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积极发展石油替代化学品技术 被引量:6
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作者 古共伟 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 2007年第5期51-57,共7页
随着石油资源的日益枯竭和油价高企,发展石油替代化学品正变得越来越重要。包括甲醇制烯烃,一氧化碳制草酸酯和乙二醇,乙炔化学品,二氧化碳聚合物,生物质气化合成化工产品,发酵法生产丙酮、丁醇,乙醇衍生化工产品,甘油合成化工产品,糠... 随着石油资源的日益枯竭和油价高企,发展石油替代化学品正变得越来越重要。包括甲醇制烯烃,一氧化碳制草酸酯和乙二醇,乙炔化学品,二氧化碳聚合物,生物质气化合成化工产品,发酵法生产丙酮、丁醇,乙醇衍生化工产品,甘油合成化工产品,糠醛和羟甲基糠醛合成化工产品,淀粉合成化工产品等重要的石油替代化学品生产技术被介绍。 展开更多
关键词 石油替代化学品 工艺技术 乙烯 丙烯 乙二醇 丙二醇 丁醇 二氧化碳塑料
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全氟辛烷磺酸盐(PFOS)替代品对中国白羽鹌鹑的毒性 被引量:6
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作者 王瀛寰 王会利 +2 位作者 张艳峰 刘乐乐 李建中 《生态毒理学报》 CAS CSCD 北大核心 2012年第5期537-541,共5页
为研究全氟辛烷磺酸盐(perfluorooctane sulfonate,PFOS)替代品对环境生物的毒害效应,选用中国白羽鹌鹑作为受试生物,建立其环境危害评价毒性测试方法,并对PFOS替代化学品进行了急性经口、急性饲喂及繁殖毒性的风险评价。结果表明,全氟... 为研究全氟辛烷磺酸盐(perfluorooctane sulfonate,PFOS)替代品对环境生物的毒害效应,选用中国白羽鹌鹑作为受试生物,建立其环境危害评价毒性测试方法,并对PFOS替代化学品进行了急性经口、急性饲喂及繁殖毒性的风险评价。结果表明,全氟丁基有机铵盐阳离子表面活性剂急性经口毒性实验的LD50为500.44mg·kg-1,其余3种替代化学品在上限浓度2000mg·kg-1,白羽鹌鹑均未出现明显死亡,4种PFOS替代品对中国白羽鹌鹑的急性经口毒性均为低毒。全氟丁基有机铵盐阳离子表面活性剂急性饲喂毒性实验的LC50为970.50mg.kg-1,对白羽鹌鹑的饲喂毒性为中毒,而其余3种替代化学品在上限浓度5000mg·kg-1,白羽鹌鹑均未出现明显死亡,对中国白羽鹌鹑的急性饲喂毒性为低毒。在长期饲喂过程中,织物三防整理剂和C6织物三防整理剂会表现出一定的生殖毒性,造成中国白羽鹌鹑的孵化率降低,胚胎死亡率及未受精率升高;全氟丁基有机铵盐阳离子表面活性剂会影响到中国白羽鹌鹑的未受精率,C4织物三防整理剂未表现出明显的生殖毒性。 展开更多
关键词 PFOS替代化学品 中国白羽鹌鹑 急性经口毒性 急性饲喂毒性 繁殖毒性
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全氟辛基磺酸及其替代产品的内分泌干扰效应评价 被引量:3
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作者 杨蓉 李娜 +1 位作者 马梅 王子健 《生态毒理学报》 CAS CSCD 北大核心 2013年第5期702-707,共6页
为研究全氟辛基磺酸(PFOS)及其替代品的内分泌干扰效应,将重组人雌激素/雄激素/孕激素/甲状腺激素/维甲酸受体基因的双杂交酵母暴露于不同浓度的PFOS及替代品中,并结合体外代谢活化技术检测直接和间接的类/抗激素活性。结果表... 为研究全氟辛基磺酸(PFOS)及其替代品的内分泌干扰效应,将重组人雌激素/雄激素/孕激素/甲状腺激素/维甲酸受体基因的双杂交酵母暴露于不同浓度的PFOS及替代品中,并结合体外代谢活化技术检测直接和间接的类/抗激素活性。结果表明,被替代品PFOS表现为雄激素受体、甲状腺受体和维甲酸受体拮抗剂,且在代谢活化后新增了雌激素受体拮抗效应,其半数效应浓度(EC50)在3.0×10^-4~4.8×10^-3g·L^-1之间;同时,4种替代化学品没有任何效应检出,说明不会通过与核受体结合干扰天然激素的正常功能。研究结果说明,与原化学品相比,替代产品的应用在内分泌干扰效应方面可能具有更低的环境风险。 展开更多
关键词 全氟辛基磺酸 替代化学品 重组酵母 核受体 激素效应
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UNEP鼓励公私合作应对ODS的非法ODS贸易
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《产业与环境》 2005年第2期60-60,共1页
关键词 ODS 非法贸易 化学物质 替代化学品 多边环境协议 信息交换系统 环境废物
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Assessment of Non-chemical Alternatives for Controlling the Burrowing Nematode on Banana in Costa Rica
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作者 A. Martinuz G. Navarro +1 位作者 L. Pocasangre L. Quiros 《Journal of Agricultural Science and Technology(A)》 2011年第4X期550-562,共13页
The objective of this study was to technically and economically assess the effect of biopesticides on the serious plant parasitic nematode Radopholus similis on banana in Costa Rica. The following treatments were eval... The objective of this study was to technically and economically assess the effect of biopesticides on the serious plant parasitic nematode Radopholus similis on banana in Costa Rica. The following treatments were evaluated: a mixture of nematode trapping fungi-Arthrobotrys oligospora, A. botryospora, Dactylella brochophaga and Drechmeria coniospora; DiTera DF which