Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermom...Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermometry of spherite-hosted fluid inclusions from the Xinqiao deposit in the Middle-Lower Yangtze Metallogenic Belt and sheds new light on the ore genesis of the deposit.Considering that infrared light may lead to non-negligible temperature deviations during microthermometry,some tests were first conducted to ensure the accuracy of the microthermometric measurements.The measurement results indicated that using the lowest light intensity of the microscope and inserting an optical filter were effective in minimizing the possible temperature deviations of infrared microthermometry.All sphalerite-hosted fluid inclusions from the Xinqiao deposit were aqueous.They show homogenization temperature ranging from~200 to 350℃,but have two separate salinity groups(1.0 wt%-10 wt%and 15.1 wt%-19.2 wt%NaCl equivalent).The low-salinity group represents sedimentary exhalative(SEDEX)-associated fluids,whereas the high-salinity group results from modification by later magmatic hydrothermal fluids.Combined with published fluid inclusion data,the four-stage fluid evolution of the Xinqiao deposit was depicted.Furthermore,our data suggest that the Xinqiao deposit was formed by twostage metallogenic events including SEDEX and magmatic-hydrothermal mineralization.展开更多
Ultrastructure of Kupffer cells and hepatocytes in liver bioptate was evaluated in a 17-year-old boy with Dubin -Johnson syndrome (D.1S). The liver tissue obtained by needle biopsy was fixed in glutaraldehyde and pa...Ultrastructure of Kupffer cells and hepatocytes in liver bioptate was evaluated in a 17-year-old boy with Dubin -Johnson syndrome (D.1S). The liver tissue obtained by needle biopsy was fixed in glutaraldehyde and paraformaldehyde and routinely processed for electron microscopic analysis. The ultrastructural examinations of liver bioptate revealed the accumulation of membranebound, electron-dense lysosomal granules within the cytoplasm of hepatocytes, characteristic of D.1S. They were located mainly in the vicinity of the biliary pole, and preferentially in the centrilobular region that corresponded to the pigment deposits seen under light microscope. The presence of the granules was accompanied by dilated elements of the granular endoplasmic reticulum and paracrystalline mitochondrial inclusions as well as dilation of the bile canaliculi. The changes in hepatocytes coexisted with marked stimulation and enhanced phagocytic activity of Kupffer cells. This was manifested in the accumulation of pigment deposits within their cytoplasm that corresponded to those observed in hepatocytes. Hyperactive pericentral Kupffer cells which are involved in the response to pigmentary material originating from disintegrated hepatocytes may play an essential role in the development of DJS.展开更多
Based on the harmonic vibration equation, the relationship between IR characteristic peak of fiberglass and Si-O-Si bond angle was deduced, and 1 100 cm^-1 characteristic peak was specifically studied. It is found tha...Based on the harmonic vibration equation, the relationship between IR characteristic peak of fiberglass and Si-O-Si bond angle was deduced, and 1 100 cm^-1 characteristic peak was specifically studied. It is found that 1 100 cm^-1 characteristic peak shifts to higher wave number when Si-O-Si bond angle increases. Taking fused biconical taper (FBT) coupler as an example, the microstructures of the fiber coupler manufactured at different draw- ing speeds were tested with micro infrared spectrum. According to the test results, it is found that the bond angle at the taper region is the largest, the one at the fused region is the second largest, and the one of bare fiber is the smal- lest. The characteristic peaks of fused-taper region shift to higher wave number when drawing speed increases.展开更多
The organization of the higher order structure of chromatin in chicken erythrocytes has been examined withtapping-mode scanning force microscopy under conditionsclose to their native environment. Reproducible highreso...The organization of the higher order structure of chromatin in chicken erythrocytes has been examined withtapping-mode scanning force microscopy under conditionsclose to their native environment. Reproducible highresolution AFM images of chromatin compaction at several levels can be demonstrated. An extended beads-on-astring (width of ~ 15-20nm, height of ~ 2-3nm for eachindividual nucleosome) can be consistently observed. Furthermore, superbeads (width of ~ 40nm, height of ~ 7nm)are demonstrated. Visualization of the solenoid conformation at the level of 30nm chromatin fiber is attained eitherby using AFM or by using electron microscopy. In addition, tightly coiled chromatin fibers (~ 50-60nm and ~90-110nm) can be revealed. Our data suggest that the chromatin in the interphase nucleus of chicken erythrocyte represents a high-order conformation and AFM provides useful high-resolution structural information concerning thefolding pattern of interphase chromatin fibers.展开更多
