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Techno-economic and Environmental Assessments of SAF from Bioamss:An Review

This review presents a comprehensive techno-economic and life-cycle assessment of sustainable aviation fuel(SAF)production from biomass.The critical need for transitioning towards environmentally sustainable alternatives for liquid fuel and aviation industry is first discussed.Key insights encompass the evolutionary progression of biofuel production from first-generation to second-generation biofuels,with a focus on utilizing non-food sources like woody biomass for enhanced sustainability.Available data from the literature on techno-economic assessments of various SAF production pathways are analyzed including production costs,conversion efficiency,and scalability.Moreover,results of lifecycle assessments associated with different SAF production pathways are presented,providing essential insights for decision-making processes.The challenges of scaling up woody biomass-based SAF production are discussed based on the assessment results,and recommendations are proposed to steer stakeholders towards a greener and more sustainable trajectory for aviation operations.

Synergistic effect of pinellia total alkaloids and uncaria total alkaloids on anticonvulsant action in mice and rats

Aim To investigate the synergistic effect of the combination of pinellia total alkaloid （PTA） and uncaria total alkaloid （UTA）, and explore the mechanism of anticonvulsant action. Methods Anticonvulsant and toxic effect profiles of combinations of PTA with UTA, alone and at three fixed ratios of 1：4, 1 ：1, 4：1, were evaluated in maximal electroshock （MES）-induced seizures and acute toxicity test in mice. Respective ED50 and LD50 were calculated with Bliss＇s method. Their synergistic effect were evaluated by isobolographic analysis and allowed the determination of benefit indices （BI） for respective combinations. The model of convulsive rats kindled by penicillin topically injected into cortex was used to investigated the content of Glu, Asp, Gly and GABA in hippocampus using high performance liquid chromatography （HPLC）. Results Combinations of PTA and UTA at the ratio of 4：1 were synergistic in MES test and antagonistic in acute toxicity test, showing the best profile for combinations of PTA with UTA. In contrast, the ratios of 1 ：4 and 1 ： 1, despite synergistic in MES test, were additive in acute toxicity test. The 4：1 combination and two drugs alone significantly decreased Glu level and increased GABA level in the hippocampus, but the GABA level in the 4：1 combination group was higher than that in the two drugs alone groups. They did not have significant influence on the levels of ASp and Gly. Conclusion Combinations of PTA and UTA at 4：1 ratio demonstrated synergistic effect in anticonvulsant action and antagonistic effect in toxicity. The anticonvulsant mechanism might be related to decreasing the excitability of Glutamatergic neurons and increasing the inhibition of GABAergic neurons.

Minimum secure speed of fully mechanized coal face based on critical temperature of coal spontaneous combustion

The critical temperature theory of spontaneous combustion of coal and the numerical simulation method are used to explore the minimum secure speed of fully mechanized coal face to prevent the spontaneous combustion in goaf. Combined with the actual situation of workface 31005 in a coal mine, the highest temperatures in goal at different advancing speeds were obtained by the numerical simulation of spontaneous combustion in goal, and then a power function equation between the highest temperature and the advancing speed was achieved by regression analysis. The advancing speed corresponding to the critical temperature value was taken as the minimum safe speed of workface based on the equation. Finally, the accuracy and reliability of the speed were verified by the actual advancing process of workface 31005. The results of this research show that the new judgment method of the minimum safety speed has a higher value to be applied in the field.

The shortest period of coal spontaneous combustion on the basis of oxidative heat release intensity

It’s necessary to forecast the shortest spontaneous combustion period for preventing and controlling the coal spontaneous combustion.During the experimental process,a calculating model of the SSCP is established on the basis of the oxidative heat release intensity and thermal capacity at different temperatures.According to the basic parameters of spontaneous combustion,heat of water evaporation and gas desorption,the SSCPs of different coals are further predicted.Finally,this study analyzed the relationships of the SSCP and the judging indexes of the self-ignite tendency.The result shows that the SSCP non-linearly increases with the decrease of dynamic oxygen adsorption and increase of activation energy.Compared with the practical fire situation of mine,this reliable method can meet the actual requirement of mine production.

