Painan coals of West Sumatra were selected as semi-anthracitic coal sample for studying the physicochemical properties such as measurement, evaluation and description of the changes of surface characteristic of coal s...Painan coals of West Sumatra were selected as semi-anthracitic coal sample for studying the physicochemical properties such as measurement, evaluation and description of the changes of surface characteristic of coal sample and their oxidation in the atmospheric air at a temperature ranging from 105 to 400 ℃ for 30 min. Several methods are adopted to analyze and discuss several phenomena of the oxidized Painan coal surface during oxidation process for the change in the physicochemical properties as determined by Atomic Force Microscope (AFM), contact angle, Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric and Differential Thermal Analysis (TG-DTA) analyses as well as other supporting analytical equipment. AFM analyses revealed some changes in adhesion force and surface morphology with more adhesion force available between 0.6 and 8.6 nN on polished coal surfaces due to the increased oxidation temperature. The study revealed that the extent of hydrophobicity of coal surface decreased with the increased of oxidation temperature expressed as contact angles at about 80° and 20°. Another phenomenon occurred during the experiment was hydrophilicity index of coal surface increase at approximately 1.3 and 2.9. Oxidation of coal that occurred with increased temperature also indicated an increase in oxygen content from 3.8% to 22.9 wt%. Increased oxygen functional group also noted that oxidation of coal took place during the treatment. We also found that oxidation treatment also affected the combustion properties of coal: decreasing ignition temperature between 452.9 and 317.6, lowering the reactivity of coal at maximum combustion rate temperature, and reflecting their char characteristics as burnt out, ranging from 652.3 to 648.5 ℃.展开更多
The present study documents the variability of surface sensible heat flux over Northwest China using station observations for the period 1961 2000.It is found that the afternoon and nighttime sensible heat flux variat...The present study documents the variability of surface sensible heat flux over Northwest China using station observations for the period 1961 2000.It is found that the afternoon and nighttime sensible heat flux variations are remarkably different.The variability of the instant flux in the afternoon is much larger than in the nighttime.The afternoon and nighttime flux anomalies tend to be opposite.The diurnal and seasonal dependence of sensible heat flux variations is closely related to the diurnal cycle of mean land-air temperature difference.The relationship of sensible heat flux with land-air temperature difference based on the instant value differs from that based on the daily mean.The present study indicates the importance for the models to properly simulate mean land-air temperature difference and its diurnal and seasonal variations in order to capture surface sensible heat flux variability over Northwest China and predicts its plausible impacts on climate.展开更多
The microstructure and mechanical properties of Inconel 625 alloy fabricated by wire arc additive manufacturing process were evaluated under as-prepared and heat-treated conditions.A dendritic Ni-based solid solution ...The microstructure and mechanical properties of Inconel 625 alloy fabricated by wire arc additive manufacturing process were evaluated under as-prepared and heat-treated conditions.A dendritic Ni-based solid solution phase along with(Nb,Ti)C carbide,Laves,and δ-Ni3Nb secondary phases were developed in the microstructure of the as-prepared alloy.Solution heat treatment led to the dissolution of Laves and Ni3Nb phases.In addition,dendrites were replaced with large columnar grains.Aging heat treatment resulted in the formation of grain boundary M23C6 carbide and nanometric γ''precipitates.Hardness,yield and tensile strengths,as well as elongation of the as-prepared part,were close to those of the cast alloy and its fracture occurred in a transgranular ductile mode.Solution heat treatment improved hardness and yield strength and declined the elongation,but it did not have a considerable impact on the tensile strength.Furthermore,aging heat treatment caused the tensile properties to deteriorate and changed the fracture to a mixture of transgranular ductile and intergranular brittle mode.展开更多
