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提高烧结余热发电量的生产技术实践 被引量:1
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作者 穆固天 李刚 +3 位作者 李强 郑志强 张德千 张丰皓 《冶金动力》 2023年第4期57-60,88,共5页
从铁矿烧结工艺参数控制角度研究了影响余热回收的因素,得出大烟道温度、终点温度波动趋势可间接表征烧结矿显热量的变化趋势。针对影响烧结大烟道温度、终点温度稳定性、终点位置控制等因素采取了相应的管控措施,结合当前公司烧结生产... 从铁矿烧结工艺参数控制角度研究了影响余热回收的因素,得出大烟道温度、终点温度波动趋势可间接表征烧结矿显热量的变化趋势。针对影响烧结大烟道温度、终点温度稳定性、终点位置控制等因素采取了相应的管控措施,结合当前公司烧结生产现状建立了烧结余热发电管控模型,2022年烧结余热发电量提高至20.51kWh/t,同比增加16.38%。 展开更多
关键词 烧结终点位置 返矿粒度偏析 显热量 余热发电
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AHRI机房空调认证和测试要求
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作者 杨弋 薛桥生 《制冷与空调》 2016年第11期86-90,共5页
AHRI 1360/1361系列机房空调测试标准已经从2013版本升级为2016版本,为了方便广大机房空调制造商和相关工程师全面地了解AHRI(美国空调供暖和制冷工业协会)关于机房空调的认证和测试要求,本文就机房空调的分类和应用及其对应的工况条件... AHRI 1360/1361系列机房空调测试标准已经从2013版本升级为2016版本,为了方便广大机房空调制造商和相关工程师全面地了解AHRI(美国空调供暖和制冷工业协会)关于机房空调的认证和测试要求,本文就机房空调的分类和应用及其对应的工况条件、认证模式和标准,机房空调认证项目以及测试方法等分别进行了介绍。 展开更多
关键词 机房空调 显热量 热能效
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辐射供冷空调系统下的人体热舒适性研究 被引量:6
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作者 高松 赵民 +4 位作者 李扬 王宇昂 孟祥兆 顾兆林 金立文 《西安交通大学学报》 EI CAS CSCD 北大核心 2017年第9期98-105,共8页
为了深入研究辐射供冷空调系统下的人体热舒适性,对辐射供冷空调系统的传热机理进行了分析,合理简化了人体热平衡方程,获得了人体显热散热量、辐射对流散热量比与热舒适性的关系。实验及数值模拟结果表明:在辐射供冷空调系统下,人体热... 为了深入研究辐射供冷空调系统下的人体热舒适性,对辐射供冷空调系统的传热机理进行了分析,合理简化了人体热平衡方程,获得了人体显热散热量、辐射对流散热量比与热舒适性的关系。实验及数值模拟结果表明:在辐射供冷空调系统下,人体热舒适性指标(PMV)与人体显热散热量之间具有较好的线性关系,利用该线性关系,可从人体热平衡的角度直接对人体热舒适性进行评价;人体辐射对流散热量比与热舒适性指标之间没有明显的相关关系,即人体辐射对流散热量比对热舒适性没有影响。因此,在保证人体热舒适性的基础上,可以通过提高人体辐射对流散热量比,即使辐射供冷空调系统具有较大的辐射末端面积、较低的辐射末端温度或较高的送风温度,从而达到建筑节能的效果。此项研究可为辐射供冷空调系统的热舒适性评价及系统设计提供参考。 展开更多
关键词 辐射供冷空调系统 人体热舒适性 人体热平衡 热散热量
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Surface physicochemical properties of semi-anthracitic coal from Painan-Sumatra during air oxidation 被引量:6
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作者 Anggoro Tri Mursito Tsuyoshi Hirajima +1 位作者 Lina Nur Listiyowati Sudarsono Sudarsono 《International Journal of Coal Science & Technology》 EI 2018年第2期156-166,共11页
Painan coals of West Sumatra were selected as semi-anthracitic coal sample for studying the physicochemical properties such as measurement, evaluation and description of the changes of surface characteristic of coal s... Painan coals of West Sumatra were selected as semi-anthracitic coal sample for studying the physicochemical properties such as measurement, evaluation and description of the changes of surface characteristic of coal sample and their oxidation in the atmospheric air at a temperature ranging from 105 to 400 ℃ for 30 min. Several methods are adopted to analyze and discuss several phenomena of the oxidized Painan coal surface during oxidation process for the change in the physicochemical properties as determined by Atomic Force Microscope (AFM), contact angle, Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric and Differential Thermal Analysis (TG-DTA) analyses as well as other supporting analytical equipment. AFM analyses revealed some changes in adhesion force and surface morphology with more adhesion force available between 0.6 and 8.6 nN on polished coal surfaces due to the increased oxidation temperature. The study revealed that the extent of hydrophobicity of coal surface decreased with the increased of oxidation temperature expressed as contact angles at about 80° and 20°. Another phenomenon occurred during the experiment was hydrophilicity index of coal surface increase at approximately 1.3 and 2.9. Oxidation of coal that occurred with increased temperature also indicated an increase in oxygen content from 3.8% to 22.9 wt%. Increased oxygen functional group also noted that oxidation of coal took place during the treatment. We also found that oxidation treatment also affected the combustion properties of coal: decreasing ignition temperature between 452.9 and 317.6, lowering the reactivity of coal at maximum combustion rate temperature, and reflecting their char characteristics as burnt out, ranging from 652.3 to 648.5 ℃. 展开更多
关键词 Coal surface Adhesion force Contact angle Combustion properties
