氧化物单晶晶纤的生长规律

用LHPG法可以生长出优质单晶纤维,其条件是:(1)熔区长度调整到1_c=K(D+d),其中K在0.55～0.75间,其值与晶体表面能有关;(2)在V_f=(D/d),V_s条件下,选择合适的V_f可以使△d/d极小。(3)源棒均匀,即△D=0。式中D、d别为源棒和晶纤直径,V_f和V_s分别为提拉晶纤和输送源棒速率。文中用晶体生长理论讨论了上述规律。

Y_3Ga_5O_(12)单晶及其晶纤的生长

本文介绍了用CZ法生长Nd:Y_3Ga_5O_(12)(YGG)大单晶。YGG熔体易挥发,且其对流花样呈涡流状。X射线衍射相分析表明挥发物为Ga_2O_3。加大炉内保护气N_2压力或用98％N_2及2％O_2的混合气体,都可明显的抑制Ga_2O_3的挥发。常压激光加热基座生长(LHPG)法不能生长YGG单晶光纤。对晶纤的X射线能谱分析(EDS)表明,YGG中Ga_2O_3探发很严重,且Ga从中心迁移到边缘,造成晶纤中组分极不均匀。

YAP和YAG单晶晶纤中Nd^(3+)离子分布

用 X 射线电子能量色散谱(EDS)对 YAP 和 YAG 单晶晶纤中 Nd 离子分布作了测量。Nd离子沿晶纤的纵向分布基本均匀,但沿晶纤的径向分布是不均匀的、中心高而边缘低。用区熔生长理论对实验结果进行了讨论。

铌酸锂单晶光纤包层研究

通过镁离子内扩散铌酸锂单晶光纤，以改变晶纤表层的折射率，首次在国内实现了沿不同轴向生长、不同掺杂的铌酸锂单晶光纤的芯－包层波导结构。通过匹配扩散温度、扩散时间、ＭｇＯ膜厚等扩散参数及选择合适的晶纤直径，实现了晶纤具有阶跃和抛物折射率分布的包层，并对包层晶纤的模式特性进行了观察，得到低次模传输。

铌酸锂单晶光纤包层研究

通过镁离子内扩散铌酸锂晶光纤，以改变晶纤表层的折射率，首次在国内实现了沿不同的轴向生长，不同掺杂的铌酸锂单晶光纤的芯－包层波导结构。通过匹配扩散温度，扩散时间，ＭｇＯ膜厚等扩散参数及选择合适的晶纤直径，实现了晶纤具有阶跃和抛物折射率分布的包层，并对包层晶纤的模式特性进行了观察，得到低次模传输。

Polyetherketoneketone/carbon fiber composites with an amorphous interface prepared by solution impregnation

Interfacial adhesion between carbon fibers(CF)and polyetherketoneketone(PEKK)is a key factor that affects the mechanical performances of their composites.It is therefore of great importance to impregnate the CF bundles with PEKK as effi-ciently as possible.We report that PEKK with a good dispersion in a mixed solution of 4-chlorophenol and 1,2-dichloroethane can be introduced onto CF surfaces by solution impregnation and curing at 280,320,340 and 360℃.The excellent wettability or infiltra-tion of the PEKK solution guarantees a full covering and its tight binding to CFs,making it possible to evaluate the interfacial shear strength(IFSS)with the microdroplet method.The interior of the CF bundles is completely and uniformly filled with PEKK by solu-tion impregnation,leading to a high interlaminar shear strength(ILSS).The maximum IFSS and ILSS reached 107.8 and 99.3 MPa,respectively.Such superior shear properties are ascribed to the formation of amorphous PEKK in the small spaces between CFs.