The South China Sea (SCS) is significantly influenced by El Nino and the Southern Oscillation (ENSO) through ENSO-driven atmospheric and oceanic changes. We analyzed measurements made from 1960 to 2004 to investig...The South China Sea (SCS) is significantly influenced by El Nino and the Southern Oscillation (ENSO) through ENSO-driven atmospheric and oceanic changes. We analyzed measurements made from 1960 to 2004 to investigate the interannual variability of the latent and sensible heat fluxes over the SCS. Both the interannual variations of latent and sensible heat fluxes are closely related to ENSO events. The low-pass mean heat flux anomalies vary in a coherent manner with the low-pass mean Southern Oscillation Index (SOI). Time lags between the heat flux anomalies and the SST anomalies were also studied. We found that latent heat flux anomalies have a minimum value around January of the year following El Nino events. During and after the mature phase of E1 Nino, a change of atmospheric circulation alters the local SCS near-surface humidity and the monsoon winds. During the mature phase of E1 Nino, the wind speed decreases over the entire sea, and the air-sea specific humidity difference anomalies decreases in the northern SCS and increases in the southern SCS. Thus, a combined effect of wind speed anomalies and air-sea specific humidity difference anomalies results in the latent heat flux anomalies attaining minimum levels around January of the year following an E1 Nino year.展开更多
Pure WC-6%Co nanosized composite powders were synthesized via a low-temperature method.The effects of carbon source on microstructure characteristic of composite powders were investigated,and the effects of heat-treat...Pure WC-6%Co nanosized composite powders were synthesized via a low-temperature method.The effects of carbon source on microstructure characteristic of composite powders were investigated,and the effects of heat-treatment parameter on carbon content of composite powders were also discussed.The results of SEM and XRD revealed that the carbon decomposing from glucose was more active than carbon black.Therefore,WC-Co nanosized composite powders could be synthesized at 900°C for 1 h under a hydrogen atmosphere.The individual WC grains were bonded together into a long strip under the action of cobalt.The results of carbon analysis revealed that the total carbon content decreased with the increase of the temperature in the range of 800-1000°C.Moreover,the total carbon content and the compounded carbon increased with the increase of the flow rate of H2 in the range of 1.1-1.9 m3/h.展开更多
The effects of the retrogression heating rate(340℃/min,57℃/min,4.3℃/min)on the microstructures and mechanical properties of aluminum alloy 7050 were investigated by means of hardness measurement,tensile properties ...The effects of the retrogression heating rate(340℃/min,57℃/min,4.3℃/min)on the microstructures and mechanical properties of aluminum alloy 7050 were investigated by means of hardness measurement,tensile properties testing,differential scanning calorimetry(DSC)and transmission electron microscopy(TEM).The results show that the retrogression heating rate significantly affects the microstructures and mechanical properties of the alloys treated by retrogression and re-aging(RRA)process, and it is found that the medium rate(57℃/min)leads to the highest mechanical properties.The strengthening phases in the matrix are mainly the fine dispersed η′precipitates and GP zones,and the grain boundary precipitates are coarse and discontinuous η phases.展开更多
Calcium carbonate (CaCO3) crystals in their preferred orientation were obtained in BG11 culture media inoculated with Synechocystis sp. PCC6803 (inoculated BG11). In this study, the features of calcium carbonate d...Calcium carbonate (CaCO3) crystals in their preferred orientation were obtained in BG11 culture media inoculated with Synechocystis sp. PCC6803 (inoculated BG11). In this study, the features of calcium carbonate deposition were investigated. Inoculated BGll in different calcium ion concentrations was used for the experimental group, while the BGll culture medium was used for the control group. The surface morphologies of the calcium carbonate deposits in the experimental and control groups were determined by scanning and transmission electron microscopy. The deposits were analyzed by electronic probe micro-analysis, Fourier transform infrared spectrum, X-ray diffraction, thermal gravimetric analysis and differential scanning calorimetry. The results show that the surfaces of the crystals in the experimental group were hexahedral in a scaly pattern. The particle sizes were micrometer-sized and larger than those in the control group. The deposits of the control group contained calcium (Ca), carbon (C), oxygen (O), phosphorus (P), iron (Fe), copper (Cu), zinc (Zn), and other elements. The deposits in the experimental group contained Ca, C, and O only. The deposits of both groups contained calcite. The thermal decomposition temperature of the deposits in the control group was lower than those in the experimental group. It showed that the CaCO3 deposits of the experimental group had higher thermal stability than those of the control group. This may be due to the secondary metabolites produced by the algae cells, which affect the carbonate crystal structure and result in a close-packed structure. The algae cells that remained after thermal weight loss were heavier in higher calcium concentrations in BGll culture media. There may be more calcium- containing crystals inside and outside of these cells. These results shall be beneficial for understanding the formation mechanism of carbonate minerals.展开更多