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烟气在陶瓷膜管内对流凝结换热实验研究 被引量:3
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作者 谢天 陈海平 +2 位作者 冯义钧 李祥升 杨博然 《节能技术》 CAS 2018年第6期483-488,515,共7页
为了研究烟气中水蒸气在陶瓷膜管内的热、质传递规律,通过烟气在单根陶瓷膜管内的对流凝结换热实验,研究了不同烟气参数(流量、温度和相对湿度)和冷却水流量对烟气对流凝结Sherwood数、烟气对流凝结Nusselt数和烟气显热、潜热换热量的... 为了研究烟气中水蒸气在陶瓷膜管内的热、质传递规律,通过烟气在单根陶瓷膜管内的对流凝结换热实验,研究了不同烟气参数(流量、温度和相对湿度)和冷却水流量对烟气对流凝结Sherwood数、烟气对流凝结Nusselt数和烟气显热、潜热换热量的影响。实验结果表明:烟气对流凝结Sherwood数、Nusselt数随烟气流量、温度和相对湿度的增加而上升,Sherwood数随冷却水流量增加基本不变,Nusselt数随冷却水流量增加显著上升;烟气潜热换热量与烟气对流凝结Sherwood数呈相同变化趋势,烟气显热换热量随烟气相对湿度、冷却水流量增加而上升,烟气流量大于10 L/min时,烟气显热换热量增长趋于平缓,烟气温度对烟气显热换热量没有影响。研究结果对于陶瓷膜在电厂实际烟气中应用具有指导意义。 展开更多
关键词 烟气 陶瓷膜 对流凝结Sherwood数 对流凝结Nusselt数 热、潜热换热量
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Variability of Surface Sensible Heat Flux over Northwest China 被引量:6
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作者 ZHOU Lian-Tong WU Ren-Guang HUANG Rong-Hui 《Atmospheric and Oceanic Science Letters》 2010年第2期75-80,共6页
The present study documents the variability of surface sensible heat flux over Northwest China using station observations for the period 1961 2000.It is found that the afternoon and nighttime sensible heat flux variat... The present study documents the variability of surface sensible heat flux over Northwest China using station observations for the period 1961 2000.It is found that the afternoon and nighttime sensible heat flux variations are remarkably different.The variability of the instant flux in the afternoon is much larger than in the nighttime.The afternoon and nighttime flux anomalies tend to be opposite.The diurnal and seasonal dependence of sensible heat flux variations is closely related to the diurnal cycle of mean land-air temperature difference.The relationship of sensible heat flux with land-air temperature difference based on the instant value differs from that based on the daily mean.The present study indicates the importance for the models to properly simulate mean land-air temperature difference and its diurnal and seasonal variations in order to capture surface sensible heat flux variability over Northwest China and predicts its plausible impacts on climate. 展开更多
关键词 sensible heat flux land-air temperature difference wind speed
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Effects of heat treatment on microstructure and mechanical properties of Inconel 625 alloy fabricated by wire arc additive manufacturing process 被引量:15
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作者 Abolfazl SAFARZADE Mahmood SHARIFITABAR Mahdi SHAFIEE AFARANI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第11期3016-3030,共15页
The microstructure and mechanical properties of Inconel 625 alloy fabricated by wire arc additive manufacturing process were evaluated under as-prepared and heat-treated conditions.A dendritic Ni-based solid solution ... The microstructure and mechanical properties of Inconel 625 alloy fabricated by wire arc additive manufacturing process were evaluated under as-prepared and heat-treated conditions.A dendritic Ni-based solid solution phase along with(Nb,Ti)C carbide,Laves,and δ-Ni3Nb secondary phases were developed in the microstructure of the as-prepared alloy.Solution heat treatment led to the dissolution of Laves and Ni3Nb phases.In addition,dendrites were replaced with large columnar grains.Aging heat treatment resulted in the formation of grain boundary M23C6 carbide and nanometric γ''precipitates.Hardness,yield and tensile strengths,as well as elongation of the as-prepared part,were close to those of the cast alloy and its fracture occurred in a transgranular ductile mode.Solution heat treatment improved hardness and yield strength and declined the elongation,but it did not have a considerable impact on the tensile strength.Furthermore,aging heat treatment caused the tensile properties to deteriorate and changed the fracture to a mixture of transgranular ductile and intergranular brittle mode. 展开更多
关键词 nickel alloys additive manufacturing direct energy deposition heat treatment microstructure
