Diffusion-Controlled Adsorption Kinetics of Triton X-100 at Air/Solution Interface

In this paper, the equilibrium surface tension and the dynamic surface tension of aqueous Triton X-100 solution at temperature 25 ℃ were measured by means of Wilhelmy plate method and maximal bubble pressure method respectively. The determined critical micellar concentration（cmc） of Triton X-100 at 25 ℃ is (2.2×10-4) mol/dm3. The adsorption mechanics of Triton X-100 at air/solution was determined. For the submicellar concentrations it is diffusion-controlled. The diffusion coefficient was calculated from the experimental data in the range of short limit. In the range of long time adsorption, the subsurface concentration is fitted from the measured dynamic surface tensions.

新型管材冲击液压成形装置的设计

针对常规的管材液压成形技术需要昂贵的专用设备及模具、生产效率低等不足,开发了一种简单实用、可在冲床或压力机上使用的管材冲击液压成形装置,可用于薄壁金属管材的自然胀形、轴压胀形和异形截面中空件的冲击液压成形。该装置无需外部高压供给系统和专用液压成形设备,通过撞击轴压头挤压容腔中液体的方式来为管材提供液压力和轴压力。通过设计轴压头的行程和调节溢流阀的溢流压力值等来实现最大液压力和轴向进给量的合理匹配,并以304不锈钢毛细管和H65黄铜毛细管为试验管材做了相关试验。研究结果表明:该装置结构简单、操作方便;可实现最大液压力与轴向进给量的协调控制;合理的载荷匹配能显著地提高管材冲击液压成形的成形性能;H65黄铜毛细管破裂时所需的液压力小于304不锈钢毛细管破裂时所需的液压力。