Target detection in low light background is one of the main tasks of night patrol robots for airport terminal.However,if some algorithms can run on a robot platform with limited computing resources,it is difficult for...Target detection in low light background is one of the main tasks of night patrol robots for airport terminal.However,if some algorithms can run on a robot platform with limited computing resources,it is difficult for these algorithms to ensure the detection accuracy of human body in the airport terminal. A novel thermal infrared salient human detection model combined with thermal features called TFSHD is proposed. The TFSHD model is still based on U-Net,but the decoder module structure and model lightweight have been redesigned. In order to improve the detection accuracy of the algorithm in complex scenes,a fusion module composed of thermal branch and saliency branch is added to the decoder of the TFSHD model. Furthermore,a predictive loss function that is more sensitive to high temperature regions of the image is designed. Additionally,for the sake of reducing the computing resource requirements of the algorithm,a model lightweight scheme that includes simplifying the encoder network structure and controlling the number of decoder channels is adopted. The experimental results on four data sets show that the proposed method can not only ensure high detection accuracy and robustness of the algorithm,but also meet the needs of real-time detection of patrol robots with detection speed above 40 f/s.展开更多
In this study,the sol-gel method was introduced to prepare the composite phase change material (CPCM). The CPCM was added to fabric with coating techniques and the thermal activity of modified fabric was studied. In a...In this study,the sol-gel method was introduced to prepare the composite phase change material (CPCM). The CPCM was added to fabric with coating techniques and the thermal activity of modified fabric was studied. In addition,the thermal property and the microstructure of CPCM were also discussed in detail by means of polarization microscope and differential scanning calorimeter,respectively. According to the analysis of main influencial factors of the property of CPCM,the optimal preparing technique was determined. It was proved that CPCM could exhibit a good thermal property while phase transformation process took place,and a better appearance of the fabric modified with CPCM could be obtained due to the fact that in a warm circumstance,the liquid-state phase change material could be firmly enwrapped and embedded in the three-dimensional network all the time during the phase transformation. Besides,the fabric treated with CPCM had a high phase-transition enthalpy and an appropriate phase-transition temperature. As a result,a desirable temperature-adjustable function appeared.展开更多
This article mainly discussed bulk material lHvl^ared by powder metallurgy, and the commercial 2024 aluminum alloy powder and FeNiCrCoA13 high entropy alloy powder (both produced by argon gas atomization process) we...This article mainly discussed bulk material lHvl^ared by powder metallurgy, and the commercial 2024 aluminum alloy powder and FeNiCrCoA13 high entropy alloy powder (both produced by argon gas atomization process) were ball-milled for different hours. The prepared powder was consolidated by hot extrusion method. The microstruetures of the milled powder and bulk alloy were examined by X - Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). The thermal stability was tested by differential scanning calorimetry (DSC). Mechanical properties of the extruded alloy were examined by Vickers hardness tester and mechanical testing machine. The results show that after milling, the mixed particle sizes and microstructures of the alloy powder change obviously. The compressive strength of the extruded alloy has reached 580 MPa under certain conditions of milling time and composition.展开更多
In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high temp...In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high tempera- ture. The samples were analysed by using scanning electron microscope (SEM), X-ray diffraction(XRD), energy disperse spectroscopy (EDS), and differential scanning calorimetry (DSC). The optimal conditions for preparation are as follows: the molar ratio of tetrabutyl orthotitanate to triethanolamine is 1 : 0.4, and the calcination and expansion temperature is in the range of 650--750 ~C. Under such conditions, the expansion volume of composites could reach 98 mE/g, and the mass loss ratio is less than 5%. The analysis shows that lower temperature and smaller particle size of graphite are helpful to the formation of anatase-type of TiO2, but larger particle size will lead to lower mass loss ratio, and higher temperature and larger particle size will lead to higher expansion volume.展开更多