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Interannual variability of latent and sensible heat fluxes in the South China Sea
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作者 宗海波 刘玉光 +2 位作者 修鹏 徐青 荣增瑞 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2010年第1期153-159,共7页
The South China Sea (SCS) is significantly influenced by El Nino and the Southern Oscillation (ENSO) through ENSO-driven atmospheric and oceanic changes. We analyzed measurements made from 1960 to 2004 to investig... The South China Sea (SCS) is significantly influenced by El Nino and the Southern Oscillation (ENSO) through ENSO-driven atmospheric and oceanic changes. We analyzed measurements made from 1960 to 2004 to investigate the interannual variability of the latent and sensible heat fluxes over the SCS. Both the interannual variations of latent and sensible heat fluxes are closely related to ENSO events. The low-pass mean heat flux anomalies vary in a coherent manner with the low-pass mean Southern Oscillation Index (SOI). Time lags between the heat flux anomalies and the SST anomalies were also studied. We found that latent heat flux anomalies have a minimum value around January of the year following El Nino events. During and after the mature phase of E1 Nino, a change of atmospheric circulation alters the local SCS near-surface humidity and the monsoon winds. During the mature phase of E1 Nino, the wind speed decreases over the entire sea, and the air-sea specific humidity difference anomalies decreases in the northern SCS and increases in the southern SCS. Thus, a combined effect of wind speed anomalies and air-sea specific humidity difference anomalies results in the latent heat flux anomalies attaining minimum levels around January of the year following an E1 Nino year. 展开更多
关键词 latent heat flux sensible heat flux South China Sea
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Morphology and carbon content of WC-6%Co nanosized composite powders prepared using glucose as carbon source 被引量:5
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作者 Sheng-da GUO Rui BAO +2 位作者 Ping YANG Liang LIU Jian-hong YI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第4期722-728,共7页
Pure WC-6%Co nanosized composite powders were synthesized via a low-temperature method.The effects of carbon source on microstructure characteristic of composite powders were investigated,and the effects of heat-treat... Pure WC-6%Co nanosized composite powders were synthesized via a low-temperature method.The effects of carbon source on microstructure characteristic of composite powders were investigated,and the effects of heat-treatment parameter on carbon content of composite powders were also discussed.The results of SEM and XRD revealed that the carbon decomposing from glucose was more active than carbon black.Therefore,WC-Co nanosized composite powders could be synthesized at 900°C for 1 h under a hydrogen atmosphere.The individual WC grains were bonded together into a long strip under the action of cobalt.The results of carbon analysis revealed that the total carbon content decreased with the increase of the temperature in the range of 800-1000°C.Moreover,the total carbon content and the compounded carbon increased with the increase of the flow rate of H2 in the range of 1.1-1.9 m3/h. 展开更多
关键词 WC-6%Co composite powder carbon source heat-treatment parameter carbon content microstructure characteristic
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Effects of retrogression heating rate on microstructures and mechanical properties of aluminum alloy 7050 被引量:13
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作者 李国锋 张新明 +1 位作者 李鹏辉 游江海 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第6期935-941,共7页
