瑞毒霉在白花曼陀罗中消解动态研究

用Rp－HPLC对病毒霉在白花曼陀罗花和叶中的消解动态进行了研究。其色谱柱为ODS－C18柱，流动相为MeOH－H2O（6：4，V／V），检测波长为264nm；瑞毒霉的最小检出量为2．56×10－9g。样品用硅胶小柱纯化。对白花曼陀罗花和叶的瑞毒霉添加回收率为73．56％～75．56％，RSD为0．48％～3．27％。瑞毒霉在白花曼陀罗叶和花中的消解方程和半衰期分别为C＝64．4131e－0．2119t，C＝194．31663e-0．4743t和3．27d，1．46d。

Cascade Kalman filter for gravity anomaly distortion correction based on second order potential model

Using a gravity anomaly covariance function based on the second-order Ganssian Markov gravity anomaly potential model, the state equation of a gravity anomaly signal is obtained in marine gravimetry. Combined with the system state equation and the measurement equation, a new method of the cascade Kalman filter is proposed and applied to the correction of gravity anomaly distortion. In the signal processing procedure, an inverse Kalman filter is used to restore the gravity anomaly signal and high frequency noises first. Then an adaptive Kalman filter, which uses the gravity anomaly state equation as the system equation, is set to estimate the actual gravity anomaly data. Emulations and experiments indicate that both the cascade Kalman filter method and the single inverse Kalman filter method are effective in alleviating the distortion of the gravity anomaly signal, but the performance of the cascade Kalman filter method is better than that of the single inverse Kalman filter method.

New approach of Kalman filter to nonlinear system

In order to achieve higher accuracy in nonlinear/non-Gaussian state estimation, this paper proposes a new unscented Kalman filter (UKF). It uses a deterministic sampling approach. We choose the unscented transformation (UT) scaling parameters α=0.85, β=2, l=0 to construct 2n + 1 sigma points. These sigma points completely capture the mean and covariance of the Gaussian random variables of the nonlinear system Yi=F(Xi). Simulation results show that the posterior mean and covariance of the sigma points can achieve the accuracy of the third-order Taylor series expansion after having propagated through the true nonlinear system Yi=F(Xi). Extended Kalman filter (EKF) only can achieve the first-order accuracy. The computational complexity of UKF is the same level as that of EKF. UKF can yield better performance and higher accuracy than EKF.

Multiple Kalman filters model with shaping filter GPS real-time deformation analysis

In order to detect the deformation in real-time of the GPS time series and improve its reliability, the multiple Kalman filters model with shaping filter was proposed. Two problems were solved: firstly, because the GPS real-time deformation series with a high sampling rate contain coloured noise, the multiple Kalman filter model requires the white noise, and the multiple Kalman filters model is augmented by a shaping filter in order to reduce the colored noise; secondly, the multiple Kalman filters model with shaping filter can detect the deformation epoch in real-time and improve the quality of GPS measurements for the real-time deformation applications. Based on the comparisons of the applications in different GPS time series with different models, the advantages of the proposed model were illustrated. The proposed model can reduce the colored noise, detect the smaller changes, and improve the precision of the detected deformation epoch.

Study on Adaptability of Datura stramonium and Datura stramonium var. tatual to Temperature

This study was conducted to investigate the temperature adaptability of Datura stramonium and D. stramonium var. tatual. Under 4 temperature levels,plantgrowth and pigment concentrations in leaves and stems were determined, and leaf anatomic structures of D. stramonium var. tatual and D. stramonium were analyzed. The results showed that the palisade tissue thickness/sponge tissue thickness,stomatal density and stomatal index values of D. stramonium var. tatual were significantly greater than D. stramonium; the chlorophyll content/carotenoid content in leaves of D. stramonium var. tatual increased at first and decreased then, while no regularity was found in leaves of D. stramonium; and the contents of anthocyanin,flavonoids, and total phenols in stems of D. stramonium var. tatual were significantly higher than those in stems of D. stramonium. The temperature adaptability of D.stramonium var. tatual is stronger than that of D. stramonium.

Raman Spectroscopy of Nitrogen Clathrate Hydrates

Nitrogen hydrate samples were synthesized using liquid nitrogen and powder ice at 16 MPa and 253 K. Confocal laser Raman spectroscopy was used to investigate the characteristics of nitrogen clathrate hydrates. The results show that the Raman peaks of N-N and O-H stretching vibration in nitrogen hydrates are observed at 2322.4 and 3092.1 cm^-1, respectively, which are very similar to those in natural air clathrate hydrates. For comparison, we measured the Raman peaks of N-N stretching vibration both in liquid nitrogen and nitrogen molecules saturated water, which appear at 2326.6 and 2325.0 cm^-1, respectively. The Raman spectroscopic observations on the dissociation process suggest that nitrogen molecules occupy both the large and small cages in nitrogen clathrate hydrates. However, only one Raman peak is observed for N N stretching vibration because the difference of the environment of nitrogen molecules between large and small cages is too small to be differentiated by Raman spectroscopy.