The structure of the nuclosome core particle of chromatin in chicken erythrocytes has been examined by usingAFM. The 146 hp of DNA wrapped twice around the corehistone octamer are clearly visualized. Both the ends ofe...The structure of the nuclosome core particle of chromatin in chicken erythrocytes has been examined by usingAFM. The 146 hp of DNA wrapped twice around the corehistone octamer are clearly visualized. Both the ends ofentry/exit of linker DNA are also demonstrated. The dimension of the nucleosome core particles is- 1-4 um inheight and ~13-22 um in width. In addition, superbeads(width of - 48-57 urn, beight of-2-3 nm) are occasionallyrevealed, two turns of DNA around the core particles arealso detected.展开更多
Six species of new records collected from intertidal mangrove/non-mangrove and subtidal cave sediments during a mangrove ecological study (1998-2001) and a marine cave expedition (2002) in Hong Kong waters are redescr...Six species of new records collected from intertidal mangrove/non-mangrove and subtidal cave sediments during a mangrove ecological study (1998-2001) and a marine cave expedition (2002) in Hong Kong waters are redescribed. These include two enoplids: Anoplostoma viviparum in Anoplostomatidae and Trissonchulus janetae in Ironidae, two chromadorids:Paracomesoma dubium and Actarjania splendens in Comesomatidae, and two monhysterids: Parodontophora marina and Parodontophora c.f. danker in Axonolaimidae. Five of them are the first records from China. Ecological and taxonomic remarks are provided and discussed in comparison with the original descriptions.展开更多
Nano sized powders of TiO2 (titanium dioxide) and Nb2O5 (Niobium (V) oxide) were used to fabricate TiO2/Nb2O5 composites thin films by EPD (electrophoretic deposition) technique. The metal oxide powders, toget...Nano sized powders of TiO2 (titanium dioxide) and Nb2O5 (Niobium (V) oxide) were used to fabricate TiO2/Nb2O5 composites thin films by EPD (electrophoretic deposition) technique. The metal oxide powders, together with magnesium nitrate hexahydrate pellets, were suspended in propan-2-ol inside an EPD cell. The electrodes, placed 1.2 cm apart, were partially immersed in the suspension and a DC potential applied across them. Key EPD process parameters, which include applied DC electric field, deposition time and solid concentration in suspension, were optimized through visual inspection and from UV-Vis-NIR spectrophotometer spectra. The highest (55%) transmittance was obtained for films with deposition time of 90 s, powder concentration of 0.01 g/40 mL, and 35 V DC (direct current) voltage. XRD micrographs confirmed that TiO2 and Nb2O5 particles were presented in the composite film. SEM (scanning electron microscope) micrographs of the composite electrode thin films showed that porous films of high quality with well controlled morphology were deposited by using the EPD technique.展开更多
Structural changes due to coalification and oxidation influence the coal quality, geochemically and petrologically. Understanding of the coal structures helps to predict the behaviour of coal at various processes. The...Structural changes due to coalification and oxidation influence the coal quality, geochemically and petrologically. Understanding of the coal structures helps to predict the behaviour of coal at various processes. The objective of this paper is to study the changes in organic structure and mineral phase transformation during combustion. Different density fractions were generated and then heated at different temperatures from 200 to 1000 ℃. Petrography, Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) were carried out on all the density fractions aimed to accomplish this objective. Here, through petrography, it was observed that the vitrinite and liptinite macerals disappear at higher temperature while porous inertinite is seen. The inertinite structure is exposed which is assumed by the presence of -OH and C-O-C stretches with the aromatic nucleus (CH) and three to four adjacent H from FTIR spectra. Moreover, it can be concluded that aliphatic groups get collapsed at high temperature. In case of inorganic matter, through XRD and FTIR, it is also revealed that with increasing temperature, clay minerals converted into elemental oxides. Hence, this study is suggesting that the structures of coal are altered by the degree of contact metamorphism.展开更多
