High volumetric power density （VPD） is the basis for the commercial success of micro-tubular solid oxide fuel cells （mtSOFCs）. To find maximal VPD （MVPD） for anode-supported mtSOFC （as-mtSOFC）, the effects of ...High volumetric power density （VPD） is the basis for the commercial success of micro-tubular solid oxide fuel cells （mtSOFCs）. To find maximal VPD （MVPD） for anode-supported mtSOFC （as-mtSOFC）, the effects of geometric parameters on VPD are analyzed and the anode thickness, tan, and the cathode length, lea, are identified as the key design parameters. Thermo-fluid electrochemical models were built to examine the dependence of the electrical output on the cell parameters. The multiphysics model is validated by reproducing the experimental I-V curves with no adjustable parameters. The optimal lea and the corresponding MVPDs are then determined by the multiphysics model for 20 combinations of rin, the inner tube radius, and tan. And all these optimization are made at 1073.15 K. The results show that： （i） significant performance improvement may be achieved by geometry optimization, （ii） the seemingly high MVPD of 11 and 14 W/cm^3 can be easily realized for as-mtSOFC with single- and double-terminal anode current collection, respectively. Moreover, the variation of the area specific power density with/cac（2 mm, 40 mm） is determined for three representative （tin, tan） combinations. Besides, it is demonstrated that the current output of mtSOFC with proper geometric parameters is comparable to that of planar SOFC.展开更多
The non-isothermal kinetics of mechanochemical reduction of Ag2O with graphite was studied by DSC and TGA with a model of fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin. To evalua...The non-isothermal kinetics of mechanochemical reduction of Ag2O with graphite was studied by DSC and TGA with a model of fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin. To evaluate the kinetics parameters, Ag2O–graphite mixture of as-received and milled for 2 and 4 h samples were selected. Based on the results obtained by Vyazovkin method calculation, however, the difference between the maximum and minimum values of activation energy is less than 20%-30%of the average activation energy （（99.38±2.36） kJ/mol） and thermal decomposition of mechanically activated Ag2O for 2 h is a multi-step process. Moreover, the thermal decomposition of mechanically activated Ag2O–graphite powder activated for 4 h is a single-step process （the average activation energy=（93.68±2.26） kJ/mol）. The kinetics modeling shows that the complexity of thermal decomposition of as-received Ag2O–graphite mixture is higher than that of the others. While, the autocatalytic tendency of as-received Ag2O–graphite mixture is lower than that of the others.展开更多
Along with the economic development and the acceleration of urbanization,urban construction land expands rapidly in China,and has resulted in a series of socio-economic problems.This article summarized the major point...Along with the economic development and the acceleration of urbanization,urban construction land expands rapidly in China,and has resulted in a series of socio-economic problems.This article summarized the major points of controlling the unchecked and rash expansion of construction land in the academic circle,and analyzed the problems of regulating the expansion of construction land from three aspects.First,this article analyzed the relationships between socio-economic development and urbanization from the historical viewpoints,and pointed out that the expansion of construction land is a historical phenomenon which will be surely appeared in the development of human race.Second,the authors utilized two-sector model to analyze the importance of urbanization in the socio-economic development from the academic angles.At last,the authors utilize four-quadrant model and bidrent curve model to analyze the influence that brought by the strict control of construction land expansion.Through analysis,this article drew some conclusions.First,the expansion of construction land is a phenomenon which will surely appear in the social development.It is impossible to accomplish the national modernization on the basis of dualistic structure between urban and rural areas.Second,under the function of rent gradient gap,strict control of construction land expansion will not only obtain the anticipated effects,but also cause a series of socio-economic problems,such as land-levying contradiction,the appearance of limited property right house,and being dependant on lease instead of expropriation.Third,unreasonable policies and governmental behaviors are the roots of the unchecked and rash expansion of urban construction land.Based on these conclusions,this article proposed that three transformations should be realized to regulate the unchecked and rash expansion of construction land:transfers from quantity regulation to quality regulation,from direct regulation to indirect regulation,and from single-measure regulation to multi-measures regulation.展开更多
