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晶种面织构对溶液化学法生长ZnO纳米棒的影响 被引量:4
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作者 赵娟 靳正国 刘晓新 《无机化学学报》 SCIE CAS CSCD 北大核心 2005年第11期1643-1648,共6页
采用化学沉积法,在ZnO晶种面上研究了纳米棒于70℃过饱和硝酸锌/氢氧化钠溶液中的定向生长。通过sol-gel法在玻璃基底上引入了ZnO的晶种面,通过热处理温度、冷却方式和拉膜速度改变其织构,重点考察其对ZnO纳米棒生长形态的影响。采用XRD... 采用化学沉积法,在ZnO晶种面上研究了纳米棒于70℃过饱和硝酸锌/氢氧化钠溶液中的定向生长。通过sol-gel法在玻璃基底上引入了ZnO的晶种面,通过热处理温度、冷却方式和拉膜速度改变其织构,重点考察其对ZnO纳米棒生长形态的影响。采用XRD和SEM分析了不同晶种面以及相应棒晶的生长形态。结果表明,随热处理温度的提高,晶种长大,相应的棒晶直径从25nm增加到50nm,1.5h的生长棒长达约800nm。300 ̄400℃热处理、急冷或低的拉膜速度条件下制备的晶种面具有更高的晶体取向和较少的表面缺陷。从而导致生长面高的成核密度,使得ZnO纳米棒能够在垂直于基底的方向上择优生长。 展开更多
关键词 ZNO纳米棒 晶种面 溶液化学法 体生长
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Synthesis and optical properties research of gold nanoparticles with different morphologies 被引量:1
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作者 徐宏妍 薛晨阳 +4 位作者 张强 王慧娟 袁艳玲 孙东 熊继军 《Journal of Measurement Science and Instrumentation》 CAS 2014年第1期96-102,共7页
This paper presents an approach to synthesis of gold nanoparticles with different morphologies and investigation of the relationship between morphologies and their optical properties.Spherical gold nanoparticles with ... This paper presents an approach to synthesis of gold nanoparticles with different morphologies and investigation of the relationship between morphologies and their optical properties.Spherical gold nanoparticles with different sizes are synthesized via reduction method.Using seed-mediated solution growth method,gold nanoparticles with shuttle,star and stick shapes can be obtained.The sizes and morphologies of the gold nanoparticles are characterized by transmission electron microscopy (TEM).The characterization results illustrate the growth process of the gold nanoparticles with different morphologies.Absorption spectroscopy and Raman spectroscopy measurements are performed to demonstrate the relationship between the morphologies and optical properties.The results of Raman characterization show that the gold nanoparticles with different morphologies can be used to probe molecules with different concentrations. 展开更多
关键词 star-shaped gold nanoparticles spherical gold nanoparticles surface-enhanced Raman scattering (SERS) seed-mediated solution growth method
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