Rhombus-like SmCO3OH microplates with the edge lengths ranging from 5 μm to 10 μm and the thickness about 1.5 μm were synthesized through a simple hydrothermal method using urea as the precipitance. The structure a...Rhombus-like SmCO3OH microplates with the edge lengths ranging from 5 μm to 10 μm and the thickness about 1.5 μm were synthesized through a simple hydrothermal method using urea as the precipitance. The structure and properties of the rhombus-like SmCO3OH microplates were characterized by X-ray diffraction, field-emission scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The optical property of the rhombus-like SmCO3OH microplates doped with Eu^3+ was investigated by photoluminescence. A broad and strong emission band at 677 nm was obtained, which can be contributed to producing light conversion film.展开更多
Robert Burns wrote about 700 poems and songs. But the first poem that was translated into Chinese is "A Red, Red Rose". It was collected into a book compiled in 1908 which was published in 1911. It was retranslated ...Robert Burns wrote about 700 poems and songs. But the first poem that was translated into Chinese is "A Red, Red Rose". It was collected into a book compiled in 1908 which was published in 1911. It was retranslated many times at different times, mostly by people who were both poets and translators at the same time. And almost all the translators were famous poets such as Su Manshu, Yuan Shuipai, Wang Zuoliang, Yuan Kejia, and Guo Moruo. These translators had their own unique taste and typical features. This article will present a survey of translation history and at the same time give some comments on different versions.展开更多
The effects of B2O3 addition on both the sintering behavior and microwave dielectric properties of CaO-B2O3-SiO2 (CBS) glass ceramics were investigated by Fourier transform infrared spectroscopy (FTIR), X-ray diff...The effects of B2O3 addition on both the sintering behavior and microwave dielectric properties of CaO-B2O3-SiO2 (CBS) glass ceramics were investigated by Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results show that the increasing amount of B203 causes the increase of the contents of [BO3], [BO4] and [SiO4], which deduces the increase of CaB204 and a-SiO2 and the decrease of CaSiO3 correspondingly. No new phase is observed throughout the entire experiments. A bulk density of 2.54 g/cm3, a thermal expansion coefficient value of 11.95× 10-6 ℃-1 (20-500℃), a dielectric constant er value of 6.42 and a dielectric loss tanδ value of 0.000 9 (measured at 9.7 GHz) are obtained for CBS glass ceramics containing 35%-B203 (mass fraction) sintered at 850 ℃ for 15 min.展开更多
In order to greatly improve adsorption capacity, the diatomite was pillared by polyhydroxyl-aluminum.A series of adsorption tests were conducted to obtain the optimum condition for pillared diatomite synthesis. The sc...In order to greatly improve adsorption capacity, the diatomite was pillared by polyhydroxyl-aluminum.A series of adsorption tests were conducted to obtain the optimum condition for pillared diatomite synthesis. The scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), surface area and porosity analyzer and micro-electrophoresis were used to determine pore structure and surface property.The pillared diatomite attaining the optimal adsorption densities (qe) of Pb^2+ and Cd^2+ was synthesized with the following conditions: Addition of pillaring solution containing Al3+-oligomers with a concentration range of 0.1-0.2 mol/L to a suspension containing Na+-diatomite to obtain the required Al/diatomite ratio of 10 mmol/g; synthesis temperature of 80 ℃ for 120 min; aging at a temperature of 105 ℃ for 16 h. The adsorption capacities of Pb^2+ and Cd^2+ on pillared diatomite increase by 23.79% and 27.36% compared with natural diatomite, respectively. The surface property of pillared diatomite is more favorable for ion adsorption than natural diatomite. The result suggests that diatomite can be modified by pillaring with polyhydroxyl-aluminum to improve its adsorption properties greatly.展开更多
