shrinkage holes in casting are caused by two different reasons. For biscuit, the shrinkage holes are caused by the blocked access of feeding liquid to the shrinkage zone for the agglomerated unmelted α-Mg grains. For component, the shrinkage holes are caused by the lack of feeding of liquid alloy.展开更多
To shorten the fabrication process of difficult-to-form TiAl sheets, twin-roll strip casting and microstructural control were investigated in Ti-43Al alloy. A crack-free sheet with dimensions of 1000 mm × 110 mm ...To shorten the fabrication process of difficult-to-form TiAl sheets, twin-roll strip casting and microstructural control were investigated in Ti-43Al alloy. A crack-free sheet with dimensions of 1000 mm × 110 mm × 2 mm was obtained. The microstructure of stip casting sheets and heat treatments was systematically studied. The macrostructure consisted of columnar crystals extending inward and centrally located equiaxed crystals with severe Al segregation were observed along the thickness direction, due to the symmetrical solidification process and decreasing cooling rates. The strip casting alloy was characterized by fine duplex microstructure with a grain spacing of 20-30 μm and a lamellar spacing of 10-20 nm. Furthermore, multiple microstructures of near gamma, nearly lamellar and fully lamellar were obtained through heat treatment process with significantly improved homogeneity of the microstructure.展开更多
The microstructure evolution and its effect on flow stress of TC17 alloy during deformation in the α+β two-phase region were investigated via microstructure characterization and isothermal compression tests. Results...The microstructure evolution and its effect on flow stress of TC17 alloy during deformation in the α+β two-phase region were investigated via microstructure characterization and isothermal compression tests. Results showed that the spheroidized rate of α phase at 820 and 850℃ slightly increased with increasing strain. With increasing deformation temperature, the spheroidized rate of α phase showed a slight increasing trend, but the volume fraction of α phase significantly decreased. The flow stress at 780 ℃ and 1 s^-1 decreased continuously and steady state condition was not achieved up to strain of 1.2 due to dislocation annihilation and α lamellae rotation. Under this condition, the dynamic spheroidization was retarded. At the deformation temperatures of 820 and 850℃, and a strain rate of 1 s^-1, a steady state flow stress was observed at strains above 0.8 due to the balance between work hardening and dynamic softening. The dynamic softening was attributed to the α lamellae rotation, dynamic recovery and a little spheroidization.展开更多
Vitamin D3 (VD3) proliposomes (VDP), consisted of hydrogenated phosphatidycholine (HPC) and VD3, were prepared using supercritical anti-solvent technology (SAS). The effects of operation conditions (temperatu...Vitamin D3 (VD3) proliposomes (VDP), consisted of hydrogenated phosphatidycholine (HPC) and VD3, were prepared using supercritical anti-solvent technology (SAS). The effects of operation conditions (temperature, pressure and components) on the VD3 loading in VDP were studied. At the optimum conditions of pressure of 8.0 MPa, temperature of 45 ℃, and the mass ratio of 15.0% between VD3 and HPC, the VD3 loading reached 12.89%. VD3 liposomes (VDL) were obtained by hydrating VDP and the entrapment efficiency of VD3 in VDL reached 98.5%. The morphology and structure of VDP and VDL were characterized by SEM (scanning electron micro-scope), TEM (transmission electron microscope) and XRD (X-ray diffractometer). The structure of VD3 nanoparti-cles in HPC matrix was formed. The size of VDL with an average diameter of about 1μm was determined by dynamic light scattering instrument (DLS). The results indicated that VDP can be made by SAS and VDL with high entrapment efficiency can be formed easily via the hydration of VDP.展开更多
