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γ-氧化铝表面性质与晶面特性关系研究 被引量:6
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作者 季洪海 苗升 +5 位作者 马波 沈智奇 凌凤香 王少军 肖锦春 符荣 《精细石油化工》 CAS CSCD 北大核心 2014年第5期38-43,共6页
以AlCl3·6H2O为铝源,NaOH为沉淀剂,通过控制n(OH-)∶n(Al3+)比例,采用水热合成法制得棒状及片状γ-Al2O3纳米粒子。应用红外光谱、X射线衍射、透射电镜等手段研究了两种氧化铝表面性质与晶面特性。结果表明:棒状氧化铝表面以{100}... 以AlCl3·6H2O为铝源,NaOH为沉淀剂,通过控制n(OH-)∶n(Al3+)比例,采用水热合成法制得棒状及片状γ-Al2O3纳米粒子。应用红外光谱、X射线衍射、透射电镜等手段研究了两种氧化铝表面性质与晶面特性。结果表明:棒状氧化铝表面以{100}晶面族为主,片状氧化铝表面以{110}晶面族为主。棒状氧化铝表面有两种类型的羟基,分别属于(110)晶面HO-μ2-AlⅥ和(100)晶面HO-μ3-AlⅥ。片状氧化铝表面有4种类型的羟基,分别属于(111)晶面HO-μ3-AlⅥ、HO-μ2-AlⅥ和(110)晶面HO-μ2-AlⅥ和HO-μ3-AlⅥ。两种氧化铝表面以L酸为主,B酸含量较低,片状氧化铝表面L酸量约为棒状氧化铝表面L酸量1.5倍。这两种氧化铝表面性质的区别是由于两种氧化铝表面晶面特性不同而引起表面配位不饱和铝离子的类型和数量不同造成的。 展开更多
关键词 氧化铝 表面性质 晶面特性 关系
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Free dendritic growth model incorporating interfacial nonisosolutal nature due to normal velocity variation 被引量:1
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作者 李述 谷志慧 +3 位作者 李大勇 吴双双 陈明华 冯宇 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第10期3363-3369,共7页
Considering both the effects of the interfacial normal velocity dependence of solute segregation and the local nonequilibrium solute diffusion,an extended free dendritic growth model was analyzed.Compared with the pre... Considering both the effects of the interfacial normal velocity dependence of solute segregation and the local nonequilibrium solute diffusion,an extended free dendritic growth model was analyzed.Compared with the predictions from the dendritic model with isosolutal interface assumption,the transition from solutal dendrite to thermal dendrite moves to higher undercoolings,i.e.,the region of undercoolings with solute controlled growth is extended.At high undercoolings,the transition from the mainly thermal-controlled growth to the purely thermal-controlled growth is not sharp as predicted by the isosolute model,but occurs in a range of undercooling,due to both the effects of the interfacial normal velocity dependence of solute segregation and the local nonequilibrium solute diffusion.Model test indicates that the present model can give a satisfactory agreement with the available experimental data for the Ni-0.7% B(mole fraction) alloy. 展开更多
关键词 dendritic growth interfacial nonisosolutal nature MODELING binary alloy
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Mixed P3HT/PCBM Organic Thin-Film Transistors: Relation between Morphology and Electrical Characteristics
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作者 Khairul Anuar Mohamad Afishah Alias +3 位作者 Ismail Saad Bablu Kumar Gosh Katsuhiro Uesugi Hisashi Fukuda 《Journal of Chemistry and Chemical Engineering》 2014年第5期476-481,共6页
The mixed P3HT (poly(3-hexylthiophene)) and [6,6]-PCBM (phenyl C61-butyric acid methyl ester) organic thin films were investigated for electronic structure using UV-Vis spectrophotometer and PESA (photo-electro... The mixed P3HT (poly(3-hexylthiophene)) and [6,6]-PCBM (phenyl C61-butyric acid methyl ester) organic thin films were investigated for electronic structure using UV-Vis spectrophotometer and PESA (photo-electron spectroscopy in air). Furthermore, ESR (electron spin resonance) and AFM (atomic force microscopy) were used to investigate the surface morphology and molecular orientation, respectively. ESR analysis indicated the molecular orientation of the P3HT crystalline in the blend thin films, which the crystalline oriented normal to the substrate with distribution of 35°. AFM images indicated that the surface morphology of P3HT film was affected by the presence of PCBM nanoparticles. Solution-processed OTFTs (organic thin-film transistors) based on P3HT/PCBM blend thin film in a top source-drain contact structure was fabricated, and the electrical characteristics of the devices were also investigated. A unipolar property with p-channel characteristics were obtained in glove box measurement. 展开更多
关键词 Organic semiconductor P3HT PCBM P3HT/PCBM blend thin film organic thin-film transistor.