Synthesis of some new compounds containing chromene ring are described in this work. They were synthesized in moderate to good yield, started with Condensation of 7-hydroxy-4-methylcoumarin (1) with ethyl bromoaceta...Synthesis of some new compounds containing chromene ring are described in this work. They were synthesized in moderate to good yield, started with Condensation of 7-hydroxy-4-methylcoumarin (1) with ethyl bromoacetate furnishes ethyl-2-(4-methyl-2-oxo-2H-chromen-7-yloxy) acetate (2). The structures of all the new compounds were confirmed using IR, 1H-NMR spectra and micro analysis, selected members of the synthesized compound were screened for antimicrobial activity. They have shown a wide range of activity from one completely inactive compound to medium active ones.展开更多
A novel synthesis of LiFePO4/C from Fe2O3 with no extra carbon or carbon-containing reductant was introduced: Fe2O3 (+NH4H2PO4)→Fe2P2O7(+Li2CO3+glucose)→LiFePO4/C. X-ray diffractometry (XRD), Fourier trans...A novel synthesis of LiFePO4/C from Fe2O3 with no extra carbon or carbon-containing reductant was introduced: Fe2O3 (+NH4H2PO4)→Fe2P2O7(+Li2CO3+glucose)→LiFePO4/C. X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were utilized to characterize relevant products obtained in the synthetic procedure. The reaction of Fe2P2O7 and Li2CO3 was investigated by thermo-gravimetric and differential thermal analysis (TGA-DTA). Fe2O3 is completely reduced to Fe2P2O7 by NH4H2PO4 at 700 ℃ and Fe2P2O7 fully reacts with Li2CO3 to form LiFePO4 in the temperature range of 663.4-890 ℃. The primary particles of LiFePO4/C samples prepared at 670, 700 and 750 ℃ respectively exhibit uniform morphology and narrow size distribution, 0.5-3 μm for those obtained at 670 and 700 ℃ and 0.5-5 μm for those obtained at 750 ℃. LiFePO4/C (carbon content of 5.49%, mass fraction) made at 670 ℃ shows an appreciable average capacity of 153.2 mA·h/g at 0.1C in the first 50 cycles.展开更多
ZSM-5 zeolite was in-situ synthesized from metakaolin or s alumina sources, respectively. The ZSM-5 zeolite was characterized pinel by incorporating additional silica and by X-ray diffractometry (XRD), scanning elec...ZSM-5 zeolite was in-situ synthesized from metakaolin or s alumina sources, respectively. The ZSM-5 zeolite was characterized pinel by incorporating additional silica and by X-ray diffractometry (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and N2 adsorption measurement. This supported zeolite was tested on the methanol to propylene (MTP) processes. Experimental results showed that the ZSM-5 zeolite exhibited high selectivity for propylene. The yield of propylene on ZSM-5 zeolite made from metakaolin was increased by 17.73%, while that on ZSM-5 zeolite made from spinel was raised by 9.90%, compared to that achieved with the commercial ZSM-5 zeolite. The significant increase in propylene production is probably due to the distinctive morphology of the ZSM-5 zeolite, which possessed a rough external surface covered with sphere-like particles and distribution of small crystals sized at around 400--500 nm. This morphology could help to generate more crystal defects so that more active centers could be exposed to the reaction mixture. In addition, the zeolite product had a gradient pore distribution and many medium Brǒnsted acid sites, both of which might also contribute to the increased propylene production.展开更多
In this study we used l-allyl-3-methyl imidazole formate ([Amim][COOH]) as ionic liquid to pre-treat the cellulose and determined the rate of polymerization and enzymatic hydrolysis. The results showed that pretreat...In this study we used l-allyl-3-methyl imidazole formate ([Amim][COOH]) as ionic liquid to pre-treat the cellulose and determined the rate of polymerization and enzymatic hydrolysis. The results showed that pretreatment with ([Amim][COOH]) significantly decreased the cellulose polymerization. As the pretreatment temperature went up, the enzymatic hydrolysis rate was first increased and then decreased The maximal enzymatic hydrolysis rate was achieved when the pretreatment temperature was 90 ℃. Under the ultrasonic condition, the initial rate of enzmatic hydrolysis for the ionic liquid-treated cellulose was up to 11.10 gL-1h-1, which was 33% increase compared to the untreated cellulose. Scanning Electronic Microscopy (SEM) and Fourier Transform Infrared-Raman Spectroscop (FT-IR) analysis showed that ionic liquidtreated cellulose started to depolymerize. In addition, the cr3'stallinity of the cellulose was significantly decreased after pretreatment with ionic liquid.展开更多
基金supported by the National Key R&D Program of China(2018YFA0702701)the Fundamental Research Funds for the Central Universities(WK3410000015).