Core and cast sections observation and description,and logging,scanning electron microscope and core lab analysis data etc. were applied to the present research of the characteristics and mechanism of low permeability...Core and cast sections observation and description,and logging,scanning electron microscope and core lab analysis data etc. were applied to the present research of the characteristics and mechanism of low permeability beach-bar sandstone reservoir of Es4 in Dongying sag. The results indicated the reservoir has the characteristics of middle-low pores,low-permeability,low compositional and structural maturity,and thin throat. The low-permeability is mainly due to sedimentation (fine particles and argillaceous inter beds) and diagenesis (compaction,cementation,and dissolution). The cementation reduced the physical property of the reservoir mainly by carbonate cementation,quartz autogeny and enragement,and autogeny clay. Clay minerals usually jam the pores by filling holes,close-fitting the wall of hole,bridging,wrapping grains,and separate attaching the pores and so on. The dissolution is insufficient so as not to improve the porosity and permeability of the reservoir obviously. So it is also an important factor of forming low-permeability reservoir.展开更多
Nb tubes were fabricated through hydrostatic extrusion at extrusion ratios of 3.1 and 6.1 at ambient temperature,and then their microstructure,texture,and Vickers hardness were investigated based on electron back-scat...Nb tubes were fabricated through hydrostatic extrusion at extrusion ratios of 3.1 and 6.1 at ambient temperature,and then their microstructure,texture,and Vickers hardness were investigated based on electron back-scattered diffraction(EBSD)data.The fraction of low-angle boundaries(LABs)largely decreased with a sharp decrease in mean grain sizes after hydrostatic extrusion and was not proportional to extrusion ratios,assuming that mixed-asymmetrical junctions forming LABs dissociate at high extrusion ratios from the external stress(>981 MPa)with thermal activation by the generated heat.The correlation between grain size and Vickers hardness followed the Hall−Petch relationship despite the texture gradient of theá111ñcyclic fiber textural microstructure at low extrusion ratios and theá100ñtrue fiber textural microstructure at high extrusion ratios.The increase in hydrostatic pressure on the Nb tubes contributed to texture evolution in terms of extrusion ratios due to the difference between{110}<111>and{112}<111>components based on EBSD data.展开更多
The electrochemical dissolution and passivation of laser additive manufactured Ti6Al4V were investigated through Tafel polarization,potentiostatic polarization and AC impedance measurements.The results show that the s...The electrochemical dissolution and passivation of laser additive manufactured Ti6Al4V were investigated through Tafel polarization,potentiostatic polarization and AC impedance measurements.The results show that the solution treatment−aging(STA)process aggravates the element micro-segregation compared to the annealing process,leading to varied Al and V contents of the phases from different samples.It is proven that either Al-rich or V-rich condition can highly affect the electrochemical dissolution behaviors due to thermodynamical instability caused by element segregation.The dissolution rate in the metastable passivation process is controlled by the stability of the produced film that is affected by phases distribution,especially the difficult-to-dissolve phase.And then,the dissolution rate of the phases in the transpassivation region is consistent with the rank in the activation process because the dense film is not capable of being produced.Compared to the annealed sample,the higher dissolution rate of the STA sample is beneficial to the electrochemical machining(ECM)of Ti6Al4V.展开更多
The effects of applying an electromagnetic interaction of low intensity (EMILI) on the microstructure and corrosion resistance of 7075-T651 Al alloy plates (13 mm in thickness) during modified indirect electric arc (M...The effects of applying an electromagnetic interaction of low intensity (EMILI) on the microstructure and corrosion resistance of 7075-T651 Al alloy plates (13 mm in thickness) during modified indirect electric arc (MIEA) welding were investigated. The welding process was conducted in a single pass with a heat input of ~1.5 kJ/mm. The microstructural observations of the welds were correlated with the effect of EMILI on the local mechanical properties and the corrosion resistance in natural seawater by means of microhardness measurements and electrochemical impedance spectroscopy, respectively. Microstructural characterization of the welds revealed a grain refinement in the weld metal due to the electromagnetic stirring induced by EMILI of 3 mT during welding. In addition, observations in the scanning electron microscope showed that the precipitation of Cu-rich phases and segregation of eutectics were reduced in the heat affected zone (HAZ) also as an effect of EMILI. The high corrosion dissolution of the 7075-T651 welds in natural seawater and the extent of overaging in the HAZ were reduced when welding with EMILI of 3 mT. Thus, EMILI along with the MIEA technique may lead to welded joints with better microstructural characteristics, improved mechanical properties in the HAZ and reduced electrochemical activity.展开更多
