An electrochemical study on the redox behavior of indium in the eutectic LiCl-KCl system at 450 ℃ was carried out with the transient techniques of cyclic voltammetry and chronopotentiometry on an inert molybdenum ele...An electrochemical study on the redox behavior of indium in the eutectic LiCl-KCl system at 450 ℃ was carried out with the transient techniques of cyclic voltammetry and chronopotentiometry on an inert molybdenum electrode. The reduction of In(Ⅲ) was found to be a two-step process involving In(Ⅲ)/In(Ⅰ) and In(Ⅰ)/In couples at the potentials of about-0.4 and-0.8 V versus Ag/AgCl, respectively. The redox mechanism was further confirmed by the theoretical evaluation of the number of transferred electrons based on cyclic voltammetry and characterizations of the precipitates generated by the potentiostatic electrolysis. The diffusion coefficients of indium ions in the eutectic LiCl-KCl melt at 450 ℃ were estimated by cyclic voltammetry and chronopotentiometry. The results obtained through the two methods are in fair agreement, delivering an average diffusion coefficient of approximately 1.8×10^(-5)cm^(2)/s for In(Ⅲ), and 1.4×10^(-4)cm^(2)/s for In(Ⅰ).展开更多
Surface Penetrating Radar (SPR) is a recently developed technology for non-destructive testing. It can be used to image and interpret the inner structure of the reinforced concrete. This paper gives the details about ...Surface Penetrating Radar (SPR) is a recently developed technology for non-destructive testing. It can be used to image and interpret the inner structure of the reinforced concrete. This paper gives the details about a compact and handheld SPR developed recently for reinforced concrete structure detection. The center operation frequency of the radar is 1.6 GHz. Not only it has fast acquisition ability, but also it can display the testing result on the LCD screen in real-time. The testing results show that the radar has a penetrating range of more than 30 cm, and a lateral resolution better than 5 cm. The performance validates that the radar can meet the application requirements for reinforced concrete structure detection.展开更多
基金the National Natural Science Foundation of China(Nos.51904003,U1703130,51704011)the China Postdoctoral Science Foundation(No.2019M651466)the Foundation of Anhui Province Key Laboratory of Metallurgical Engineering&Resources Recycling of China(Nos.SKF18-01,SKF19-05).
文摘An electrochemical study on the redox behavior of indium in the eutectic LiCl-KCl system at 450 ℃ was carried out with the transient techniques of cyclic voltammetry and chronopotentiometry on an inert molybdenum electrode. The reduction of In(Ⅲ) was found to be a two-step process involving In(Ⅲ)/In(Ⅰ) and In(Ⅰ)/In couples at the potentials of about-0.4 and-0.8 V versus Ag/AgCl, respectively. The redox mechanism was further confirmed by the theoretical evaluation of the number of transferred electrons based on cyclic voltammetry and characterizations of the precipitates generated by the potentiostatic electrolysis. The diffusion coefficients of indium ions in the eutectic LiCl-KCl melt at 450 ℃ were estimated by cyclic voltammetry and chronopotentiometry. The results obtained through the two methods are in fair agreement, delivering an average diffusion coefficient of approximately 1.8×10^(-5)cm^(2)/s for In(Ⅲ), and 1.4×10^(-4)cm^(2)/s for In(Ⅰ).
文摘Surface Penetrating Radar (SPR) is a recently developed technology for non-destructive testing. It can be used to image and interpret the inner structure of the reinforced concrete. This paper gives the details about a compact and handheld SPR developed recently for reinforced concrete structure detection. The center operation frequency of the radar is 1.6 GHz. Not only it has fast acquisition ability, but also it can display the testing result on the LCD screen in real-time. The testing results show that the radar has a penetrating range of more than 30 cm, and a lateral resolution better than 5 cm. The performance validates that the radar can meet the application requirements for reinforced concrete structure detection.