Gelatins extracted from two edible insects Aspongubus viduatus (melon bug) and Agonoscelis pubescens (sorghum bug) were studied. The two insects showed 27.0 and 28.2% crude protein, respectively. Extraction of gel...Gelatins extracted from two edible insects Aspongubus viduatus (melon bug) and Agonoscelis pubescens (sorghum bug) were studied. The two insects showed 27.0 and 28.2% crude protein, respectively. Extraction of gelatin using hot water gave high yield followed by mild acid and distilled water extraction, respectively. SDS-PAGE pattern showed low molecular weight chains, and the two gelatins contained protein with molecular weight of 40 kDa as main component. The differential scanning calorimetry thermograms results confirm no difference between extraction methods concerning the extracted gelatin quality. FTIR spectra of melon and sorghum bug gelatins were similar and the absorption bands were situated in more than 6 bands in melon bug gelatin and only 6 bands in sorghum bug gelatin. Amide II bands of gelatins from both melon and sorghum bug appeared at around 1554 cm^-1, while Amide I bands (1734-1632 cmt) appeared only in melon bug method 2 (MB2) and melon bug method3 (MB3). Microstructures of the insect gelatin examined with the scanning electron microscope showed that melon bug exhibited the finest gelatin network with very small voids. Melon bug gelatin showed finer structure with smaller protein strands and voids than sorghum bug gelatin.展开更多
Sodium fluoride and high specific area silica were synthesized by using sodium hexafluorosilicate(Na2Si F6) and sodium carbonate decahydrate(Na2CO3·10H2O). The influencing factors of react temperature, contact ti...Sodium fluoride and high specific area silica were synthesized by using sodium hexafluorosilicate(Na2Si F6) and sodium carbonate decahydrate(Na2CO3·10H2O). The influencing factors of react temperature, contact time, sodium dodecyl sulfate(SDS) and molar ratio of Na2 Si F6 to Na2CO3·10H2O were investigated. The optimum process involves the reaction of 0.075 mol Na2 Si F6 and 150 m L, 0.225 mol Na2CO3·10H2O(molar ratio of 1:3) at 85 °C for 90 min, and 2.0×10-3 mol sodium dodecyl sulfate(SDS) as additive. The results show that the purities of Si O2 and Na F at extraction yields of 96.5% and 98.0% are 91.0% and 98.6%, respectively. The obtained Si O2 were characterized by X-ray diffraction(XRD), scanning electron microscope(SEM), Fourier transform infrared ray(FTIR), differential scanning calorimetry and thermogravimetric analysis(DSC-TGA), N2 absorption/desorption(BET) and laser particle size analyzer. The result demonstrates that Si O2 particles have a high BET surface area of 103 m2/g, and a mean grain size of 985 nm.展开更多
A facile and practical route was introduced to prepare LiFePO4/C cathode material with nano-sized primary particles and excellent electrochemical performance. LiH2PO4 was synthesized by using H3PO4 and LiOH as raw mat...A facile and practical route was introduced to prepare LiFePO4/C cathode material with nano-sized primary particles and excellent electrochemical performance. LiH2PO4 was synthesized by using H3PO4 and LiOH as raw materials. Then, as-prepared LiH2PO4, reduced iron powder andα-D-glucose were ball-milled, dried and sin-tered to prepare LiFePO4/C. X-ray diffractometry was used to characterize LiH2PO4, ball-milled product and LiFePO4/C. Differential scanning calorimeter-thermo gravimetric analysis was applied to investigate possible reac-tions in sintering and find suitable temperature for LiFePO4 formation. Scanning electron microscopy was em-ployed for the morphology of LiFePO4/C. As-prepared LiH2PO4 is characterized to be in P21cn(33) space group, which reacts with reduced iron powder to form Li3PO4, Fe3(PO4)2 and H2 in ball-milling and sintering. The appro-priate temperature for LiFePO4/C synthesis is 541.3-976.7 ℃. LiFePO4/C prepared at 700 ℃ presents nano-sized primary particles forming aggregates. Charge-discharge examination indicates that as-prepared LiFePO4/C displays appreciable discharge capacities of 145 and 131 mA·h·g^-1 at 0.1 and 1 C respectively and excellent discharge ca-pacity retention.展开更多