To investigate the effect of grain refinement on the material properties of recently developed Al-25 Zn-3 Cu based alloys,Al-25 Zn-3 Cu,Al-25 Zn-3 Cu-0.01 Ti,Al-25 Zn-3 Cu-3 Si and Al-25 Zn-3 Cu-3 Si-0.01 Ti alloys we...To investigate the effect of grain refinement on the material properties of recently developed Al-25 Zn-3 Cu based alloys,Al-25 Zn-3 Cu,Al-25 Zn-3 Cu-0.01 Ti,Al-25 Zn-3 Cu-3 Si and Al-25 Zn-3 Cu-3 Si-0.01 Ti alloys were produced by permanent mold casting method.Microstructures of the alloys were examined by SEM.Hardness and mechanical properties of the alloys were determined by Brinell method and tensile tests,respectively.Tribological characteristics of the alloys were investigated by a ball-on-disc type test machine.Corrosion properties of the alloys were examined by an electrochemical corrosion experimental setup.It was observed that microstructure of the ternary A1-25 Zn-3 Cu alloy consisted ofα,α+ηandθ(Al2Cu)phases.It was also observed that the addition of 3 wt.%Si to A1-25Zn-3Cu alloy resulted in the formation of silicon particles in its microstructure.The addition of 0.01 wt.%Ti to the Al-25Zn-3Cu and Al-25 Zn-3 Cu-3 Si alloys caused a decrement in grain size by approximately 20%and 39%and an increment in hardness from HRB 130 to 137 and from HRB 141 to 156,respectively.Yield strengths of these alloys increased from 278 to 297 MPa and from 320 to 336 MPa while their tensile strengths increased from 317 to 340 MPa and from 334 to 352 MPa.Wear resistance of the alloys increased,but corrosion resistance decreased with titanium addition.展开更多
The effects of yttrium and artificial aging on AA2024 alloy were investigated.The developed samples were further subjected to artificial aging at 190℃for 1-10 h with an interval of 1 h.The metallurgical characterizat...The effects of yttrium and artificial aging on AA2024 alloy were investigated.The developed samples were further subjected to artificial aging at 190℃for 1-10 h with an interval of 1 h.The metallurgical characterization was done by scanning electron microscope and X-ray diffraction.The mechanical characterization like hardness and tensile strength of the samples was done using computerized Vickers hardness testing machine and universal testing machine.The microstructures revealed that addition of yttrium refined theα(Al)matrix and led to the formation of Al-Cu-Y intermetallic in the shape of Chinese script which strengthened the samples.Compared to the base metal,samples with yttrium addition showed better mechanical properties.The sample reinforced with 0.3 wt.%yttrium showed the highest mechanical properties with the hardness of 66 HV,UTS of 223 MPa,YS of 180 MPa,and elongation of 20.9%.The artificially aged samples showed that the peak hardening of all the samples took place within 5 h of aging at 190℃with Al2 Cu precipitation.Aging changed the intermetallic from Chinese script to the fibrous form.The optimum amount of yttrium addition to AA2024 was found to be 0.3 wt.%.展开更多
In this paper, we give the explicit expressions of level-k circulant matrices of type (n1,n2,…nk) and of order n1n2…nk,and the explicit expressions for the eigenvalues,the determinants and the inverse matrices of th...In this paper, we give the explicit expressions of level-k circulant matrices of type (n1,n2,…nk) and of order n1n2…nk,and the explicit expressions for the eigenvalues,the determinants and the inverse matrices of the kind level-k circulant matrices are derived,and it is also proved that the sort matrices are unitarily diagonalizable.展开更多
基金Supported by General Project of Education Department in Helongjiang (11531263)Key Project of Science and Technology Bureau, Helongjiang Land Reclamation Bureau (HNKXIV-08-06-09)~~
文摘[Objective] The aim was to identify the ploidy of sweet clover induced by colchicine. [Method] The sweet clover germinating seeds and colchicine solution were used for materials to research colchicine-induced Melilotus. [Result] The results showed that the concentration of 0.2% colchicine solution could induced double sweet clover which showed corresponding features of polyploidy plants as a whole showed great features. [Conclusion] Sweet clover induced by colchicine was polyploidy.
