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晶种和晶化模式对金属有机骨架MIL-101合成的影响 被引量:2
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作者 陈恒 陈绍云 +1 位作者 赵文平 张永春 《功能材料》 EI CAS CSCD 北大核心 2014年第23期23115-23121,共7页
采用晶种导向法、静态水热晶化法和动态水热晶化法合成金属有机骨架MIL-101,通过XRD、SEM、N2物理吸附等表征方法考察了晶种和晶化模式对MIL-101产物收率和晶粒尺寸的影响。结果表明,MIL-101原粉作为晶种在合成过程中可溶解成(或解离成... 采用晶种导向法、静态水热晶化法和动态水热晶化法合成金属有机骨架MIL-101,通过XRD、SEM、N2物理吸附等表征方法考察了晶种和晶化模式对MIL-101产物收率和晶粒尺寸的影响。结果表明,MIL-101原粉作为晶种在合成过程中可溶解成(或解离成)适当的结构单元作为晶体生长核心,缩短晶化诱导期,提高产物收率。晶化模式影响MIL-101产物的收率和晶粒尺寸。动态晶化合成的MIL-101产物收率较静态晶化产物收率高,搅拌速率小于200r/min时收率随搅拌速率增加而增加。动态晶化合成的MIL-101产物晶粒尺寸较静态晶化产物晶粒尺寸小,随搅拌速率增加而减小。 展开更多
关键词 配合物 金属有机骨架MIL-101 合成 晶化模式
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升温速率和晶化模式对固相转化合成SAPO-5的影响 被引量:2
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作者 刘旭光 陈圣博 张宝泉 《化工学报》 EI CAS CSCD 北大核心 2013年第2期735-741,共7页
固相转化法有利于合成硅取代型磷酸铝分子筛(SAPO-5)。采用XRD、SEM、EDS表征方法研究了升温速率和晶化模式对SAPO-5分子筛结构的影响。结果表明,在高升温速率(140℃.h-1)和低升温速率(5.8℃.h-1)下能合成出纯SAPO-5分子筛,在中等升温速... 固相转化法有利于合成硅取代型磷酸铝分子筛(SAPO-5)。采用XRD、SEM、EDS表征方法研究了升温速率和晶化模式对SAPO-5分子筛结构的影响。结果表明,在高升温速率(140℃.h-1)和低升温速率(5.8℃.h-1)下能合成出纯SAPO-5分子筛,在中等升温速率(17.5~70℃.h-1)下则有SAPO-34分子筛与SA-PO-5伴生。此外,晶化模式对SAPO-5分子筛的形貌有显著影响。在中等升温速率下,动态晶化形成的SAPO-5分子筛为球形,静态晶化则为六边形片状,但Si的取代机制均可能为SM3取代。在高升温速率和低升温速率下,晶化模式不影响SAPO-5分子筛的形貌。而Si在动态晶化时为SM2取代,静态晶化时为SM3取代。 展开更多
关键词 SAPO-5 程序升温速率 晶化模式 取代机制
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Nb含量对FeZrNbB合金结构及晶化模式的影响
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作者 赵书华 孙亚明 +1 位作者 于万秋 华中 《吉林师范大学学报(自然科学版)》 2008年第1期104-105,121,共3页
采用机械合金化法制备Fe68Zr20-xNbxB12(x=0,5,10,15)合金粉末,利用XRD、SEM和DTA等测试手段对该合金系进行测试,研究Nb含量对FeZrNbB合金系的结构及晶化模式的影响.结果表明:添加5 at%的Nb元素抑制非晶合金的形成,Nb含量为10,15 at%时... 采用机械合金化法制备Fe68Zr20-xNbxB12(x=0,5,10,15)合金粉末,利用XRD、SEM和DTA等测试手段对该合金系进行测试,研究Nb含量对FeZrNbB合金系的结构及晶化模式的影响.结果表明:添加5 at%的Nb元素抑制非晶合金的形成,Nb含量为10,15 at%时,又促进了非晶合金的形成;随Nb含量的增加,颗粒尺寸先减小后增加;Nb含量的增加使晶化模式由一次晶化向共晶晶化转变. 展开更多
关键词 机械合金 颗粒尺寸 晶化模式
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Hard Switching Process Optimization for Selected Transistor Suited for High Power and High Frequency Operation
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作者 M. Frivaldsloy P. Drgona P. Spanik 《Journal of Energy and Power Engineering》 2010年第12期36-42,共7页
This paper deals with optimization of hard switching commutation mode for high-power, high-frequency consumer applications for selected power transistor. The experimental investigation of suitable settings is outgoing... This paper deals with optimization of hard switching commutation mode for high-power, high-frequency consumer applications for selected power transistor. The experimental investigation of suitable settings is outgoing from simulation analysis of hard switching for different transistor structures. For these purposes, the simulation models of power semiconductor switches with high level of validity have been used. After that, the experimental analysis for selected transistor was done with change of parameters that are influencing commutation process of transistor. Target of such kind of analysis was to reach as low switching losses as possible, achieving high power density and efficiency of power system, without utilization of improved switching techniques such as resonant switching. The results confirm that this task is realizable through use of progressive semiconductor devices such as SiC diodes and/or through latest families of MOSFET devices. 展开更多
关键词 TRANSISTOR COMMUTATION LOSSES frequency simulation experimental analysis converter.
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Morphological evolution of the solid-liquid interface near grain boundaries during directional solidification
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作者 XING Hui WANG CaiFang +1 位作者 WANG JianYuan CHEN ChangLe 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第12期2174-2180,共7页
Morphological evolution of the solid-liquid interface near grain boundaries has been studied during directional solidification of succinonitrile-based transparent alloys (SCN-0.9wt%DCB). Experimental results show that... Morphological evolution of the solid-liquid interface near grain boundaries has been studied during directional solidification of succinonitrile-based transparent alloys (SCN-0.9wt%DCB). Experimental results show that the grain boundary provides the starting point of morphological instability of the solid-liquid interface. The initial perturbation near the grain boundary is significantly larger than other perturbations on the interface. The initial shape of the interface and the competition between the thermal direction and preferred crystalline orientations determine the subsequent growth pattern selections. The temporal variations of the curvature radius of cell/ridge tips near the grain boundary have also been studied when the instability occurs. This process is divided into three parts. As the pulling velocity increases, dendrites at the grain boundary grow in two different directions to form a bicrystal microstructure. Side branches on either side of the dendrite exhibit different growth patterns. 展开更多
关键词 grain boundary solid-liquid interface directional solidification growth directions
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