文摘Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermometry of spherite-hosted fluid inclusions from the Xinqiao deposit in the Middle-Lower Yangtze Metallogenic Belt and sheds new light on the ore genesis of the deposit.Considering that infrared light may lead to non-negligible temperature deviations during microthermometry,some tests were first conducted to ensure the accuracy of the microthermometric measurements.The measurement results indicated that using the lowest light intensity of the microscope and inserting an optical filter were effective in minimizing the possible temperature deviations of infrared microthermometry.All sphalerite-hosted fluid inclusions from the Xinqiao deposit were aqueous.They show homogenization temperature ranging from~200 to 350℃,but have two separate salinity groups(1.0 wt%-10 wt%and 15.1 wt%-19.2 wt%NaCl equivalent).The low-salinity group represents sedimentary exhalative(SEDEX)-associated fluids,whereas the high-salinity group results from modification by later magmatic hydrothermal fluids.Combined with published fluid inclusion data,the four-stage fluid evolution of the Xinqiao deposit was depicted.Furthermore,our data suggest that the Xinqiao deposit was formed by twostage metallogenic events including SEDEX and magmatic-hydrothermal mineralization.
文摘Ultrastructure of Kupffer cells and hepatocytes in liver bioptate was evaluated in a 17-year-old boy with Dubin -Johnson syndrome (D.1S). The liver tissue obtained by needle biopsy was fixed in glutaraldehyde and paraformaldehyde and routinely processed for electron microscopic analysis. The ultrastructural examinations of liver bioptate revealed the accumulation of membranebound, electron-dense lysosomal granules within the cytoplasm of hepatocytes, characteristic of D.1S. They were located mainly in the vicinity of the biliary pole, and preferentially in the centrilobular region that corresponded to the pigment deposits seen under light microscope. The presence of the granules was accompanied by dilated elements of the granular endoplasmic reticulum and paracrystalline mitochondrial inclusions as well as dilation of the bile canaliculi. The changes in hepatocytes coexisted with marked stimulation and enhanced phagocytic activity of Kupffer cells. This was manifested in the accumulation of pigment deposits within their cytoplasm that corresponded to those observed in hepatocytes. Hyperactive pericentral Kupffer cells which are involved in the response to pigmentary material originating from disintegrated hepatocytes may play an essential role in the development of DJS.
基金Project(50235040) supported bythe National Natural Science Foundation of China project(NCET-040753) supported bythe New Century Excellent Talents in University project(20050533037) supported by the research fund for the Doctoral Program ofHigher Education
文摘Based on the harmonic vibration equation, the relationship between IR characteristic peak of fiberglass and Si-O-Si bond angle was deduced, and 1 100 cm^-1 characteristic peak was specifically studied. It is found that 1 100 cm^-1 characteristic peak shifts to higher wave number when Si-O-Si bond angle increases. Taking fused biconical taper (FBT) coupler as an example, the microstructures of the fiber coupler manufactured at different draw- ing speeds were tested with micro infrared spectrum. According to the test results, it is found that the bond angle at the taper region is the largest, the one at the fused region is the second largest, and the one of bare fiber is the smal- lest. The characteristic peaks of fused-taper region shift to higher wave number when drawing speed increases.