The effects of the retrogression heating rate(340℃/min,57℃/min,4.3℃/min)on the microstructures and mechanical properties of aluminum alloy 7050 were investigated by means of hardness measurement,tensile properties ... The effects of the retrogression heating rate(340℃/min,57℃/min,4.3℃/min)on the microstructures and mechanical properties of aluminum alloy 7050 were investigated by means of hardness measurement,tensile properties testing,differential scanning calorimetry(DSC)and transmission electron microscopy(TEM).The results show that the retrogression heating rate significantly affects the microstructures and mechanical properties of the alloys treated by retrogression and re-aging(RRA)process, and it is found that the medium rate(57℃/min)leads to the highest mechanical properties.The strengthening phases in the matrix are mainly the fine dispersed η′precipitates and GP zones,and the grain boundary precipitates are coarse and discontinuous η phases. 展开更多
关键词 aluminum alloy 7050 retrogression and re-aging treatment MICROSTRUCTURE mechanical properties
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要“温度”不要“风度”──电脑散热专题
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作者 钟元翔 《电脑知识与技术(过刊)》 2003年第22期58-62,共5页
今年夏天格外的热,还没到三伏天,就已经是天天三十六、七度的高温了,真是让人受不了。听说商场里现在卖的最好的东西就是空调了。不过,对于咱们这些电脑发烧友来说,不仅仅要注意给自己散热去暑,还要注意要让你的“爱机”清凉一“夏”哟... 今年夏天格外的热,还没到三伏天,就已经是天天三十六、七度的高温了,真是让人受不了。听说商场里现在卖的最好的东西就是空调了。不过,对于咱们这些电脑发烧友来说,不仅仅要注意给自己散热去暑,还要注意要让你的“爱机”清凉一“夏”哟,要知道,高温对我们的“爱机”是有很大的危害的,尤其对那些喜欢超频的朋友更要注意保护好自己的机器。在这个时候大家一定想多了解一些有关散热方面的知识吧?那么,在这个专题里,我就把有关散热的知识详细的介绍给大家,希望大家能借助这些知识,让自己的“爱机”清凉一夏。 展开更多
关键词 电脑散热 散热知识 热量 CPU热量 热量 散热因素 散热装置 散热风扇
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Characterization of calcium deposition induced by Synechocystis sp. PCC6803 in BG11 culture medium 被引量:7
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作者 闫华晓 韩作振 +8 位作者 赵辉 周仕学 迟乃杰 韩梅 寇小燕 张艳 徐琳琳 田晨晨 秦松 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2014年第3期503-510,共8页
Calcium carbonate (CaCO3) crystals in their preferred orientation were obtained in BG11 culture media inoculated with Synechocystis sp. PCC6803 (inoculated BG11). In this study, the features of calcium carbonate d... Calcium carbonate (CaCO3) crystals in their preferred orientation were obtained in BG11 culture media inoculated with Synechocystis sp. PCC6803 (inoculated BG11). In this study, the features of calcium carbonate deposition were investigated. Inoculated BGll in different calcium ion concentrations was used for the experimental group, while the BGll culture medium was used for the control group. The surface morphologies of the calcium carbonate deposits in the experimental and control groups were determined by scanning and transmission electron microscopy. The deposits were analyzed by electronic probe micro-analysis, Fourier transform infrared spectrum, X-ray diffraction, thermal gravimetric analysis and differential scanning calorimetry. The results show that the surfaces of the crystals in the experimental group were hexahedral in a scaly pattern. The particle sizes were micrometer-sized and larger than those in the control group. The deposits of the control group contained calcium (Ca), carbon (C), oxygen (O), phosphorus (P), iron (Fe), copper (Cu), zinc (Zn), and other elements. The deposits in the experimental group contained Ca, C, and O only. The deposits of both groups contained calcite. The thermal decomposition temperature of the deposits in the control group was lower than those in the experimental group. It showed that the CaCO3 deposits of the experimental group had higher thermal stability than those of the control group. This may be due to the secondary metabolites produced by the algae cells, which affect the carbonate crystal structure and result in a close-packed structure. The algae cells that remained after thermal weight loss were heavier in higher calcium concentrations in BGll culture media. There may be more calcium- containing crystals inside and outside of these cells. These results shall be beneficial for understanding the formation mechanism of carbonate minerals. 展开更多
关键词 Synechocystis sp. PCC6803 preferred orientation BIOMINERALIZATION calcium carbonate thermal stability
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Thermal Infrared Salient Human Detection Model Combined with Thermal Features in Airport Terminal
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作者 YU Yuecheng LIU Chang +1 位作者 WANG Chuan SHI Jinlong 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2022年第4期434-449,共16页