Mechanical properties and microstructures of Al-Li-Cu-Mg-Ag alloy after solution treatments were investigated by means of optical microscopy (OM), tensile test, hardness measurement and electrical conductivity test,...Mechanical properties and microstructures of Al-Li-Cu-Mg-Ag alloy after solution treatments were investigated by means of optical microscopy (OM), tensile test, hardness measurement and electrical conductivity test, differential scanning calorimetric (DSC), energy dispersive X-ray (EDX), scanning electron microscopy (SEM) and transition electron microscopy (TEM), respectively The results show that both tensile strength and hardness increase first and then decrease with temperature at constant holding time of 30 min with maximum strength and hardness appearing at 520 ℃. Tensile strength, hardness and elongation of samples treated at 520 ℃ for 30 min are 566 MPa (σb), 512 MPa (σ0.2), HB 148 and 8.23% (δ), respectively. There are certain amount of fine T1 (AI2CuLi) phase dispersing among AI substrates according to TEM images. This may result in mixed fracture morphology with trans-granular and inter-granular delamination cracks observed in SEM images.展开更多
文摘Painan coals of West Sumatra were selected as semi-anthracitic coal sample for studying the physicochemical properties such as measurement, evaluation and description of the changes of surface characteristic of coal sample and their oxidation in the atmospheric air at a temperature ranging from 105 to 400 ℃ for 30 min. Several methods are adopted to analyze and discuss several phenomena of the oxidized Painan coal surface during oxidation process for the change in the physicochemical properties as determined by Atomic Force Microscope (AFM), contact angle, Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric and Differential Thermal Analysis (TG-DTA) analyses as well as other supporting analytical equipment. AFM analyses revealed some changes in adhesion force and surface morphology with more adhesion force available between 0.6 and 8.6 nN on polished coal surfaces due to the increased oxidation temperature. The study revealed that the extent of hydrophobicity of coal surface decreased with the increased of oxidation temperature expressed as contact angles at about 80° and 20°. Another phenomenon occurred during the experiment was hydrophilicity index of coal surface increase at approximately 1.3 and 2.9. Oxidation of coal that occurred with increased temperature also indicated an increase in oxygen content from 3.8% to 22.9 wt%. Increased oxygen functional group also noted that oxidation of coal took place during the treatment. We also found that oxidation treatment also affected the combustion properties of coal: decreasing ignition temperature between 452.9 and 317.6, lowering the reactivity of coal at maximum combustion rate temperature, and reflecting their char characteristics as burnt out, ranging from 652.3 to 648.5 ℃.
基金supported by the National Basic Research Program of China (Grant No. 2009CB421405)the National Natural Science Foundation of China (Grant Nos.40905027 and 40730952)Program of Knowledge Innovationfor the 3rd period of Chinese Academy of Sciences (Grant No.KZCX2-YW-220)
文摘The present study documents the variability of surface sensible heat flux over Northwest China using station observations for the period 1961 2000.It is found that the afternoon and nighttime sensible heat flux variations are remarkably different.The variability of the instant flux in the afternoon is much larger than in the nighttime.The afternoon and nighttime flux anomalies tend to be opposite.The diurnal and seasonal dependence of sensible heat flux variations is closely related to the diurnal cycle of mean land-air temperature difference.The relationship of sensible heat flux with land-air temperature difference based on the instant value differs from that based on the daily mean.The present study indicates the importance for the models to properly simulate mean land-air temperature difference and its diurnal and seasonal variations in order to capture surface sensible heat flux variability over Northwest China and predicts its plausible impacts on climate.
文摘The microstructure and mechanical properties of Inconel 625 alloy fabricated by wire arc additive manufacturing process were evaluated under as-prepared and heat-treated conditions.A dendritic Ni-based solid solution phase along with(Nb,Ti)C carbide,Laves,and δ-Ni3Nb secondary phases were developed in the microstructure of the as-prepared alloy.Solution heat treatment led to the dissolution of Laves and Ni3Nb phases.In addition,dendrites were replaced with large columnar grains.Aging heat treatment resulted in the formation of grain boundary M23C6 carbide and nanometric γ''precipitates.Hardness,yield and tensile strengths,as well as elongation of the as-prepared part,were close to those of the cast alloy and its fracture occurred in a transgranular ductile mode.Solution heat treatment improved hardness and yield strength and declined the elongation,but it did not have a considerable impact on the tensile strength.Furthermore,aging heat treatment caused the tensile properties to deteriorate and changed the fracture to a mixture of transgranular ductile and intergranular brittle mode.