文摘The organization of the higher order structure of chromatin in chicken erythrocytes has been examined withtapping-mode scanning force microscopy under conditionsclose to their native environment. Reproducible highresolution AFM images of chromatin compaction at several levels can be demonstrated. An extended beads-on-astring (width of ~ 15-20nm, height of ~ 2-3nm for eachindividual nucleosome) can be consistently observed. Furthermore, superbeads (width of ~ 40nm, height of ~ 7nm)are demonstrated. Visualization of the solenoid conformation at the level of 30nm chromatin fiber is attained eitherby using AFM or by using electron microscopy. In addition, tightly coiled chromatin fibers (~ 50-60nm and ~90-110nm) can be revealed. Our data suggest that the chromatin in the interphase nucleus of chicken erythrocyte represents a high-order conformation and AFM provides useful high-resolution structural information concerning thefolding pattern of interphase chromatin fibers.
文摘The structure of the nuclosome core particle of chromatin in chicken erythrocytes has been examined by usingAFM. The 146 hp of DNA wrapped twice around the corehistone octamer are clearly visualized. Both the ends ofentry/exit of linker DNA are also demonstrated. The dimension of the nucleosome core particles is- 1-4 um inheight and ~13-22 um in width. In addition, superbeads(width of - 48-57 urn, beight of-2-3 nm) are occasionallyrevealed, two turns of DNA around the core particles arealso detected.
基金funded by National Key Basic Research Program from the Ministry of Science and Technology,People’s Repubfic of China(G 19990437)also supported by the National Natural Science Foundation of China(No.40176033)
文摘Six species of new records collected from intertidal mangrove/non-mangrove and subtidal cave sediments during a mangrove ecological study (1998-2001) and a marine cave expedition (2002) in Hong Kong waters are redescribed. These include two enoplids: Anoplostoma viviparum in Anoplostomatidae and Trissonchulus janetae in Ironidae, two chromadorids:Paracomesoma dubium and Actarjania splendens in Comesomatidae, and two monhysterids: Parodontophora marina and Parodontophora c.f. danker in Axonolaimidae. Five of them are the first records from China. Ecological and taxonomic remarks are provided and discussed in comparison with the original descriptions.
文摘Nano sized powders of TiO2 (titanium dioxide) and Nb2O5 (Niobium (V) oxide) were used to fabricate TiO2/Nb2O5 composites thin films by EPD (electrophoretic deposition) technique. The metal oxide powders, together with magnesium nitrate hexahydrate pellets, were suspended in propan-2-ol inside an EPD cell. The electrodes, placed 1.2 cm apart, were partially immersed in the suspension and a DC potential applied across them. Key EPD process parameters, which include applied DC electric field, deposition time and solid concentration in suspension, were optimized through visual inspection and from UV-Vis-NIR spectrophotometer spectra. The highest (55%) transmittance was obtained for films with deposition time of 90 s, powder concentration of 0.01 g/40 mL, and 35 V DC (direct current) voltage. XRD micrographs confirmed that TiO2 and Nb2O5 particles were presented in the composite film. SEM (scanning electron microscope) micrographs of the composite electrode thin films showed that porous films of high quality with well controlled morphology were deposited by using the EPD technique.