文摘The commercialization of proton exchange membrane fuel cells(PEMFCs)could provide a cleaner energy society in the near future.However,the sluggish reaction kinetics and harsh conditions of the oxygen reduction reaction affect the durability and cost of PEMFCs.Most previous reports on Pt-based electrocatalyst designs have focused more on improving their activity;however,with the commercialization of PEMFCs,durability has received increasing attention.In-depth insight into the structural evolution of Pt-based electrocatalysts throughout their lifecycle can contribute to further optimization of their activity and durability.The development of in situ electron microscopy and other in situ techniques has promoted the elucidation of the evolution mechanism.This mini review highlights recent advances in the structural evolution of Pt-based electrocatalysts.The mechanisms are adequately discussed,and some methods to inhibit or exploit the structural evolution of the catalysts are also briefly reviewed.
基金Supported by Graduate Innovation Foundation of Harbin Medical University No.HCXB2010010Key Technology Project of Heilongjiang Science and Technology Department,No.ZJY04-0102
文摘AIM:To investigate the biological features of hepatitis B virus(HBV)-transfected HepG2.2.15 cells. METHODS:The cell ultrastructure,cell cycle and apoptosis,and the abilities of proliferation and invasion of HBV-transfected HepG2.2.15 and the parent HepG2 cells were examined by electron microscopy,flow cytometry, 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide and trans-well assay.Oncogenicity of the two cell lines was compared via subcutaneous injection and orthotopic injection or implantation in nude mice,and the pathological analysis of tumor formation was performed.Two cytoskeletal proteins were detected by Western blotting. RESULTS:Compared with HepG2 cells,HepG2.2.15 cells showed organelle degeneration and filopodia disappearance under electron microscope.HepG2.2.15 cells proliferated and migrated slowly in vitro,and hardly formed tumor and lung metastasis in nude mice.Flow cytometry showed that the majority of HepG2.2.15 cells were arrested in G1 phase,and apoptosis was minor in both cell lines.Furthermore,the levels of cytoskeletal proteins F-actin and Ezrin were decreased in HepG2.2.15 cells. CONCLUSION:HepG2.2.15 cells demonstrated a lower proliferation and invasion ability than the HepG2 cells due to HBV transfection.
文摘In this paper,we give the explicit expressions of level k (r 1,r 2,…,r k) circulant matrices of order n 1n 2…n k,and the explicit expressions for the eigenvalues,the determinants and the inverse matrices of the kind level k (r 1,r 2,…,r k) circulant matrices are derived,and it is also proved that the sort of matrices are diagonalizable.
文摘The effect of laser beam welding(LBW) process on the microstructure-mechanical property relationship of a dissimilar weld between the copper(Cu) and stainless steel(SS) was investigated.Backscattered electron(BSE) based scanning electron microscopy(SEM) imaging was used to characterize the highly heterogeneous microstructural features across the LBW(Cu-SS) weld.The BSE analysis thoroughly evidenced the complex microstructures produced at dissimilar weld interfaces and fusion zone along with the compositional information.Widely different grain growths from coarse columnar grains to equiaxed ultrafine grains were also evident along the Cu-weld interface.A highresolution electron backscattered diffraction(EBSD) analysis confirmed the existence of the grain refinement mechanism at the Cu-weld interface.Both tensile and impact properties of the dissimilar weld were found to be closely aligned with the property of Cu base metal.Microhardness gradients were spatially evident in the non-homogeneous material composition zones such as fusion zone and the Cu-weld interface regions.The heterogeneous nucleation spots across the weld sub-regions were clearly identified and interlinked with their microhardness measurements for a holistic understanding of structure-property relationships of the local weld sub-regions.The findings were effectively correlated to achieve an insight into the local microstructural gradients across the weld.