In this paper,a new method for curve and surface modelling is introduced which generates curves and surfaces by recursively cutting and grinding polygons and polyhedra.It is a generalization of the existing corner-cut...In this paper,a new method for curve and surface modelling is introduced which generates curves and surfaces by recursively cutting and grinding polygons and polyhedra.It is a generalization of the existing corner-cutting methods.A lot of properties,such as geometric continuity,representation,shape-preserving,and the algorithm are studied which show that such curves and surfaces are suitable for geometric designs in CAD,computer graphics and their application fields.展开更多
The theoretical light curves of contact binaries are calculated with and without putting in the contact binary evolution model.Firstly,we do not use the contact binary evolution model.A comparison of the light curve i...The theoretical light curves of contact binaries are calculated with and without putting in the contact binary evolution model.Firstly,we do not use the contact binary evolution model.A comparison of the light curve is performed with and without the deformation caused by rotation and tides.It shows that the light curve presents many differences,especially on the bottom and top.Secondly,we adopt the contact binary model [Huang R Q,et al.Chin J Astron Astrophys,2007,7:235-244;Song H F,et al.Chin J Astron Astrophys,2007,7:539-550] and compute the theoretical light curve with and without rotational and tidal effects by studying three binary systems(with low-,intermediate-and high-mass components).The bottom and top of the theoretical light curves are discussed and compared to observations.The results show that taking into account the rotational effect has a better agreement with observations than without it.Therefore,the deformation of the light curve of contact binaries caused by rotation and tides is very important.Meanwhile,the rotational and tidal effect can advance the start of the semi-detached,contact phase and the time of mass-reversal.展开更多
The emission and contact drying kinetics of the paper mill sludge (PMS) were studied through experiments carried out in a paddle dryer. To get a better understanding of its drying mechanism, a penetration model develo...The emission and contact drying kinetics of the paper mill sludge (PMS) were studied through experiments carried out in a paddle dryer. To get a better understanding of its drying mechanism, a penetration model developed by Tsotsas and Schlünder (1986) was used to simulate the drying kinetics of the PMS. The result indicated that this kinetics could be divided into three phases: pasty, lumpy and granular phases, and could be successfully simulated by the penetration model as the related sludge parameters were integrated into the model. The emission rate curves of the volatile compounds (VCs) were interrelated to the drying rate curve of the PMS, especially for volatile fatty acids (VFAs) and ammonia in this study.展开更多
基金This work was supported by the National Natural Science Foundation of China （No.11374272 and No.11574284） and the Collaborative Innovation Center of Suzhou Nano Science and Technology.
文摘High volumetric power density （VPD） is the basis for the commercial success of micro-tubular solid oxide fuel cells （mtSOFCs）. To find maximal VPD （MVPD） for anode-supported mtSOFC （as-mtSOFC）, the effects of geometric parameters on VPD are analyzed and the anode thickness, tan, and the cathode length, lea, are identified as the key design parameters. Thermo-fluid electrochemical models were built to examine the dependence of the electrical output on the cell parameters. The multiphysics model is validated by reproducing the experimental I-V curves with no adjustable parameters. The optimal lea and the corresponding MVPDs are then determined by the multiphysics model for 20 combinations of rin, the inner tube radius, and tan. And all these optimization are made at 1073.15 K. The results show that： （i） significant performance improvement may be achieved by geometry optimization, （ii） the seemingly high MVPD of 11 and 14 W/cm^3 can be easily realized for as-mtSOFC with single- and double-terminal anode current collection, respectively. Moreover, the variation of the area specific power density with/cac（2 mm, 40 mm） is determined for three representative （tin, tan） combinations. Besides, it is demonstrated that the current output of mtSOFC with proper geometric parameters is comparable to that of planar SOFC.
文摘The non-isothermal kinetics of mechanochemical reduction of Ag2O with graphite was studied by DSC and TGA with a model of fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin. To evaluate the kinetics parameters, Ag2O–graphite mixture of as-received and milled for 2 and 4 h samples were selected. Based on the results obtained by Vyazovkin method calculation, however, the difference between the maximum and minimum values of activation energy is less than 20%-30%of the average activation energy （（99.38±2.36） kJ/mol） and thermal decomposition of mechanically activated Ag2O for 2 h is a multi-step process. Moreover, the thermal decomposition of mechanically activated Ag2O–graphite powder activated for 4 h is a single-step process （the average activation energy=（93.68±2.26） kJ/mol）. The kinetics modeling shows that the complexity of thermal decomposition of as-received Ag2O–graphite mixture is higher than that of the others. While, the autocatalytic tendency of as-received Ag2O–graphite mixture is lower than that of the others.
