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晶格能效应
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作者 张灿久 《长沙水电师院自然科学学报》 1989年第6期51-56,共6页
本文首次给出了晶格能效应的确切涵义,即对于同一族内不同元素的阳离子与同一种阴离子组成的离子化合物,它们相对于稳定单质的热力学稳定性往往是小阴离子与小阳离子组成的晶体最稳定;大阴离子与大阳离子组成的晶体最稳定。通过Born—Ha... 本文首次给出了晶格能效应的确切涵义,即对于同一族内不同元素的阳离子与同一种阴离子组成的离子化合物,它们相对于稳定单质的热力学稳定性往往是小阴离子与小阳离子组成的晶体最稳定;大阴离子与大阳离子组成的晶体最稳定。通过Born—Haber热化学循环法,得出了上述两种不同的热稳定性递变倾向主要是由于阴离子大小不同时,随阳离子半径递增,晶体的晶格能递减幅度不同造成的。晶格能效应是一个有用的经验规则,应用时注意它所定义的范围。 展开更多
关键词 晶格能效应 晶体 热力学稳定性
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Interface of transition metal oxides at the atomic scale 被引量:1
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作者 Tong-Tong Shang Xin-Yu Liu Lin Gu 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2016年第9期1-9,共9页
Remarkable phenomena arise at well-defined heterostructures, composed of transition metal oxides, which is absent in the bulk counterpart, providing us a paradigm for exploring the various electron correlation effects... Remarkable phenomena arise at well-defined heterostructures, composed of transition metal oxides, which is absent in the bulk counterpart, providing us a paradigm for exploring the various electron correlation effects. The functional properties of such heterostructures have attracted much attention in the microelectronic and renewable energy fields. Exotic and unexpected states of matter could arise from the reconstruction and coupling among lattice, charge, orbital and spin at the interfaces. Aberration-corrected scanning transmission electron microscopy (STEM) is a powerful tool to visualize the lattice structure and electronic structure at the atomic scale. In the present study some novel phenomena of oxide heterostructures at the atomic scale are summarized and pointed out from the perspective of electron microscopy. 展开更多
关键词 INTERFACE transition metal oxides STEM strong correlation
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