文摘Structural changes due to coalification and oxidation influence the coal quality, geochemically and petrologically. Understanding of the coal structures helps to predict the behaviour of coal at various processes. The objective of this paper is to study the changes in organic structure and mineral phase transformation during combustion. Different density fractions were generated and then heated at different temperatures from 200 to 1000 ℃. Petrography, Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) were carried out on all the density fractions aimed to accomplish this objective. Here, through petrography, it was observed that the vitrinite and liptinite macerals disappear at higher temperature while porous inertinite is seen. The inertinite structure is exposed which is assumed by the presence of -OH and C-O-C stretches with the aromatic nucleus (CH) and three to four adjacent H from FTIR spectra. Moreover, it can be concluded that aliphatic groups get collapsed at high temperature. In case of inorganic matter, through XRD and FTIR, it is also revealed that with increasing temperature, clay minerals converted into elemental oxides. Hence, this study is suggesting that the structures of coal are altered by the degree of contact metamorphism.
文摘Rhombus-like SmCO3OH microplates with the edge lengths ranging from 5 μm to 10 μm and the thickness about 1.5 μm were synthesized through a simple hydrothermal method using urea as the precipitance. The structure and properties of the rhombus-like SmCO3OH microplates were characterized by X-ray diffraction, field-emission scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The optical property of the rhombus-like SmCO3OH microplates doped with Eu^3+ was investigated by photoluminescence. A broad and strong emission band at 677 nm was obtained, which can be contributed to producing light conversion film.
文摘Robert Burns wrote about 700 poems and songs. But the first poem that was translated into Chinese is "A Red, Red Rose". It was collected into a book compiled in 1908 which was published in 1911. It was retranslated many times at different times, mostly by people who were both poets and translators at the same time. And almost all the translators were famous poets such as Su Manshu, Yuan Shuipai, Wang Zuoliang, Yuan Kejia, and Guo Moruo. These translators had their own unique taste and typical features. This article will present a survey of translation history and at the same time give some comments on different versions.
基金Project(2007AA03Z0455) supported by the National High-Technology Research and Development Program of ChinaProject(BE2009168) supported by the Natural Science Foundation of Jiangsu Province in ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institution,China
文摘The effects of B2O3 addition on both the sintering behavior and microwave dielectric properties of CaO-B2O3-SiO2 (CBS) glass ceramics were investigated by Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results show that the increasing amount of B203 causes the increase of the contents of [BO3], [BO4] and [SiO4], which deduces the increase of CaB204 and a-SiO2 and the decrease of CaSiO3 correspondingly. No new phase is observed throughout the entire experiments. A bulk density of 2.54 g/cm3, a thermal expansion coefficient value of 11.95× 10-6 ℃-1 (20-500℃), a dielectric constant er value of 6.42 and a dielectric loss tanδ value of 0.000 9 (measured at 9.7 GHz) are obtained for CBS glass ceramics containing 35%-B203 (mass fraction) sintered at 850 ℃ for 15 min.
基金Project(12JJ8016)supported by the Hunan Provincial Natural Science Foundation of ChinaProject(CX2012B317)supported by Hunan Provincial Innovation Foundation For Postgraduate,ChinaProject(2006180)supported by the Hunan Key Discipline Construction Found of Environmental Science,China
文摘In order to greatly improve adsorption capacity, the diatomite was pillared by polyhydroxyl-aluminum.A series of adsorption tests were conducted to obtain the optimum condition for pillared diatomite synthesis. The scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), surface area and porosity analyzer and micro-electrophoresis were used to determine pore structure and surface property.The pillared diatomite attaining the optimal adsorption densities (qe) of Pb^2+ and Cd^2+ was synthesized with the following conditions: Addition of pillaring solution containing Al3+-oligomers with a concentration range of 0.1-0.2 mol/L to a suspension containing Na+-diatomite to obtain the required Al/diatomite ratio of 10 mmol/g; synthesis temperature of 80 ℃ for 120 min; aging at a temperature of 105 ℃ for 16 h. The adsorption capacities of Pb^2+ and Cd^2+ on pillared diatomite increase by 23.79% and 27.36% compared with natural diatomite, respectively. The surface property of pillared diatomite is more favorable for ion adsorption than natural diatomite. The result suggests that diatomite can be modified by pillaring with polyhydroxyl-aluminum to improve its adsorption properties greatly.
