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循环预处理对铁基非晶微观结构及晶化相析出的影响 被引量:4
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作者 傅明喜 熊震东 黄军庆 《特种铸造及有色合金》 CAS CSCD 北大核心 2010年第10期887-890,共4页
分析了深冷循环处理、预退火循环处理及深冷+预退火循环处理方法对铁基非晶结构和晶化析出相的影响。DSC检测结果表明,循环处理改变了非晶的晶化参数Tg和Tx,DSC检测曲线上出现"焓弛豫峰";TEM检测显示,预处理后样品仍保持非晶... 分析了深冷循环处理、预退火循环处理及深冷+预退火循环处理方法对铁基非晶结构和晶化析出相的影响。DSC检测结果表明,循环处理改变了非晶的晶化参数Tg和Tx,DSC检测曲线上出现"焓弛豫峰";TEM检测显示,预处理后样品仍保持非晶的衍射特征,但在非晶基体上有纳米晶析出;SEM和TEM分析表明,预处理后,非晶基体中团簇合并,尺寸增大,形成"葡萄状"团簇结构;预处理后晶化时,在非晶中析出不同类型和尺度的晶化相。这表明,通过元素的扩散,预处理促进非晶基体中形成新的原子团簇,导致团簇的合并与长大,改变了非晶的晶化热力学与动力学过程。 展开更多
关键词 铁基非合金 循环处理 晶化析出相 团簇
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Fe_(63)Ni_1Al_5Ga_2P_(9.65)B_(4.6)Si_3C_(6.75)Co_5非晶合金的晶化行为研究 被引量:4
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作者 熊震东 傅明喜 黄军庆 《功能材料》 EI CAS CSCD 北大核心 2011年第B04期335-337,345,共4页
采用XRD、DSC检测技术,采用连续升温晶化和等温退火晶化方法,研究分析了Fe63Ni1Al5-Ga2P9.65B4.6Si3C6.75Co5非晶薄带的晶化动力学行为和晶化过程中晶化相的析出过程。结果表明,该非晶合金的玻璃转变和晶化行为均具有显著的动力学特征。... 采用XRD、DSC检测技术,采用连续升温晶化和等温退火晶化方法,研究分析了Fe63Ni1Al5-Ga2P9.65B4.6Si3C6.75Co5非晶薄带的晶化动力学行为和晶化过程中晶化相的析出过程。结果表明,该非晶合金的玻璃转变和晶化行为均具有显著的动力学特征。Kissinger法计算得到的Eg、Ex、Ep1、Ep2分别为750、340、432、689kJ/mol,Eg Ex,表明合金具有较好的热稳定性。合金晶化过程为:非晶→非晶+α-Fe→非晶+α-Fe+Fe2P+Fe3P→α-Fe+Fe2P+Fe3P+Fe3C(Al,Si)+Fe5PB2+SiC。合金的晶化类型为初晶型和随后的共晶型反应。 展开更多
关键词 FE基非 动力学 激活能 析出
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Isothermal annealing of cold-rolled Al-Mn-Fe-Si alloy with different microchemistry states 被引量:2
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作者 黄科 李彦军 Knut MARTHINSEN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第12期3840-3847,共8页
Microstructural evolution of a cold-rolled Al-Mn-Fe-Si alloy during annealing was studied. Except the as-cast variant, two other different homogenizations were considered, one gave a high density of fine dispersiods p... Microstructural evolution of a cold-rolled Al-Mn-Fe-Si alloy during annealing was studied. Except the as-cast variant, two other different homogenizations were considered, one gave a high density of fine dispersiods providing a considerable Zener drag influencing the softening behavior while the other gave a lower density of coarser dispersoid structure providing a much smaller drag effect. The gradual microstructural evolutions during annealing for the three variants were captured by interrupting annealing at different time. Effects of microchemistry state on recrystallization kinetics, recrystallized grain structure and texture were characterized by EBSD. It is demonstrated that the actual softening kinetics, final microstructure and texture are a result of delicate balance between processing condition and microchemistry state. Strong concurrent precipitation takes place in the case with high concentration of Mn in solid solution, which suppresses nucleation and retards recrystallization and finally leads to grain structure of coarse elongated grains dominated by a P texture component together with a ND-rotated cube component. On the contrary, when solute content of Mn is low and pre-existing dispersoids are relatively coarser, faster recrystallization kinetics is exhibited together with an equiaxed grain structure with mainly cube texture. 展开更多
关键词 aluminum alloy Al-Mn-Fe-Si alloy recrystallization kinetics MICROCHEMISTRY PRECIPITATION recrystallization texture
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