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富锂层状氧化物正极材料研究进展 被引量:1
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作者 陈宇方 李宇杰 +2 位作者 郑春满 谢凯 陈重学 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2017年第8期792-800,共9页
富锂层状氧化物正极材料(xLi_2MnO_3·(1–x)LiMO_2(M=Ni_yMn_zCo_(1-y-z)….)理论容量高、价格低廉,是新一代锂离子电池正极材料的候选之一。本文概述了该正极材料的结构,分析了其在电化学活化过程与循环过程中结构的演变,探讨了... 富锂层状氧化物正极材料(xLi_2MnO_3·(1–x)LiMO_2(M=Ni_yMn_zCo_(1-y-z)….)理论容量高、价格低廉,是新一代锂离子电池正极材料的候选之一。本文概述了该正极材料的结构,分析了其在电化学活化过程与循环过程中结构的演变,探讨了结构变化对正极材料电化学性能的影响规律,并概括了目前针对该类正极材料电化学性能提升所开展的离子掺杂和表面改性的研究工作,展望了未来富锂层状氧化物正极材料的发展方向。 展开更多
关键词 富锂层状氧化物 活化和循环过程 晶相结构演变 表面改性 离子掺杂 综述
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Influence of minor Sc additions on grain refinement and microstructure characteristics of a high Zn-containing Al-Zn-Mg-Cu-Zr alloy 被引量:3
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作者 WEN Kai LI Xi-wu +5 位作者 XIONG Bai-qing LIU Hong-lei WANG Ying-jun LI Zhi-hui ZHANG Yong-an LI Ya-nan 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第3期780-794,共15页
In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cas... In the present work, scandium elements with a series of contents(0.06 wt.%, 0.10 wt.%, 0.14 wt.%,0.17 wt.%, 0.20 wt.% and 0.25 wt.%) were added in a high Zn-containing Al-Zn-Mg-Cu-Zr alloy and the corresponding as-cast microstructure characteristics including grains and phases were thoroughly investigated. The results indicated that fine grain boundaries existed in these alloys and fine MgZn2phases discontinuously distributed on them. Besides,AlZnMgCu eutectic phases and Sc, Zr-containing phases with flocculent morphology were observed. As scandium contents vary from 0.06 wt.% to 0.17 wt.%, the average grain size continuously decreased and its equiaxial characteristics were strengthened. Meanwhile, the content of AlZnMgCu eutectic phase showed a decrease trend. When scandium contents were 0.20 wt.% and 0.25 wt.%, no further enhancement on grain refinement was observed, so as to the reduction of AlZnMgCu eutectic phase content. Besides, Sc, Zr-containing phases with blocky morphology were observed and the alloy with a scandium content of 0.25 wt.% possessed a larger amount of blocky Sc, Zr-containing phase than the alloy with a scandium content of 0.20 wt.%. Grain refinement and reduction of AlZnMgCu eutectic phase content associated with scandium addition were discussed. 展开更多
关键词 Al-Zn-Mg-Cu-Zr alloy high zinc content microstructure Sc addition grain refinement phase evolution
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