基金founded by the National S&T Pillar Program (Grant no.2007BAC15B03)the Project for Knowledge Innovation Program of CAS (Grant no.066U0111SZ)
文摘Along with the economic development and the acceleration of urbanization,urban construction land expands rapidly in China,and has resulted in a series of socio-economic problems.This article summarized the major points of controlling the unchecked and rash expansion of construction land in the academic circle,and analyzed the problems of regulating the expansion of construction land from three aspects.First,this article analyzed the relationships between socio-economic development and urbanization from the historical viewpoints,and pointed out that the expansion of construction land is a historical phenomenon which will be surely appeared in the development of human race.Second,the authors utilized two-sector model to analyze the importance of urbanization in the socio-economic development from the academic angles.At last,the authors utilize four-quadrant model and bidrent curve model to analyze the influence that brought by the strict control of construction land expansion.Through analysis,this article drew some conclusions.First,the expansion of construction land is a phenomenon which will surely appear in the social development.It is impossible to accomplish the national modernization on the basis of dualistic structure between urban and rural areas.Second,under the function of rent gradient gap,strict control of construction land expansion will not only obtain the anticipated effects,but also cause a series of socio-economic problems,such as land-levying contradiction,the appearance of limited property right house,and being dependant on lease instead of expropriation.Third,unreasonable policies and governmental behaviors are the roots of the unchecked and rash expansion of urban construction land.Based on these conclusions,this article proposed that three transformations should be realized to regulate the unchecked and rash expansion of construction land:transfers from quantity regulation to quality regulation,from direct regulation to indirect regulation,and from single-measure regulation to multi-measures regulation.
文摘In this paper,a new method for curve and surface modelling is introduced which generates curves and surfaces by recursively cutting and grinding polygons and polyhedra.It is a generalization of the existing corner-cutting methods.A lot of properties,such as geometric continuity,representation,shape-preserving,and the algorithm are studied which show that such curves and surfaces are suitable for geometric designs in CAD,computer graphics and their application fields.
基金supported by the National Natural Science Foundation of China (Grant No.10933002)
文摘The theoretical light curves of contact binaries are calculated with and without putting in the contact binary evolution model.Firstly,we do not use the contact binary evolution model.A comparison of the light curve is performed with and without the deformation caused by rotation and tides.It shows that the light curve presents many differences,especially on the bottom and top.Secondly,we adopt the contact binary model [Huang R Q,et al.Chin J Astron Astrophys,2007,7:235-244;Song H F,et al.Chin J Astron Astrophys,2007,7:539-550] and compute the theoretical light curve with and without rotational and tidal effects by studying three binary systems(with low-,intermediate-and high-mass components).The bottom and top of the theoretical light curves are discussed and compared to observations.The results show that taking into account the rotational effect has a better agreement with observations than without it.Therefore,the deformation of the light curve of contact binaries caused by rotation and tides is very important.Meanwhile,the rotational and tidal effect can advance the start of the semi-detached,contact phase and the time of mass-reversal.
基金Project (No. 2007C03003) supported by the Key Project of Science and Technology of Zhejiang Province, China
文摘The emission and contact drying kinetics of the paper mill sludge (PMS) were studied through experiments carried out in a paddle dryer. To get a better understanding of its drying mechanism, a penetration model developed by Tsotsas and Schlünder (1986) was used to simulate the drying kinetics of the PMS. The result indicated that this kinetics could be divided into three phases: pasty, lumpy and granular phases, and could be successfully simulated by the penetration model as the related sludge parameters were integrated into the model. The emission rate curves of the volatile compounds (VCs) were interrelated to the drying rate curve of the PMS, especially for volatile fatty acids (VFAs) and ammonia in this study.