基金Project(2008BB4177) supported by the Natural Science Foundation of Chongqing City, China
文摘Near-liquidus cast ingot was reheated to semi-solid firstly, and then a bracket of motor was prepared by die casting the semi-solid ingot into mould. The microstructural characteristics of AZ91D alloy in these processes were investigated. In the process of near-liquidus casting, primary α-Mg grains tend to be rosette-like because of the increase of plentiful quasi-solid atom clusters in molten alloy with the decrease of pouring temperature. These rosette-like a-Mg grains in ingots fabricated by near-liquidus casting are fused off and refined into near-globular structure owing to the solute diffusion mechanism and the minimum surface energy mechanism during reheating. After semi-solid die-casting, a-Mg grains, located in biscuit, impact and connect with each other; α-Mg grains, located in inner gate, congregate together; while α-Mg grains, located in component, distribute uniformly and become into globularity or strip. Because the inner gate limits the flowing of semi-solid slurry, and the pressure acted on the semi-solid slurry decreases gradually along the filling direction of semi-solid slurry in Cavity, microstructural segregation of unmelted a-Mg grains appears along this direction. Shrinkage holes in casting are caused by two different reasons. For biscuit, the shrinkage holes are caused by the blocked access of feeding liquid to the shrinkage zone for the agglomerated unmelted α-Mg grains. For component, the shrinkage holes are caused by the lack of feeding of liquid alloy.
基金Project(51504060) supported by the National Natural Science Foundation of ChinaProjects(2016YFB0301201,2016YFB0300603) supported by the National Key Research and Development Program of ChinaProject(N160713001) supported by the Fundamental Research Funds for the Central Universities,China
文摘To shorten the fabrication process of difficult-to-form TiAl sheets, twin-roll strip casting and microstructural control were investigated in Ti-43Al alloy. A crack-free sheet with dimensions of 1000 mm × 110 mm × 2 mm was obtained. The microstructure of stip casting sheets and heat treatments was systematically studied. The macrostructure consisted of columnar crystals extending inward and centrally located equiaxed crystals with severe Al segregation were observed along the thickness direction, due to the symmetrical solidification process and decreasing cooling rates. The strip casting alloy was characterized by fine duplex microstructure with a grain spacing of 20-30 μm and a lamellar spacing of 10-20 nm. Furthermore, multiple microstructures of near gamma, nearly lamellar and fully lamellar were obtained through heat treatment process with significantly improved homogeneity of the microstructure.
基金Project(51575446)supported by the National Natural Science Foundation of ChinaProject(2017KJXX-27)supported by the Shaanxi Province Youth Science and Technology New Star Plan,ChinaProject(3102017AX003)supported by the Fundamental Research Funds for the Central Universities,China
文摘The microstructure evolution and its effect on flow stress of TC17 alloy during deformation in the α+β two-phase region were investigated via microstructure characterization and isothermal compression tests. Results showed that the spheroidized rate of α phase at 820 and 850℃ slightly increased with increasing strain. With increasing deformation temperature, the spheroidized rate of α phase showed a slight increasing trend, but the volume fraction of α phase significantly decreased. The flow stress at 780 ℃ and 1 s^-1 decreased continuously and steady state condition was not achieved up to strain of 1.2 due to dislocation annihilation and α lamellae rotation. Under this condition, the dynamic spheroidization was retarded. At the deformation temperatures of 820 and 850℃, and a strain rate of 1 s^-1, a steady state flow stress was observed at strains above 0.8 due to the balance between work hardening and dynamic softening. The dynamic softening was attributed to the α lamellae rotation, dynamic recovery and a little spheroidization.
基金Supported by the National High Technology Research and Development Program of China (2007AA 10Z350) and the National Natural Science Foundation of China (20976103).