Target detection in low light background is one of the main tasks of night patrol robots for airport terminal.However,if some algorithms can run on a robot platform with limited computing resources,it is difficult for... Target detection in low light background is one of the main tasks of night patrol robots for airport terminal.However,if some algorithms can run on a robot platform with limited computing resources,it is difficult for these algorithms to ensure the detection accuracy of human body in the airport terminal. A novel thermal infrared salient human detection model combined with thermal features called TFSHD is proposed. The TFSHD model is still based on U-Net,but the decoder module structure and model lightweight have been redesigned. In order to improve the detection accuracy of the algorithm in complex scenes,a fusion module composed of thermal branch and saliency branch is added to the decoder of the TFSHD model. Furthermore,a predictive loss function that is more sensitive to high temperature regions of the image is designed. Additionally,for the sake of reducing the computing resource requirements of the algorithm,a model lightweight scheme that includes simplifying the encoder network structure and controlling the number of decoder channels is adopted. The experimental results on four data sets show that the proposed method can not only ensure high detection accuracy and robustness of the algorithm,but also meet the needs of real-time detection of patrol robots with detection speed above 40 f/s. 展开更多
关键词 thermal infrared image human body detection SALIENCY thermal features lightweight model
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Preparation of Composite Phase Change Material Based on Sol-Gel Method and Its Temperature-Adjustable Textile 被引量:2
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作者 易世雄 马晓光 +1 位作者 张莹 李桦 《Journal of Donghua University(English Edition)》 EI CAS 2009年第3期284-289,共6页
In this study,the sol-gel method was introduced to prepare the composite phase change material (CPCM). The CPCM was added to fabric with coating techniques and the thermal activity of modified fabric was studied. In a... In this study,the sol-gel method was introduced to prepare the composite phase change material (CPCM). The CPCM was added to fabric with coating techniques and the thermal activity of modified fabric was studied. In addition,the thermal property and the microstructure of CPCM were also discussed in detail by means of polarization microscope and differential scanning calorimeter,respectively. According to the analysis of main influencial factors of the property of CPCM,the optimal preparing technique was determined. It was proved that CPCM could exhibit a good thermal property while phase transformation process took place,and a better appearance of the fabric modified with CPCM could be obtained due to the fact that in a warm circumstance,the liquid-state phase change material could be firmly enwrapped and embedded in the three-dimensional network all the time during the phase transformation. Besides,the fabric treated with CPCM had a high phase-transition enthalpy and an appropriate phase-transition temperature. As a result,a desirable temperature-adjustable function appeared. 展开更多
关键词 COMPOSITE phase change material SOL-GEL temperature-adjustable TEXTILE
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Fabrication and Mechanical Properties of 2024 Aluminum Alloy Reinforced by FeNiCrCoAl_3 High Entropy Particles 被引量:2
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作者 Zhi-Wei Wang Rui-Xiao Zheng +2 位作者 Chao-Li Ma Li-Rong Hao Yang Han 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2013年第5期119-122,共4页