Surface-enhanced Raman Scattering of Aflatoxin B1 on Silver by DFT Method

The structure, electrostatic properties, and Raman spectra of aflatoxin B1 （AFB1） and AFB1-Ag complex are studied by density functional theory with B3LYP/6- 311G（d,p）/Lan12dz basis set. The results show that the surface-enhanced Raman scattering （SERS） and pre-resonance Raman spectra of AFB1-Ag complex strongly depend on the adsorption site and the excitation wavelength found to enhance 102-103 order compared to of the incident light. The SERS factors are normal Raman spectrum of AFB1 molecule due to the larger static polarizabilities of the AFB1-Ag complex, which directly results in the stronger chemical enhancement in SERS spectra. The pre-resonance Raman spectra of AFB1-Ag complex are explored at 266, 482, 785, and 1064 nm incident light wavelength, in which the enhancement factors are about 10^2-10^4, mainly caused by the charge-transfer excitation resonance. The vibrational modes are analyzed to explain the relationship between the vibrational direction and the enhanced Raman intensities.

Application of unscented Kalman filter to novel terrain passive integrated navigation system

To improve the navigation accuracy of an autonomous underwater vehicle （AUV）, a novel terrain passive integrated navigation system （TPINS） is presented. According to the characteristics of the underwater environment and AUV navigation requirements of low cost and high accuracy, a novel TPINS is designed with a configuration of the strapdown inertial navigation system （SINS）, the terrain reference navigation system （TRNS）, the Doppler velocity sonar （DVS）, the magnetic compass and the navigation computer utilizing the unscented Kalman filter （UKF） to fuse the navigation information from various navigation sensors. Linear filter equations for the extended Kalman filter （EKF）, nonlinear filter equations for the UKF and measurement equations of navigation sensors are addressed. It is indicated from the comparable simulation experiments of the EKF and the UKF that AUV navigation precision is improved substantially with the proposed sensors and the UKF when compared to the EKF. The TPINS designed with the proposed sensors and the UKF is effective in reducing AUV navigation position errors and improving the stability and precision of the AUV underwater integrated navigation.

1400-1500 nm,Different Material-doped Raman Fiber Lasers Pumped by Nd∶YVO_4 Laser

Different material-doped Raman fiber lasers with very high efficiency operating in continuous-wave are presented.With 1 W Nd∶YVO 4 laser pumping at wavelength of 1 342 nm, single mode output power of above 500 mW (optical-to-optical conversion efficiency of 50%) is simulated in the range of 1 400-1 500 nm.Using high-germanium,high-phosphate and high-borate silicate fibers as the gain medium,laser output at wavelengths of 1 420,1 450,1 480 and 1 495 nm can be achieved with different geometries,which are just as pumping C-band and L-band distributed Raman fiber amplifiers.

On the T-Connection in Riemannian Manifolds

The conjugate of T-connection in a Riemannian manifold is obtained, also some of its properties are studied. T-statistical manifold is defined and was considered. Finally a characteristic vector field of the deformation algebra （M, , ） is also obtained.

Raman crystal lasers in the visible and near-infrared

Raman lasers based on potassium gadolinium tungstate and lead tungstate crystals pumped by a≈120 ps Nd: YAG laser at 1.064/μm were developed. High reflection mirrors for the Stokes wavelength have been used to generate near-infrared and eye safe spectral region of 1.15 - 1.32/μm. Second harmonic generation of the generated Raman lasers was observed. Eifficient multiple Stokes and anti-Stokes picosecond generation in 64 crystals have been shown to exhibit stimulated Raman scattering on about 700 lines covering the whole visible and near-infrared spectrum. All stimulated Raman scattering (SRS) wavelengths in the visible and near-infrared spectrum are identified and attributed to the SRS-active vibration modes of these crystals.

VEHICULAR NODE POSITIONING BASED ON DOPPLER-SHIFTED FREQUENCY MEASUREMENT ON HIGHWAY

Vehicular node positioning needs to be quick and precise on highway for safety considera-tion.In this paper,we present a novel and practical vehicular node positioning method which can achieve a higher accuracy and more reliability than the existing global-positioning-system-based po-sitioning solutions by making use of Doppler-shifted frequency measurements taken by vehicular node itself.This positioning method uses infrastructure nodes which are placed on the roadside every several kilometers as radiation sources to estimate the relative distances of vehicle to the infrastructure node.Through coordinate conversion,we get the absolute coordinates of vehicular node based on known absolute coordinates of infrastructure node.We also analyze the optimal distance of neighbor infra-structure nodes in order to ensure a high accuracy.In addition,simulation results demonstrate that the accuracy of our method with Extended Kalman Filtering(EKF) is superior to the method without EKF.