文摘Vitamin D3 (VD3) proliposomes (VDP), consisted of hydrogenated phosphatidycholine (HPC) and VD3, were prepared using supercritical anti-solvent technology (SAS). The effects of operation conditions (temperature, pressure and components) on the VD3 loading in VDP were studied. At the optimum conditions of pressure of 8.0 MPa, temperature of 45 ℃, and the mass ratio of 15.0% between VD3 and HPC, the VD3 loading reached 12.89%. VD3 liposomes (VDL) were obtained by hydrating VDP and the entrapment efficiency of VD3 in VDL reached 98.5%. The morphology and structure of VDP and VDL were characterized by SEM (scanning electron micro-scope), TEM (transmission electron microscope) and XRD (X-ray diffractometer). The structure of VD3 nanoparti-cles in HPC matrix was formed. The size of VDL with an average diameter of about 1μm was determined by dynamic light scattering instrument (DLS). The results indicated that VDP can be made by SAS and VDL with high entrapment efficiency can be formed easily via the hydration of VDP.
基金Project P06012 supported by the Key Research Project of SINOPEC
文摘Core and cast sections observation and description,and logging,scanning electron microscope and core lab analysis data etc. were applied to the present research of the characteristics and mechanism of low permeability beach-bar sandstone reservoir of Es4 in Dongying sag. The results indicated the reservoir has the characteristics of middle-low pores,low-permeability,low compositional and structural maturity,and thin throat. The low-permeability is mainly due to sedimentation (fine particles and argillaceous inter beds) and diagenesis (compaction,cementation,and dissolution). The cementation reduced the physical property of the reservoir mainly by carbonate cementation,quartz autogeny and enragement,and autogeny clay. Clay minerals usually jam the pores by filling holes,close-fitting the wall of hole,bridging,wrapping grains,and separate attaching the pores and so on. The dissolution is insufficient so as not to improve the porosity and permeability of the reservoir obviously. So it is also an important factor of forming low-permeability reservoir.
基金supported by a Grant from the Fundamental R&D Program(10067694)funded by the Ministry of Trade,Industry and Energy,Korea。
文摘Nb tubes were fabricated through hydrostatic extrusion at extrusion ratios of 3.1 and 6.1 at ambient temperature,and then their microstructure,texture,and Vickers hardness were investigated based on electron back-scattered diffraction(EBSD)data.The fraction of low-angle boundaries(LABs)largely decreased with a sharp decrease in mean grain sizes after hydrostatic extrusion and was not proportional to extrusion ratios,assuming that mixed-asymmetrical junctions forming LABs dissociate at high extrusion ratios from the external stress(>981 MPa)with thermal activation by the generated heat.The correlation between grain size and Vickers hardness followed the Hall−Petch relationship despite the texture gradient of theá111ñcyclic fiber textural microstructure at low extrusion ratios and theá100ñtrue fiber textural microstructure at high extrusion ratios.The increase in hydrostatic pressure on the Nb tubes contributed to texture evolution in terms of extrusion ratios due to the difference between{110}<111>and{112}<111>components based on EBSD data.
基金The authors are grateful for the financial supports from the project of Ministry of Industry and Information Technology of China(No.2019-00899-1-1)the Natural Science Foundation of Shaanxi Province,China(No.2021JM-060)Fundamental Research Funds for the Central Universities,China(No.3102019QD0409).
文摘The electrochemical dissolution and passivation of laser additive manufactured Ti6Al4V were investigated through Tafel polarization,potentiostatic polarization and AC impedance measurements.The results show that the solution treatment−aging(STA)process aggravates the element micro-segregation compared to the annealing process,leading to varied Al and V contents of the phases from different samples.It is proven that either Al-rich or V-rich condition can highly affect the electrochemical dissolution behaviors due to thermodynamical instability caused by element segregation.The dissolution rate in the metastable passivation process is controlled by the stability of the produced film that is affected by phases distribution,especially the difficult-to-dissolve phase.And then,the dissolution rate of the phases in the transpassivation region is consistent with the rank in the activation process because the dense film is not capable of being produced.Compared to the annealed sample,the higher dissolution rate of the STA sample is beneficial to the electrochemical machining(ECM)of Ti6Al4V.
