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制氢装置中变气不锈钢管件开裂失效分析及对策 被引量:6
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作者 柴保群 张红梅 《石油化工腐蚀与防护》 CAS 2014年第1期59-64,共6页
制氢装置空冷器入口中变气不锈钢管件多处焊缝热影响区出现穿透性裂纹,通过对失效管件进行宏观检查、射线检测、渗透检测、硬度测试、化学成分分析、金相组织观察、电镜扫描和残余应力分析等检测试验,确定所有裂纹均为沿晶裂纹,呈树枝... 制氢装置空冷器入口中变气不锈钢管件多处焊缝热影响区出现穿透性裂纹,通过对失效管件进行宏观检查、射线检测、渗透检测、硬度测试、化学成分分析、金相组织观察、电镜扫描和残余应力分析等检测试验,确定所有裂纹均为沿晶裂纹,呈树枝状分布并在热影响区及母材内扩展;断口形貌具有典型的冰糖块特征,能谱分析显示有大量S、局部存在Cl,晶界Cr质量分数达到20.0%,超过基体中Cr含量;管件局部硬度超过190HB,裂纹尖端的残余应力超过了0Cr18Ni9的屈服应力。从材料方面、介质因素与应力条件三个方面综合分析后,认为管件失效的原因是H2SCO2-H2O酸性腐蚀环境下氯离子、硫化物和残余应力共同作用的晶界应力腐蚀开裂。对失效管线进行了材质升级,消除了装置存在的隐患,并提出了有关的预防措施和建议。 展开更多
关键词 制氢装置 奥氏体不锈钢 管件 氯离子硫化物 残余应力 晶界应力腐蚀
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Grain boundary pre-precipitation and its contribution to enhancement of corrosion resistance of Al-Zn-Mg alloy 被引量:3
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作者 李慧中 姚三成 +3 位作者 梁霄鹏 陈永辉 刘超 黄岚 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第10期2523-2531,共9页
High temperature pre-precipitation (HTPP)took place in7005 alloy at various temperatures after solution treatment and itsinfluence on mechanical properties, corrosion behaviors and microstructure of the alloy was in... High temperature pre-precipitation (HTPP)took place in7005 alloy at various temperatures after solution treatment and itsinfluence on mechanical properties, corrosion behaviors and microstructure of the alloy was investigated using tensile test, intergranular corrosion (IGC) test, slow strain rate testing (SSRT), together with microstructural examinations. It is found that Vickers hardness of the aged alloy decreases gradually with decreasing the HTPP temperature, and almost a reverse trend of electrical conductivity is found compared to the hardness changes. Depending on the changes, two HTPP temperaturesof 440 and 420℃ were chosen for comparative study. Results reveal that HTPP alloy tempers exhibit higher resistance to stress corrosion cracking (SCC) and IGC than none pre-precipitate one with an acceptable strength loss due to the substantial enhancement of distribution discontinuity of the coarse grain boundary precipitates (GBPs), and the coarsening and interspacing effect on GBPs becomes more obvious with decreasing the pre-precipitation temperature. 展开更多
关键词 7005 aluminum alloy grain boundary pre-precipitation stress corrosion cracking intergranular corrosion microstructure
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