This article mainly discussed bulk material lHvl^ared by powder metallurgy, and the commercial 2024 aluminum alloy powder and FeNiCrCoA13 high entropy alloy powder (both produced by argon gas atomization process) we... This article mainly discussed bulk material lHvl^ared by powder metallurgy, and the commercial 2024 aluminum alloy powder and FeNiCrCoA13 high entropy alloy powder (both produced by argon gas atomization process) were ball-milled for different hours. The prepared powder was consolidated by hot extrusion method. The microstruetures of the milled powder and bulk alloy were examined by X - Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). The thermal stability was tested by differential scanning calorimetry (DSC). Mechanical properties of the extruded alloy were examined by Vickers hardness tester and mechanical testing machine. The results show that after milling, the mixed particle sizes and microstructures of the alloy powder change obviously. The compressive strength of the extruded alloy has reached 580 MPa under certain conditions of milling time and composition. 展开更多
关键词 aluminum alloy nanocrystaUine FeNiCrCoA13 high entroy reinforced particle ball milling(BM) the extruded alloy
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Preparation and Characterization of TiO_2/Expanded Graphite 被引量:1
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作者 赖奇 朱世富 +3 位作者 刘国钦 邹敏 李玉峰 罗学萍 《Transactions of Tianjin University》 EI CAS 2010年第2期156-159,共4页
In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high temp... In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high tempera- ture. The samples were analysed by using scanning electron microscope (SEM), X-ray diffraction(XRD), energy disperse spectroscopy (EDS), and differential scanning calorimetry (DSC). The optimal conditions for preparation are as follows: the molar ratio of tetrabutyl orthotitanate to triethanolamine is 1 : 0.4, and the calcination and expansion temperature is in the range of 650--750 ~C. Under such conditions, the expansion volume of composites could reach 98 mE/g, and the mass loss ratio is less than 5%. The analysis shows that lower temperature and smaller particle size of graphite are helpful to the formation of anatase-type of TiO2, but larger particle size will lead to lower mass loss ratio, and higher temperature and larger particle size will lead to higher expansion volume. 展开更多
关键词 expanded graphite titanium dioxide COMPOSITE PREPARATION
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Preparation and Characterization of Gelatins from Two Sudanese Edible Insects 被引量:1
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作者 A. A. Mariod S. I. Abdelwahab +3 位作者 M. Y. Ibrahim S. Mohan M. Abd Elgadir N. M. Ain 《Journal of Food Science and Engineering》 2011年第1期45-55,共11页
Gelatins extracted from two edible insects Aspongubus viduatus (melon bug) and Agonoscelis pubescens (sorghum bug) were studied. The two insects showed 27.0 and 28.2% crude protein, respectively. Extraction of gel... Gelatins extracted from two edible insects Aspongubus viduatus (melon bug) and Agonoscelis pubescens (sorghum bug) were studied. The two insects showed 27.0 and 28.2% crude protein, respectively. Extraction of gelatin using hot water gave high yield followed by mild acid and distilled water extraction, respectively. SDS-PAGE pattern showed low molecular weight chains, and the two gelatins contained protein with molecular weight of 40 kDa as main component. The differential scanning calorimetry thermograms results confirm no difference between extraction methods concerning the extracted gelatin quality. FTIR spectra of melon and sorghum bug gelatins were similar and the absorption bands were situated in more than 6 bands in melon bug gelatin and only 6 bands in sorghum bug gelatin. Amide II bands of gelatins from both melon and sorghum bug appeared at around 1554 cm^-1, while Amide I bands (1734-1632 cmt) appeared only in melon bug method 2 (MB2) and melon bug method3 (MB3). Microstructures of the insect gelatin examined with the scanning electron microscope showed that melon bug exhibited the finest gelatin network with very small voids. Melon bug gelatin showed finer structure with smaller protein strands and voids than sorghum bug gelatin. 展开更多
关键词 Aspongopus viduatus agonoscelis pubescens GELATIN differential scanning calorimetry fourier transform infrared spectroscopy sodium dodecyl sulphate gel electrophoresis.