consist of a "dead" fungus Myrothecium spp. and its fermentation substrate; Savitan produced from desert plant extracts; QL Agri which contain Quillaja saponaria extracts; Japanese-style compost called Bokashi; two application of a chemical nematicide; and an absolute control. Results of root sampling on a six month basis showed that the biopesticides had lower nematode population densities than the control with the nematode trapping-fungi having statistically significant differences over the other treatments. Chemical control was highly effective and produced the lowest nematode density. However, there were no significant differences between the chemical treatment and the trapping-fungi treatment. The functional root weight and bunch weight showed no significant differences between treatments. Conversely, economic analyses indicated that using nematode trapping-fungi, chemical nematieide, or the QL Agri treatments gave a detectable profit. The land expectation value (LEV) of the banana plantation was higher than the price of banana land which indicated that under normal conditions in the banana sector, production is economically sustainable / profitable. Other results confirm that profit in banana production is affected by the price of a banana box, production and discount rate. The optimal production cycle was obtained in year ten after farm establishment, which refers to the year with the highest profit following plantation renewal. Finally, economical results highlighted the importance of nematodes control, since profitability indexes were sensitive to the efficiency and cost of nematode management technology adopted by the banana company. 展开更多
关键词 BANANA Radopholus similis land expectation value BIO-CONTROL chemical nematicide and economical analysis.
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Synthesis, Thermal Stability and Photochemical Properties of DNA Containing Fluorescent Biaryl-Type Nucleoside Surrogates
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作者 Mari Iwata Aya Ogata +1 位作者 Yasutomo Ito Yoshihito Ueno 《Journal of Chemistry and Chemical Engineering》 2013年第10期962-971,共10页
A major goal of research in biotechnology and nanotechnology is to develop assemblies of novel biomaterials that can be used in analytical, industrial, and therapeutic applications. The synthesis of DNA (oligodeoxyri... A major goal of research in biotechnology and nanotechnology is to develop assemblies of novel biomaterials that can be used in analytical, industrial, and therapeutic applications. The synthesis of DNA (oligodeoxyribonucleotide) has been described containing the biaryl-type nucleoside surrogates, 6-deamino-2'-deoxy-6-(l-naphthyl) adenosine (AN) and 6-deamino-2'-deoxy-6-(1-pyrenyl) adenosine (AP). It is found that incorporation of multiple ATM or AP residues in the middle of DNA duplexes does not significantly destabilize the duplexes and that the fluorescence intensities of the oligonucleotides containing AN or Ap significantly increases in the duplexes formed. 展开更多
关键词 DNA OLIGONUCLEOTIDE biaryl-base fluorescent probe thermal stability
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