Blind Channel Equalization Algorithm Based on Dual Unscented Kalman Filter for Chaotic Multi-Input Multi-Output Communication Systems

To reduce channel noise,fading,and inter-user interference effectively in the chaotic communication systems with multi-user,a blind channel equalization algorithm based on dual unscented Kalman filter algorithm is proposed.Assuming that the coefficients of a multi-input multi-output (MIMO) channel can be described by an autoregressive model,two separate state-space representations are used for the signals and coefficients.Then two unscented Kalman filters are used to estimate chaotic signals and channel coefficients simultaneously.The simulation results indicate that the algorithm can effectively track the coefficients of the multi-path fading channel in chaotic MIMO communication systems at a fast convergence speed.

A novel reaching law approach of quasi-sliding-mode control for uncertain discrete-time systems

A novel discrete-time reaching law was proposed for uncertain discrete-time system,which contained process noise and measurement noise.The proposed method reserves all the advantages of discrete-time reaching law,which not only decreases the band width of sliding mode and strengthens the system robustness,but also improves the dynamic performance and stability capability of the system.Moreover,a discrete-time sliding mode control strategy based on Kalman filter method was designed,and Kalman filter was employed to eliminate the influence of system noise.Simulation results show that there is no chattering phenomenon in the output of controller and the state variables of controlled system,and the proposed algorithm is also feasible and has strong robustness to external disturbances.

Autonomous determination of orbit for probe around asteroids using unscented Kalman filter

The observed images of the asteroid and the asteroid reference images are used to obtain the probe-to-asteroid direction and the location of the limb features of the asteroid in the inertial coordinate. These informa-tion in combination with the shape model of the asteroid and attitude information of the probe are utilized to ob-tain the position of the probe. The position information is then input to the UKF which determines the real-timeorbit of the probe. Finally, the autonomous orbit determination algorithm is validated using digital simulation.The determination of orbit using UKF is compared with that using extended Kalman filter (EKF), and the resultshows that UKF is superior to EKF.

Comparison of Linearized Kalman Filter and Extended Kalman Filter for Satellite Motion States Estimation

The performance of the conventional Kalman filter depends on process and measurement noise statistics given by the system model and measurements.The conventional Kalman filter is usually used for a linear system,but it should not be used for estimating the state of a nonlinear system such as a satellite motion because it is difficult to obtain the desired estimation results.The linearized Kalman filtering approach and the extended Kalman filtering approach have been proposed for a general nonlinear system.The equations of satellite motion are described.The satellite motion states are estimated,and the relevant estimation errors are calculated through the estimation algorithms of the both above mentioned approaches implemented in Matlab are estimated.The performances of the extended Kalman filter and the linearized Kalman filter are compared.The simulation results show that the extended Kalman filter is much better than the linearized Kalman filter at the aspect of estimation effect.

Fast Fabrication and Judgement of Tip-Enhanced Raman Spectroscopy-Active Tips

The quality of the scanning tip is crucial for tip-enhanced Raman spectroscopy(TERS)experiments towards large signal enhancement and high spatial resolution.In this work,we report a controllable fabrication method to prepare TERS-active tips by modifying the tip apex at the atomic scale,and propose two important criteria to in-situ judge the tip’s TERS activity for tip-enhanced Raman measurements.One criterion is based on the downshift of the first image potential state to monitor the coupling between the far-field incident laser and near-field plasmon;the other is based on the appearance of the low-wavenumber Raman peaks associated with an atomistic protrusion at the tip apex to judge the coupling efficiency of emissions from the near field to the far field.This work provides an effective method to quickly fabricate and judge TERS-active tips before real TERS experiments on target molecules and other materials,which is believed to be instrumental for the development of TERS and other tip-enhanced spectroscopic techniques.

Density Functional Theory Study on Raman Spectra of Rhodamine Molecules in Different Forms

Rhodamine molecules are one of the most used dyes for applications related to Raman spectroscopy. We have systematically studied Raman spectra of Rhodamine 6G, Rhodamine 123, and Rhodamine B （RhB） molecules using density functional theory. It is found that with BP86 functional the calculated Raman spectra of cationic Rhodamine molecules are in good agreement with corresponding experimental spectra in aqueous solution. It is shown that the involvement of the counter ion, chlorine, and the specific hydrogen bonds has noticeable effects on the Raman spectra of RhB that can partially explain the observed difference between Raman spectra of RhB in solution and on gold surfaces. It also indicates that an accurate description of surface enhanced Raman scattering for Rhodamine molecules on metal surface still requires to take into account the changes induced by the interracial interactions.