Nonlinear characteristics of induced spontaneous combustion process of sulfide ores

To investigate the relationship between nonlinear parameters and spontaneous combustion tendency of sulfide ores, nine different sulfide ore samples were taken from a pyrite mine in China, and induced spontaneous combustion experiment was carried out in the laboratory. Different stages of the induced spontaneous combustion process were studied by integrating wavelet technology and nonlinear dynamics theory. The results show that ignition points of all the ore samples are above 330 ℃, indicating that sulfide ores of the pyrite mine are difficult to combust spontaneously under normal mining conditions. Spontaneous combustion process includes three stages： incubation stage, development stage and approaching stage. The average temperature rising rate of the three stages are 1.0 ~C/min, 2.0 ~C/min and 4.2 ~C/min, respectively. During the spontaneous combustion process, mean values of approximate entropy and correlation dimension increase at first, and then decrease in the following stage. The mean value of the maximum Lyapunov exponent increases with the passage of reaction time. In a whole, correlation among the three nonlinear parameters firstly weakens, then enhances, and the best correlation period is at approaching stage. As ignition point increases, the maximum Lyapunov exponent of approaching stage decreases. Therefore, combustible tendency of sulfide ores could be qualitatively evaluated based on the maximum Lyapunov exponent of this stage.

Effects of operating pressure on the key parameters of coal direct chemical looping combustion

Techno-economic development of chemical looping combustion （CLC） process has been one of the most pursued research areas of the present decade due to its ability to reduce carbon foot print during utilization of coal to generate energy. Based on a 2D computational fluid dynamics model, the present work provides a computational approach to study the effect of operating pressure--a key parameter in designing of CLC reactors, on optimum operating conditions. The effects of operating pressure have been examined in terms of reactors temperature, percentage of fuel conversion and purity of carbon dioxide in fuel reactor exhaust. The simulated results show qualitative agreement with the trends obtained by other investigators during experimental studies.

Particle Swarm Optimization based predictive control of Proton Exchange Membrane Fuel Cell (PEMFC)

Proton Exchange Membrane Fuel Cells (PEMFCs) are the main focus of their current development as power sources because they are capable of higher power density and faster start-up than other fuel cells. The humidification system and output performance of PEMFC stack are briefly analyzed. Predictive control of PEMFC based on Support Vector Regression Machine (SVRM) is presented and the SVRM is constructed. The processing plant is modelled on SVRM and the predictive control law is obtained by using Particle Swarm Optimization (PSO). The simulation and the results showed that the SVRM and the PSO re-ceding optimization applied to the PEMFC predictive control yielded good performance.

Lowest Temperature Miniature Fuel Cell with Modified PS PEM Membrane and Fueled with Nitrogen, Sulfur and Oxygen Containing Fuels

Polymer exchange membrane fuel cells （PEMFC） are objects of the current engineering technology and these are versatile generators for electrical energy. There are various kinds from them, but all of them are going on work at highest temperature. There isn＇t a PEMFC which can run at room temperature, like 20 ℃. In this study there is a aim for constructing such one for alternative fuels utilisation. PS and many electroconducting polymer formulations were proved by different researchers for PEM benefications, but here PS was synthesized without containing metalic contaminants and after converted to the PEM membrane.

An Assessment of Eco Driving System for Agricultural Tractor

In this study, tractor power output, fuel consumption rate and work performance were indirectly predicted in order to develop an eco driving system. Firstly, equations were developed which could foretell tractor power output and fuel consumption rate using characteristic curves of tractor power output. Secondly, with actual engine revolution per minute （rpm） determined by initial engine rpm and work load, tractor power output and fuel consumption rate were forecasted. Thirdly, it was possible to foresee tractor work performance and fuel consumption rate by the speed signals of Global Positioning System （GPS）. Lastly, precision of the eco driving system was evaluated through tractor Power Take-Off （PTO） test, and effects of the eco driving system were investigated in the plowing and rotary tilling operations. Engine rpm, power output, fuel consumption rate, work performance and fuel consumption rate per plot area were displayed on the eco driving system. Predicted tractor power outputs in the full load curve were well coincided with the actual power output of prototype, but small differences, 1 to 6 kW were found in the part load curve. Error of the fuel consumption rate was 0.5 to 3 L/h at the part load curve. It was shown that 69% and 53% of fuel consumption rates could be reduced in plowing and rotary tilling operations, respectively, when the eco driving system was installed in tractor.