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Polycrystalline diamond MESFETs by Au-mask technology for RF applications 被引量:2
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作者 FENG ZhiHong WANG JingJing +7 位作者 HE ZeZhao DUN ShaoBo YU Cui LIU JinLong ZHANG PingWei GUO Hui LI ChengMing CAI ShuJun 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第4期957-962,共6页
Metal-semiconductor field effect transistors (MESFETs) were fabricated on H-terminated polycrystalline diamond.The DC characteristics of the p-channel MESFET showed a maximum drain current density of 204 mA/mm at a ga... Metal-semiconductor field effect transistors (MESFETs) were fabricated on H-terminated polycrystalline diamond.The DC characteristics of the p-channel MESFET showed a maximum drain current density of 204 mA/mm at a gate-source voltage of 6 V,and a maximum transconductance of 20 mS/mm at a gate-source voltage of 1.5 V.The small signal S-parameters of MESFET with 2 100 m gate width and 2 m gate length were measured.An extrinsic cut-off frequency (fT) of 1.7 GHz and the maximum oscillation frequency (fmax) of 2.5 GHz were obtained,which was the first report on diamond MESFETs with RF characteristics in China. 展开更多
关键词 DIAMOND wide band gap semiconductors carbon based electronics semiconductor devices RF performances
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Superconductivity in two-dimensionalη-Mo3C2 films
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作者 Wei Shi Junyao Yu +5 位作者 Tao Xu Weilin Liu Xianlei Huang Jie Xu Litao Sun Libo Gao 《Science China Materials》 SCIE EI CSCD 2021年第3期664-672,共9页
Two-dimensional(2D)superconductors have intriguing physical properties and abundant potential applications.Recently,2D superconductingα-Mo2C and facecentered cubic Mo2C have been controllably prepared and they bring ... Two-dimensional(2D)superconductors have intriguing physical properties and abundant potential applications.Recently,2D superconductingα-Mo2C and facecentered cubic Mo2C have been controllably prepared and they bring new viewpoints to carbon-based superconductivity.Although molybdenum carbides(Mo-Cs)have multiple crystalline stacking orders,there are still few structures reported for the lack of higher energy supply during growth.In this study,we report a two-step vapor deposition method to grow superconducting η-Mo3C2 films with different thicknesses,with the assistance of controllable plasma power.The grownη-Mo3C2 films show polycrystalline characteristics,but they still present superior superconductivity.The 3.0-nm-thick film has the superconducting transition temperature of 5.38 K,and its electrical performances follow truly 2D superconducting transitions.This study will not only exhibit a robust superconductingη-Mo3C2 ultrathin film,but also provides a convenient growth way to realize more carbide-based heterostructures for future device applications. 展开更多
关键词 2D superconductor η-Mo3C2 superconducting film two-step vapor deposition MXene
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Output characteristics of Nd:Gd VO_4 crystals laser with dual c-axis orthogonal gains end-pumped by two fibercoupled diode lasers
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作者 林海峰 熊飞兵 黄剑平 《Optoelectronics Letters》 EI 2015年第1期30-32,共3页
The output characteristics of neodymium-doped gadolinium vanadate(Nd:GdVO4) crystals laser with dual c-axis orthogonal gains end-pumped by two fiber-coupled diode lasers are investigated. With two 1 W semiconductor di... The output characteristics of neodymium-doped gadolinium vanadate(Nd:GdVO4) crystals laser with dual c-axis orthogonal gains end-pumped by two fiber-coupled diode lasers are investigated. With two 1 W semiconductor diode lasers pumping, the output power of TEM00 laser is 920 m W, and the optical conversion efficiency is close to 46%. By changing the relative orientations of both Nd:Gd VO4 crystals, the polarization characteristics of laser are varied. In particular, by keeping the c-axes of two Nd:Gd VO4 crystals orthogonal to each other and adjusting two diode pump lasers to operate at the same power level, the completely unpolarized light is obtained. 展开更多
关键词 oscillator resonant optoelectronic modulator longitudinal branch adding microwave demonstration constructs
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