纳米粉ZnO的制备及低温热容研究

采用液相沉淀新方法制备了ＺｎＯ纳米晶超微粉末，ＸＲＤ和ＴＥＭ分析结果表明，平均粒径为１８ｎｍ，纤锌矿晶相结构，粒径分布范围较窄．化学分析和ＩＣＰ联合测定，其纯度＞９９．９％．在７８～３７０Ｋ温区，用高精密全自动量热仪测定了热容，拟合出热容随温度变化的多项式方程： Ｃｐ＝ ４０．０４２＋ ２４．５５４Ｘ＋ ０．９３０３３Ｘ２＋ ２．１６４９Ｘ３一 １．８３８９Ｘ４；并与粗晶 ＺｎＯ热容文献值进行比较，从能量的角度分析了各热容曲线不同的原因．

Recent advances in immobilized enzymes on nanocarriers

Recent progress in nanotechnology has provided high-performance nanomaterials for enzyme immobilization.Nanobiocatalysts combining enzymes and nanocarriers are drawing increasing attention because of their high catalytic performance,enhanced stabilities,improved enzyme-substrate affinities,and reusabilities.Many studies have been performed to investigate the efficient use of cellulose nanocrystals,polydopamine-based nanomaterials,and synthetic polymer nanogels for enzyme immobilization.Various nanobiocatalysts are highlighted in this review,with the emphasis on the design,preparation,properties,and potential applications of nanoscale enzyme carriers and nanobiocatalysts.

Supercontinuum Generationin Normal-dispersion Photonic Crystal Fiber Using Picosecond Pulse

Studied is the Super-continuum(SC) generation of a normal-dispersion photonic crystal fiber(PCF) using picosecond pulse excitation. In experimental analyses, a 237 nm broadband infrared continuum was generated pumped at 1 550 nm(normal dispersion regime) by 1.6 ps pulses from an erbium-doped fiber laser. In addition, we conduct the numerical analyses of SC based on generalized nonlinear Schr dionger equation. The results have been applied to investigate the dominant physical processes underlie the generation of SC. We conclude that dispersion, self-phase modulation(SPM),four-wave-mixing(FWM) and Raman scattering are determinants of SC generation rather than fission of soliton in normal-dispersion PCF.

Switchable dual-wavelength erbium-doped fiber laser with a tilted fiber grating

A dual-wavelength erbium doped fiber laser with a tilted fiber Bragg grating and photonic crystal fiber is proposed and demonstrated. In the laser, a 2W EDFA provides gain for all the laser lines; the highly nonlinear photonic crystal fiber introduces dynamic energy transfer between the two wavelengths caused by four wave mixing effect, so that a stable dual- wavelength oscillation at room temperature is implemented. Different switching modes can be achieved by adjusting the lateral offset between the fiber grating and the guiding single mode fiber or by varying the state of polarization in the laser cavity. The maximum of output power of the laser has reached 314mW.

New High Nonlinear and Dispersion Flattened Photonic Crystal Fiber

A new high nonlinear dispersion flattened photonic crystal fiber is proposed. This fiber has three-fold symmetry core. The doped region in the core and the big air-holes in the 1-st ring can make high nonlinearity in the PCF. And the small air-holes in the 1-st ring and the radial increasing diameters air-holes rings in cladding can be used to turn the dispersion properties of the PCF. We can achieve the optimized optical properties by carefully selecting the PCF's structure parameters. A PCF with flattened dispersion is obtained. The dispersion is within ±0.8 ps·nm-1·km-1 from 1.50 μm to 1.62 μm. The nonlinear coefficient is about 12.645 6 W-1·km-1, the fundamental mode area is about 10.257 9 μm2 and the birefringence is about 3.086 96×10-5 at 1.55 μm. This work may be useful for effective design and fabrication of dispersion flattened photonic crystal with high nonlinearities.

Analysis of photonic crystal fiber sensor character

The special character of a PCF which is used as a gas or liquid sensor is discussed. The field distribution is analyzed when the solid core PCF is injected with different medium that has different relative dielectric constant （or refractive index）. And the experiential formulas of the relation between refractive index of some kinds of liquid and their concentration are given, in order to measure the concentration of the relative liquid. At the same time, the effect of propagation constant on PCF sensor character is also discussed. Furthermore, the photonic medium relative dielectric constant, when it is injected with . band-gap （PBG） of PCF （PBG-PCF） is calculated at different different medium. That is the principle basis for this kind of PCF sensors.