基金Supported by the National Basic Research Program of China under (No. 973-2007CB411807)the National High Technology Development Project (No.863-2006AA09Z140)the National Science Foundation under (No. 40506024)
文摘The South China Sea (SCS) is significantly influenced by El Nino and the Southern Oscillation (ENSO) through ENSO-driven atmospheric and oceanic changes. We analyzed measurements made from 1960 to 2004 to investigate the interannual variability of the latent and sensible heat fluxes over the SCS. Both the interannual variations of latent and sensible heat fluxes are closely related to ENSO events. The low-pass mean heat flux anomalies vary in a coherent manner with the low-pass mean Southern Oscillation Index (SOI). Time lags between the heat flux anomalies and the SST anomalies were also studied. We found that latent heat flux anomalies have a minimum value around January of the year following El Nino events. During and after the mature phase of E1 Nino, a change of atmospheric circulation alters the local SCS near-surface humidity and the monsoon winds. During the mature phase of E1 Nino, the wind speed decreases over the entire sea, and the air-sea specific humidity difference anomalies decreases in the northern SCS and increases in the southern SCS. Thus, a combined effect of wind speed anomalies and air-sea specific humidity difference anomalies results in the latent heat flux anomalies attaining minimum levels around January of the year following an E1 Nino year.
基金Project(51274107)supported by the National Natural Science Foundation of ChinaProject(2015FB127)supported by the Yunnan Natural Science Foundation,ChinaProject(2016P20151130003)supported by Analysis Foundation of Kunming University of Science and Technology,China
文摘Pure WC-6%Co nanosized composite powders were synthesized via a low-temperature method.The effects of carbon source on microstructure characteristic of composite powders were investigated,and the effects of heat-treatment parameter on carbon content of composite powders were also discussed.The results of SEM and XRD revealed that the carbon decomposing from glucose was more active than carbon black.Therefore,WC-Co nanosized composite powders could be synthesized at 900°C for 1 h under a hydrogen atmosphere.The individual WC grains were bonded together into a long strip under the action of cobalt.The results of carbon analysis revealed that the total carbon content decreased with the increase of the temperature in the range of 800-1000°C.Moreover,the total carbon content and the compounded carbon increased with the increase of the flow rate of H2 in the range of 1.1-1.9 m3/h.
基金Project(2005CB623700) supported by the National Basic Research Program of China
文摘The effects of the retrogression heating rate(340℃/min,57℃/min,4.3℃/min)on the microstructures and mechanical properties of aluminum alloy 7050 were investigated by means of hardness measurement,tensile properties testing,differential scanning calorimetry(DSC)and transmission electron microscopy(TEM).The results show that the retrogression heating rate significantly affects the microstructures and mechanical properties of the alloys treated by retrogression and re-aging(RRA)process, and it is found that the medium rate(57℃/min)leads to the highest mechanical properties.The strengthening phases in the matrix are mainly the fine dispersed η′precipitates and GP zones,and the grain boundary precipitates are coarse and discontinuous η phases.
基金Supported by the National Natural Science Foundation of China(Nos.40972043,41040018,41210104058,21176145,41372108,41302079)the Higher Educational Science and Technology Program of Shandong Province(No.J10LC15)+4 种基金the China Postdoctoral Science Foundation(No.2013M540560)the Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province,and SDUST Research Fund(No.2010KYTD103)the Open Project of Key Lab of Marine Bioactive Substance and Modern Analytical Technique,State Oceanic Administration,China(No.MBSMAT-2012-03)the Scientific and Technological Program of Qingdao(No.13-1-4-232-jch)the Domestic Visiting Scholar Program for Young Core Teachers in Shandong Universities,Shandong Province,China
文摘Calcium carbonate (CaCO3) crystals in their preferred orientation were obtained in BG11 culture media inoculated with Synechocystis sp. PCC6803 (inoculated BG11). In this study, the features of calcium carbonate deposition were investigated. Inoculated BGll in different calcium ion concentrations was used for the experimental group, while the BGll culture medium was used for the control group. The surface morphologies of the calcium carbonate deposits in the experimental and control groups were determined by scanning and transmission electron microscopy. The deposits were analyzed by electronic probe micro-analysis, Fourier transform infrared spectrum, X-ray diffraction, thermal gravimetric analysis and differential scanning calorimetry. The results show that the surfaces of the crystals in the experimental group were hexahedral in a scaly pattern. The particle sizes were micrometer-sized and larger than those in the control group. The deposits of the control group contained calcium (Ca), carbon (C), oxygen (O), phosphorus (P), iron (Fe), copper (Cu), zinc (Zn), and other elements. The deposits in the experimental group contained Ca, C, and O only. The deposits of both groups contained calcite. The thermal decomposition temperature of the deposits in the control group was lower than those in the experimental group. It showed that the CaCO3 deposits of the experimental group had higher thermal stability than those of the control group. This may be due to the secondary metabolites produced by the algae cells, which affect the carbonate crystal structure and result in a close-packed structure. The algae cells that remained after thermal weight loss were heavier in higher calcium concentrations in BGll culture media. There may be more calcium- containing crystals inside and outside of these cells. These results shall be beneficial for understanding the formation mechanism of carbonate minerals.