文摘The effects of applying an electromagnetic interaction of low intensity (EMILI) on the microstructure and corrosion resistance of 7075-T651 Al alloy plates (13 mm in thickness) during modified indirect electric arc (MIEA) welding were investigated. The welding process was conducted in a single pass with a heat input of ~1.5 kJ/mm. The microstructural observations of the welds were correlated with the effect of EMILI on the local mechanical properties and the corrosion resistance in natural seawater by means of microhardness measurements and electrochemical impedance spectroscopy, respectively. Microstructural characterization of the welds revealed a grain refinement in the weld metal due to the electromagnetic stirring induced by EMILI of 3 mT during welding. In addition, observations in the scanning electron microscope showed that the precipitation of Cu-rich phases and segregation of eutectics were reduced in the heat affected zone (HAZ) also as an effect of EMILI. The high corrosion dissolution of the 7075-T651 welds in natural seawater and the extent of overaging in the HAZ were reduced when welding with EMILI of 3 mT. Thus, EMILI along with the MIEA technique may lead to welded joints with better microstructural characteristics, improved mechanical properties in the HAZ and reduced electrochemical activity.
文摘To investigate the effect of grain refinement on the material properties of recently developed Al-25 Zn-3 Cu based alloys,Al-25 Zn-3 Cu,Al-25 Zn-3 Cu-0.01 Ti,Al-25 Zn-3 Cu-3 Si and Al-25 Zn-3 Cu-3 Si-0.01 Ti alloys were produced by permanent mold casting method.Microstructures of the alloys were examined by SEM.Hardness and mechanical properties of the alloys were determined by Brinell method and tensile tests,respectively.Tribological characteristics of the alloys were investigated by a ball-on-disc type test machine.Corrosion properties of the alloys were examined by an electrochemical corrosion experimental setup.It was observed that microstructure of the ternary A1-25 Zn-3 Cu alloy consisted ofα,α+ηandθ(Al2Cu)phases.It was also observed that the addition of 3 wt.%Si to A1-25Zn-3Cu alloy resulted in the formation of silicon particles in its microstructure.The addition of 0.01 wt.%Ti to the Al-25Zn-3Cu and Al-25 Zn-3 Cu-3 Si alloys caused a decrement in grain size by approximately 20%and 39%and an increment in hardness from HRB 130 to 137 and from HRB 141 to 156,respectively.Yield strengths of these alloys increased from 278 to 297 MPa and from 320 to 336 MPa while their tensile strengths increased from 317 to 340 MPa and from 334 to 352 MPa.Wear resistance of the alloys increased,but corrosion resistance decreased with titanium addition.
文摘The effects of yttrium and artificial aging on AA2024 alloy were investigated.The developed samples were further subjected to artificial aging at 190℃for 1-10 h with an interval of 1 h.The metallurgical characterization was done by scanning electron microscope and X-ray diffraction.The mechanical characterization like hardness and tensile strength of the samples was done using computerized Vickers hardness testing machine and universal testing machine.The microstructures revealed that addition of yttrium refined theα(Al)matrix and led to the formation of Al-Cu-Y intermetallic in the shape of Chinese script which strengthened the samples.Compared to the base metal,samples with yttrium addition showed better mechanical properties.The sample reinforced with 0.3 wt.%yttrium showed the highest mechanical properties with the hardness of 66 HV,UTS of 223 MPa,YS of 180 MPa,and elongation of 20.9%.The artificially aged samples showed that the peak hardening of all the samples took place within 5 h of aging at 190℃with Al2 Cu precipitation.Aging changed the intermetallic from Chinese script to the fibrous form.The optimum amount of yttrium addition to AA2024 was found to be 0.3 wt.%.
文摘In this paper, we give the explicit expressions of level-k circulant matrices of type (n1,n2,…nk) and of order n1n2…nk,and the explicit expressions for the eigenvalues,the determinants and the inverse matrices of the kind level-k circulant matrices are derived,and it is also proved that the sort matrices are unitarily diagonalizable.