文摘Synthesis of some new compounds containing chromene ring are described in this work. They were synthesized in moderate to good yield, started with Condensation of 7-hydroxy-4-methylcoumarin (1) with ethyl bromoacetate furnishes ethyl-2-(4-methyl-2-oxo-2H-chromen-7-yloxy) acetate (2). The structures of all the new compounds were confirmed using IR, 1H-NMR spectra and micro analysis, selected members of the synthesized compound were screened for antimicrobial activity. They have shown a wide range of activity from one completely inactive compound to medium active ones.
基金Project(2010ZC051)supported by the Natural Science Foundation of Yunnan Province,ChinaProject(2009-041)supported by Analysis and Testing Foundation from Kunming University of Science and Technology,ChinaProject(14118245)supported by the Starting Research Fund from Kunming University of Science and Technology,China
文摘A novel synthesis of LiFePO4/C from Fe2O3 with no extra carbon or carbon-containing reductant was introduced: Fe2O3 (+NH4H2PO4)→Fe2P2O7(+Li2CO3+glucose)→LiFePO4/C. X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were utilized to characterize relevant products obtained in the synthetic procedure. The reaction of Fe2P2O7 and Li2CO3 was investigated by thermo-gravimetric and differential thermal analysis (TGA-DTA). Fe2O3 is completely reduced to Fe2P2O7 by NH4H2PO4 at 700 ℃ and Fe2P2O7 fully reacts with Li2CO3 to form LiFePO4 in the temperature range of 663.4-890 ℃. The primary particles of LiFePO4/C samples prepared at 670, 700 and 750 ℃ respectively exhibit uniform morphology and narrow size distribution, 0.5-3 μm for those obtained at 670 and 700 ℃ and 0.5-5 μm for those obtained at 750 ℃. LiFePO4/C (carbon content of 5.49%, mass fraction) made at 670 ℃ shows an appreciable average capacity of 153.2 mA·h/g at 0.1C in the first 50 cycles.
基金the financial support from National Natural Science Foundation of China(20776124 and 20736011)
文摘ZSM-5 zeolite was in-situ synthesized from metakaolin or s alumina sources, respectively. The ZSM-5 zeolite was characterized pinel by incorporating additional silica and by X-ray diffractometry (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and N2 adsorption measurement. This supported zeolite was tested on the methanol to propylene (MTP) processes. Experimental results showed that the ZSM-5 zeolite exhibited high selectivity for propylene. The yield of propylene on ZSM-5 zeolite made from metakaolin was increased by 17.73%, while that on ZSM-5 zeolite made from spinel was raised by 9.90%, compared to that achieved with the commercial ZSM-5 zeolite. The significant increase in propylene production is probably due to the distinctive morphology of the ZSM-5 zeolite, which possessed a rough external surface covered with sphere-like particles and distribution of small crystals sized at around 400--500 nm. This morphology could help to generate more crystal defects so that more active centers could be exposed to the reaction mixture. In addition, the zeolite product had a gradient pore distribution and many medium Brǒnsted acid sites, both of which might also contribute to the increased propylene production.
文摘In this study we used l-allyl-3-methyl imidazole formate ([Amim][COOH]) as ionic liquid to pre-treat the cellulose and determined the rate of polymerization and enzymatic hydrolysis. The results showed that pretreatment with ([Amim][COOH]) significantly decreased the cellulose polymerization. As the pretreatment temperature went up, the enzymatic hydrolysis rate was first increased and then decreased The maximal enzymatic hydrolysis rate was achieved when the pretreatment temperature was 90 ℃. Under the ultrasonic condition, the initial rate of enzmatic hydrolysis for the ionic liquid-treated cellulose was up to 11.10 gL-1h-1, which was 33% increase compared to the untreated cellulose. Scanning Electronic Microscopy (SEM) and Fourier Transform Infrared-Raman Spectroscop (FT-IR) analysis showed that ionic liquidtreated cellulose started to depolymerize. In addition, the cr3'stallinity of the cellulose was significantly decreased after pretreatment with ionic liquid.