基金supported in part by the National Key Research and Development Program of China(No. 2018YFC0309104)the Construction System Science and Technology Project of Jiangsu Province (No.2021JH03)。
文摘Target detection in low light background is one of the main tasks of night patrol robots for airport terminal.However,if some algorithms can run on a robot platform with limited computing resources,it is difficult for these algorithms to ensure the detection accuracy of human body in the airport terminal. A novel thermal infrared salient human detection model combined with thermal features called TFSHD is proposed. The TFSHD model is still based on U-Net,but the decoder module structure and model lightweight have been redesigned. In order to improve the detection accuracy of the algorithm in complex scenes,a fusion module composed of thermal branch and saliency branch is added to the decoder of the TFSHD model. Furthermore,a predictive loss function that is more sensitive to high temperature regions of the image is designed. Additionally,for the sake of reducing the computing resource requirements of the algorithm,a model lightweight scheme that includes simplifying the encoder network structure and controlling the number of decoder channels is adopted. The experimental results on four data sets show that the proposed method can not only ensure high detection accuracy and robustness of the algorithm,but also meet the needs of real-time detection of patrol robots with detection speed above 40 f/s.
基金Fujian Province I mportant Science and Technology Development Fund,China (No.2005Z17)
文摘In this study,the sol-gel method was introduced to prepare the composite phase change material (CPCM). The CPCM was added to fabric with coating techniques and the thermal activity of modified fabric was studied. In addition,the thermal property and the microstructure of CPCM were also discussed in detail by means of polarization microscope and differential scanning calorimeter,respectively. According to the analysis of main influencial factors of the property of CPCM,the optimal preparing technique was determined. It was proved that CPCM could exhibit a good thermal property while phase transformation process took place,and a better appearance of the fabric modified with CPCM could be obtained due to the fact that in a warm circumstance,the liquid-state phase change material could be firmly enwrapped and embedded in the three-dimensional network all the time during the phase transformation. Besides,the fabric treated with CPCM had a high phase-transition enthalpy and an appropriate phase-transition temperature. As a result,a desirable temperature-adjustable function appeared.
文摘This article mainly discussed bulk material lHvl^ared by powder metallurgy, and the commercial 2024 aluminum alloy powder and FeNiCrCoA13 high entropy alloy powder (both produced by argon gas atomization process) were ball-milled for different hours. The prepared powder was consolidated by hot extrusion method. The microstruetures of the milled powder and bulk alloy were examined by X - Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). The thermal stability was tested by differential scanning calorimetry (DSC). Mechanical properties of the extruded alloy were examined by Vickers hardness tester and mechanical testing machine. The results show that after milling, the mixed particle sizes and microstructures of the alloy powder change obviously. The compressive strength of the extruded alloy has reached 580 MPa under certain conditions of milling time and composition.
基金Supported by Applied Basic Research Project of Sichuan Province (No.2006J13-014)Innovation Fund of Panzhihua University
文摘In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high tempera- ture. The samples were analysed by using scanning electron microscope (SEM), X-ray diffraction(XRD), energy disperse spectroscopy (EDS), and differential scanning calorimetry (DSC). The optimal conditions for preparation are as follows: the molar ratio of tetrabutyl orthotitanate to triethanolamine is 1 : 0.4, and the calcination and expansion temperature is in the range of 650--750 ~C. Under such conditions, the expansion volume of composites could reach 98 mE/g, and the mass loss ratio is less than 5%. The analysis shows that lower temperature and smaller particle size of graphite are helpful to the formation of anatase-type of TiO2, but larger particle size will lead to lower mass loss ratio, and higher temperature and larger particle size will lead to higher expansion volume.