Dispersion Properties of TIRPCF under Compton Scattering

The dispersion properties in the short wavelength region of total internal reflective photonic crystal fiber(TIRPCF) in Compton scattering have been studied by using the model of the equivalent twin waveguide soliton coupling, dispersion management solitons and effective refractive index. It is shown that the positive dispersion of the cladding waveguide of TIRPCF and the negative dispersion of its core waveguide are quickly increased by the square of the collision non-elastic composition between the electron and photons, and they are lessened by the increase of the electron absorption photon number. Under the one-photon nonlinear Compton scattering, the method of the compensated probing laser diffraction by the phase hole induced by the stationary pumping laser in the cladding waveguide enables the average dispersion value of TIRPCF to be close to zero, and the zero dispersion point quickly shifts to the short wavelength region.

Spectrally Sliced Pulse Source Based on Supercontinuum Generation in Dispersion-Flattened Photonic Crystal Fiber

Designed is dispersion-flattened photonic crystal fiber（PCF） with small normal dispersion for generating flat wideband supercontinuum （SC）, and demonstrated is spectrally sliced pulse source which utilizes supereontinuum generated in dispersion-flattened photonic crystal fiber. The results show that the fiber characterized by flattened dispersion with small normal dispersion is suitable for flat wideband supercontinuum generation. In the process of spectral broadening, self-phase modulation plays a dominant role. By filtering the supercontinuum, multi-wavelength pulses can be obtained over a wide spectral range.

Pulse-width compression based on photonic crystal fiber

According to the characteristics of high-order solitons,compressed picosecond pulses are numerically simulated in the photonic crystal fiber (PCF),by means of split-step Fourier method. The results show that,PCF enables input pulse with lower peak power to form high-order solitons for the purpose of femtosecond pulse-width compression. For example,60- femtosecond pulse width was made for 1-ps initial pulse width only over the distance of 2.2 m.Besides,shorter optimum fiber length for compression and higher compression ratio could be obtained on the premise of pre-chirp technique.

Transmission spectrum method to measure the photonic bandgap of hollow-core photonic crystal fiber

A full-vector plane-wave method is introduced, particularly in calculating the photonic crystal in-plane photonic bandgap of a 2D triangular structure. Using numerical simulation, we can obtain the in-plane bandgap structure of a hollow-core photonic crystal fiber. In the experiments, we measured the transmission spectra of a hollow-core photonic crystal fiber and a silica rod. And using the numerical calculation we can get the relative transmission spectrum of a hollow-core photonic crystal fiber. Compared with the result of theoretical simulation, we found that they are in accordance with each other, i.e. they have the same bandgap in about the same normalized frequency.

Experimental investigation of hollow-core photonic crystal fibers with five photonic band-gaps

The hollow-core photonic crystal fibers （HC-PCFs） with integrity structure have been fabricated with an improved twice stack-and-draw technique. The transmission spectrum shows that five photonic band-gaps within 450-1100 nm have been obtained.And the green fight transmission in the HC-PCFs has been observed remarkably.

Effect of content of Al_2O_3 and MgO on crystallization of blast furnace slag during fiber formation

The simulation of blast furnace slag was prepared by pure chemical reagents.Test methods like DSC,XRD and SEM were used to study the effect of Al2O3 and MgO content on crystallization of blast furnace slag during fiber formation.The results show that as Al2O3 and MgO contents in the sample changed,blast furnace slag was crystallized at the average temperature below 1232 K.When the ratio of Mg/Al in the samples is 0.6 calculated by Kissinger equation,crystallization activation energy is at the maximum value and the system is in the most stable condition.The sample crystallization phases are mainly calcium akermanite(2CaO?MgO?2SiO2)and gehlenite(2CaO?Al2O3?SiO2).Secondary crystallization phases are anorthite(CaAl2Si2O8),wollastonite minerals(WOLLA)and pyroxene minerals(cPyrA).Meanwhile,the principal crystallization phases of the samples are different types and have different contents,and the microstructures of the sample sections are different due to the difference between MgO/Al2O3 ratio.