The complex(C_5H_5)2 Yb(NC4H4)(OC_4H_8) crystallizes in orthorhombic system with space group Pnma and a=15.552(4),b=12.491(3),c=8. 711(3),V=1692. 2(7),Z=4 and Dc=1.733 g/cm3. Crystal study has shown that the molecule ...The complex(C_5H_5)2 Yb(NC4H4)(OC_4H_8) crystallizes in orthorhombic system with space group Pnma and a=15.552(4),b=12.491(3),c=8. 711(3),V=1692. 2(7),Z=4 and Dc=1.733 g/cm3. Crystal study has shown that the molecule has crystallographic mirror symmetry.The Yb(Ⅲ) has a distorted tetrahedral coordination geometry.展开更多
Dinuclear palladium complex (Et_4N)_2[Pd_2(mp)_2 (mpH)_2 (mpH=_2-SC_6H_4OH ) (M_r = 971. 95 ) is prepared in a reaction of sodium 2-mercaptophenolate (Na_2mp) with PdCl_2. It crystallizes in monoclinic with space grou...Dinuclear palladium complex (Et_4N)_2[Pd_2(mp)_2 (mpH)_2 (mpH=_2-SC_6H_4OH ) (M_r = 971. 95 ) is prepared in a reaction of sodium 2-mercaptophenolate (Na_2mp) with PdCl_2. It crystallizes in monoclinic with space group P2_1/n, a=9. 088(1),b=17. 851 (4), c=12. 932(2) , β= 93. 21 (1)°, V=2094. 7(7), D_c=1. 54 g/cm￣3, F(000) = 1000, Z=2, and final R= 0. 044 and R_w= 0. 055 for 3090 reflections (I≥3σ(I)). Structure analysis revealed the multifunction chelating character of mp functions as S_tO_t(t for terminal) and S_bOH (b for bridging) in the complex.展开更多
The title compound [Cu(dtp) PPh3]2 (dtp=S2,P(OEt)2) was prepared by heating the mononuclear compound Cu(dtp)(PPh3)2 in CH3CN solution.It crystallizes in the triclinic space group P1 with parameters a=9.71 6(5),b=11.02...The title compound [Cu(dtp) PPh3]2 (dtp=S2,P(OEt)2) was prepared by heating the mononuclear compound Cu(dtp)(PPh3)2 in CH3CN solution.It crystallizes in the triclinic space group P1 with parameters a=9.71 6(5),b=11.026(5),c=12.475(4) A.α=78.16(3)°,β=102. 64(4), γ=114.34(4)°,V=1178(1)A 3,Z=1,Dc=1.44 g/cm3,MoKα(λ=0.71069 A) μ=12. 48cm-1,F(000)=528.Final R=0.041.Rω= 0. 052 for 3653 unique intensity data(I≥3σ(I)).The molecule of the title compound can be viewed as a centrosymmetric dimer with two[Cu(dtp)(PPh3)] units,which are bridged by two S atoms belonging to the dtp ligands.The exact planar[Cu2S2] core and two[CuS2P] four-membered rings form a chair conformation.The Cu…Cu distance is 2.991(5) A.展开更多
The title complex, mercury bridged biferrocene trinuclear complex Hg(FcL)2. Bis (S-methyl-N- (1-ferrocenyl-1-methyl) methylenedithiocarbazate) mercury,Crystallizes in space group Pbca with a =19. 510 (4), b=19. 921 (5...The title complex, mercury bridged biferrocene trinuclear complex Hg(FcL)2. Bis (S-methyl-N- (1-ferrocenyl-1-methyl) methylenedithiocarbazate) mercury,Crystallizes in space group Pbca with a =19. 510 (4), b=19. 921 (5), c=15. 581 (3)A. V=6095(3) A, Z=8,M.=863. 12, Dc=1.881 g/cm3; u=19. 24 cm-1 and F(000) = 3376. The final refinement of 2455 observed reflections is converged with R= 0. 043 and Rw=0.047. X-ray crystal structure analysis revealed that the coordinationgeometry of Hg atom is a distorted tetrahedron with two Hg-N bonds and two Hg- S bonds. The Schiff-base ligand loses a proton from its tautomeric thiol form and is cryordianted to the Hg aotm uia the mercapto sulphur and the β-nitrogen atoms.展开更多
文摘The complex(C_5H_5)2 Yb(NC4H4)(OC_4H_8) crystallizes in orthorhombic system with space group Pnma and a=15.552(4),b=12.491(3),c=8. 711(3),V=1692. 2(7),Z=4 and Dc=1.733 g/cm3. Crystal study has shown that the molecule has crystallographic mirror symmetry.The Yb(Ⅲ) has a distorted tetrahedral coordination geometry.
文摘Dinuclear palladium complex (Et_4N)_2[Pd_2(mp)_2 (mpH)_2 (mpH=_2-SC_6H_4OH ) (M_r = 971. 95 ) is prepared in a reaction of sodium 2-mercaptophenolate (Na_2mp) with PdCl_2. It crystallizes in monoclinic with space group P2_1/n, a=9. 088(1),b=17. 851 (4), c=12. 932(2) , β= 93. 21 (1)°, V=2094. 7(7), D_c=1. 54 g/cm￣3, F(000) = 1000, Z=2, and final R= 0. 044 and R_w= 0. 055 for 3090 reflections (I≥3σ(I)). Structure analysis revealed the multifunction chelating character of mp functions as S_tO_t(t for terminal) and S_bOH (b for bridging) in the complex.
文摘The title compound [Cu(dtp) PPh3]2 (dtp=S2,P(OEt)2) was prepared by heating the mononuclear compound Cu(dtp)(PPh3)2 in CH3CN solution.It crystallizes in the triclinic space group P1 with parameters a=9.71 6(5),b=11.026(5),c=12.475(4) A.α=78.16(3)°,β=102. 64(4), γ=114.34(4)°,V=1178(1)A 3,Z=1,Dc=1.44 g/cm3,MoKα(λ=0.71069 A) μ=12. 48cm-1,F(000)=528.Final R=0.041.Rω= 0. 052 for 3653 unique intensity data(I≥3σ(I)).The molecule of the title compound can be viewed as a centrosymmetric dimer with two[Cu(dtp)(PPh3)] units,which are bridged by two S atoms belonging to the dtp ligands.The exact planar[Cu2S2] core and two[CuS2P] four-membered rings form a chair conformation.The Cu…Cu distance is 2.991(5) A.
文摘The title complex, mercury bridged biferrocene trinuclear complex Hg(FcL)2. Bis (S-methyl-N- (1-ferrocenyl-1-methyl) methylenedithiocarbazate) mercury,Crystallizes in space group Pbca with a =19. 510 (4), b=19. 921 (5), c=15. 581 (3)A. V=6095(3) A, Z=8,M.=863. 12, Dc=1.881 g/cm3; u=19. 24 cm-1 and F(000) = 3376. The final refinement of 2455 observed reflections is converged with R= 0. 043 and Rw=0.047. X-ray crystal structure analysis revealed that the coordinationgeometry of Hg atom is a distorted tetrahedron with two Hg-N bonds and two Hg- S bonds. The Schiff-base ligand loses a proton from its tautomeric thiol form and is cryordianted to the Hg aotm uia the mercapto sulphur and the β-nitrogen atoms.