文摘Gelatins extracted from two edible insects Aspongubus viduatus (melon bug) and Agonoscelis pubescens (sorghum bug) were studied. The two insects showed 27.0 and 28.2% crude protein, respectively. Extraction of gelatin using hot water gave high yield followed by mild acid and distilled water extraction, respectively. SDS-PAGE pattern showed low molecular weight chains, and the two gelatins contained protein with molecular weight of 40 kDa as main component. The differential scanning calorimetry thermograms results confirm no difference between extraction methods concerning the extracted gelatin quality. FTIR spectra of melon and sorghum bug gelatins were similar and the absorption bands were situated in more than 6 bands in melon bug gelatin and only 6 bands in sorghum bug gelatin. Amide II bands of gelatins from both melon and sorghum bug appeared at around 1554 cm^-1, while Amide I bands (1734-1632 cmt) appeared only in melon bug method 2 (MB2) and melon bug method3 (MB3). Microstructures of the insect gelatin examined with the scanning electron microscope showed that melon bug exhibited the finest gelatin network with very small voids. Melon bug gelatin showed finer structure with smaller protein strands and voids than sorghum bug gelatin.
文摘Sodium fluoride and high specific area silica were synthesized by using sodium hexafluorosilicate(Na2Si F6) and sodium carbonate decahydrate(Na2CO3·10H2O). The influencing factors of react temperature, contact time, sodium dodecyl sulfate(SDS) and molar ratio of Na2 Si F6 to Na2CO3·10H2O were investigated. The optimum process involves the reaction of 0.075 mol Na2 Si F6 and 150 m L, 0.225 mol Na2CO3·10H2O(molar ratio of 1:3) at 85 °C for 90 min, and 2.0×10-3 mol sodium dodecyl sulfate(SDS) as additive. The results show that the purities of Si O2 and Na F at extraction yields of 96.5% and 98.0% are 91.0% and 98.6%, respectively. The obtained Si O2 were characterized by X-ray diffraction(XRD), scanning electron microscope(SEM), Fourier transform infrared ray(FTIR), differential scanning calorimetry and thermogravimetric analysis(DSC-TGA), N2 absorption/desorption(BET) and laser particle size analyzer. The result demonstrates that Si O2 particles have a high BET surface area of 103 m2/g, and a mean grain size of 985 nm.
基金Supported partially by the Natural Science Foundation of Yunnan Province(2010ZC051)Analysis and Testing Foundation(2009-041)Starting Research Fund(14118245) from Kunming University of Science and Technology
文摘A facile and practical route was introduced to prepare LiFePO4/C cathode material with nano-sized primary particles and excellent electrochemical performance. LiH2PO4 was synthesized by using H3PO4 and LiOH as raw materials. Then, as-prepared LiH2PO4, reduced iron powder andα-D-glucose were ball-milled, dried and sin-tered to prepare LiFePO4/C. X-ray diffractometry was used to characterize LiH2PO4, ball-milled product and LiFePO4/C. Differential scanning calorimeter-thermo gravimetric analysis was applied to investigate possible reac-tions in sintering and find suitable temperature for LiFePO4 formation. Scanning electron microscopy was em-ployed for the morphology of LiFePO4/C. As-prepared LiH2PO4 is characterized to be in P21cn(33) space group, which reacts with reduced iron powder to form Li3PO4, Fe3(PO4)2 and H2 in ball-milling and sintering. The appro-priate temperature for LiFePO4/C synthesis is 541.3-976.7 ℃. LiFePO4/C prepared at 700 ℃ presents nano-sized primary particles forming aggregates. Charge-discharge examination indicates that as-prepared LiFePO4/C displays appreciable discharge capacities of 145 and 131 mA·h·g^-1 at 0.1 and 1 C respectively and excellent discharge ca-pacity retention.
基金Foundation item: Project(6140506) supported by GAD (General Armament Department), China
文摘Mechanical properties and microstructures of Al-Li-Cu-Mg-Ag alloy after solution treatments were investigated by means of optical microscopy (OM), tensile test, hardness measurement and electrical conductivity test, differential scanning calorimetric (DSC), energy dispersive X-ray (EDX), scanning electron microscopy (SEM) and transition electron microscopy (TEM), respectively The results show that both tensile strength and hardness increase first and then decrease with temperature at constant holding time of 30 min with maximum strength and hardness appearing at 520 ℃. Tensile strength, hardness and elongation of samples treated at 520 ℃ for 30 min are 566 MPa (σb), 512 MPa (σ0.2), HB 148 and 8.23% (δ), respectively. There are certain amount of fine T1 (AI2CuLi) phase dispersing among AI substrates according to TEM images. This may result in mixed fracture morphology with trans-granular and inter-granular delamination cracks observed in SEM images.