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Recovery of high specific area silica and sodium fluoride from sodium hexafluorosilicate 被引量:4
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作者 徐徽 李贵 +1 位作者 程俊峰 刘卫平 《Journal of Central South University》 SCIE EI CAS 2014年第11期4084-4090,共7页
Sodium fluoride and high specific area silica were synthesized by using sodium hexafluorosilicate(Na2Si F6) and sodium carbonate decahydrate(Na2CO3·10H2O). The influencing factors of react temperature, contact ti... Sodium fluoride and high specific area silica were synthesized by using sodium hexafluorosilicate(Na2Si F6) and sodium carbonate decahydrate(Na2CO3·10H2O). The influencing factors of react temperature, contact time, sodium dodecyl sulfate(SDS) and molar ratio of Na2 Si F6 to Na2CO3·10H2O were investigated. The optimum process involves the reaction of 0.075 mol Na2 Si F6 and 150 m L, 0.225 mol Na2CO3·10H2O(molar ratio of 1:3) at 85 °C for 90 min, and 2.0×10-3 mol sodium dodecyl sulfate(SDS) as additive. The results show that the purities of Si O2 and Na F at extraction yields of 96.5% and 98.0% are 91.0% and 98.6%, respectively. The obtained Si O2 were characterized by X-ray diffraction(XRD), scanning electron microscope(SEM), Fourier transform infrared ray(FTIR), differential scanning calorimetry and thermogravimetric analysis(DSC-TGA), N2 absorption/desorption(BET) and laser particle size analyzer. The result demonstrates that Si O2 particles have a high BET surface area of 103 m2/g, and a mean grain size of 985 nm. 展开更多
关键词 recovery sodium hexafluosilicate sodium fluoride silica
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A Facile Route for Synthesis of LiFePO_4/C Cathode Material with Nano-sized Primary Particles 被引量:1
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作者 肖政伟 胡国荣 +1 位作者 杜柯 彭忠东 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第5期590-595,共6页
A facile and practical route was introduced to prepare LiFePO4/C cathode material with nano-sized primary particles and excellent electrochemical performance. LiH2PO4 was synthesized by using H3PO4 and LiOH as raw mat... A facile and practical route was introduced to prepare LiFePO4/C cathode material with nano-sized primary particles and excellent electrochemical performance. LiH2PO4 was synthesized by using H3PO4 and LiOH as raw materials. Then, as-prepared LiH2PO4, reduced iron powder andα-D-glucose were ball-milled, dried and sin-tered to prepare LiFePO4/C. X-ray diffractometry was used to characterize LiH2PO4, ball-milled product and LiFePO4/C. Differential scanning calorimeter-thermo gravimetric analysis was applied to investigate possible reac-tions in sintering and find suitable temperature for LiFePO4 formation. Scanning electron microscopy was em-ployed for the morphology of LiFePO4/C. As-prepared LiH2PO4 is characterized to be in P21cn(33) space group, which reacts with reduced iron powder to form Li3PO4, Fe3(PO4)2 and H2 in ball-milling and sintering. The appro-priate temperature for LiFePO4/C synthesis is 541.3-976.7 ℃. LiFePO4/C prepared at 700 ℃ presents nano-sized primary particles forming aggregates. Charge-discharge examination indicates that as-prepared LiFePO4/C displays appreciable discharge capacities of 145 and 131 mA·h·g^-1 at 0.1 and 1 C respectively and excellent discharge ca-pacity retention. 展开更多
关键词 lithium ion cell reduced iron powder ball-milling LIFEPO4/C nano-sized primary particle
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Effects of solution treatment on mechanical properties and microstructures of Al-Li-Cu-Mg-Ag alloy 被引量:4
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作者 YU Cheng YIN Deng-feng +1 位作者 ZHENG Feng YU Xin-xiang 《Journal of Central South University》 SCIE EI CAS 2013年第8期2083-2089,共7页
Mechanical properties and microstructures of Al-Li-Cu-Mg-Ag alloy after solution treatments were investigated by means of optical microscopy (OM), tensile test, hardness measurement and electrical conductivity test,... Mechanical properties and microstructures of Al-Li-Cu-Mg-Ag alloy after solution treatments were investigated by means of optical microscopy (OM), tensile test, hardness measurement and electrical conductivity test, differential scanning calorimetric (DSC), energy dispersive X-ray (EDX), scanning electron microscopy (SEM) and transition electron microscopy (TEM), respectively The results show that both tensile strength and hardness increase first and then decrease with temperature at constant holding time of 30 min with maximum strength and hardness appearing at 520 ℃. Tensile strength, hardness and elongation of samples treated at 520 ℃ for 30 min are 566 MPa (σb), 512 MPa (σ0.2), HB 148 and 8.23% (δ), respectively. There are certain amount of fine T1 (AI2CuLi) phase dispersing among AI substrates according to TEM images. This may result in mixed fracture morphology with trans-granular and inter-granular delamination cracks observed in SEM images. 展开更多
关键词 Al-Li-Cu-Mg-Ag alloy solution treatment microstructure mechanical properties
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