Numerical Investigation of Fuel Dilution Effects on the Performance of the Conventional and the Highly Preheated and Diluted Air Combustion Furnaces

This numerical study investigates the effects of using a diluted fuel （50% natural gas and 50% N2） in an industrial furnace under several cases of conventional combustion （air with 21% O2 at 300 and 1273 K） and the highly preheated and diluted air （1273 K with 10% O2 and 90% N2） combustion （HPDAC） conditions using an in-house computer program. It was found that by applying a combined diluted fuel and oxidant instead of their uncombined and/or undiluted states, the best condition is obtained for the establishment of HPDAC＇s main unique features. These features are low mean and maximum gas temperature and high radiation/total heat transfer to gas and tubes; as well as more uniformity of theirs distributions which results in decrease in NOx pollutant formation and increase in furnace efficiency or energy saving. Moreover, a variety of chemical flame shape, the process fluid and tubes walls temperatures profiles, the required regenerator efficiency and finally the concentration and velocity patterns have been also qualitatively/quantitatively studied.

Characteristics of gas explosion flow fields in complex pipelines

The explosion flow field in five straight pipes with different diameters and one bending pipe selected from a domestic coal mine are studied by the method of numerical simulation. And the results show that,both in the straight and bending pipes, the pressure wave and velocity wave are accelerated by the rising of reaction rate. As the explosion progressed, with the temperature reaching approximately 3000 K, only one pressure wave and one reaction rate wave were observed, while several velocity waves were found.The larger diameter presented the highest relative pressure as well as the largest velocity increase and subsequent decrease inside the tube. The bent pipes caused both turbulence and kinetic energy to increase, resulting in the acceleration of the reaction rate. The burning time was 7.4% shorter than the burning time observed for the straight pipe. Based on these results, designing one explosion resistance device, and in the practical engineering applications, it was to be proved to meet the security requirements fully.

Numerical investigation of optimal geometry parameters for ejectors of premixed burner

An ejector of low NO~ burner was designed for a gas instantaneous water heater in this work. The flowing and mixing process of the ejector was investigated by computational fluid dynamics （CFD） approach. A comprehensive study was conducted to understand the effects of the geometrical parameters on the static pressure of air and methane, and mole fraction uniformity of methane at the outlet of ejector. The distribution chamber was applied to balance the pressure and improve the mixing process of methane and air in front of the fire hole. A distribution orifice plate with seven distribution orifices was introduced at the outlet of the ejector to improve the flow organization. It is found that the nozzle exit position of 5 mm and nozzle diameter d 〉1.3 mm should be used to improve the flow organization and realize the well premixed combustion for this designed ejector.

Estimating the Impacts of Nuclear Phase-out and FIT on Tokyo Electric Power Company Jurisdiction

This study examines the effects of nuclear phase-out and newly implemented FIT （feed-in tariff） at the TEPCO （Tokyo Electric Power Company） jurisdiction. A power generation mix linear programming model is developed for the TEPCO jurisdiction up to 2030. Three results are found from this analysis. First, coal-fired power plants compensate for an abolishment of nuclear power generation when power mix is analyzed to maximum profits. Second, it is clarified that FIT provides competitiveness to wind power for potential and photovoltaics at the location where 15% of efficiency is expected at the TEPCO jurisdiction. Third, implementing FIT can decrease fossil-fuel dependency and CO2 emissions as much as planned nuclear power generation. However, system costs increase 4.61 trillion.

Efficient reversible CO/CO_(2) conversion in solid oxide cells with a phase-transformed fuel electrode

The reversible solid oxide cell(RSOC)is an attractive technology to mutually convert power and chemicals at elevated temperatures.However,its development has been hindered mainly due to the absence of a highly active and durable fuel electrode.Here,we report a phase-transformed CoFe-Sr_(3)Fe_(1.25)Mo_(0.75)O_(7)-δ(CoFe-SFM)fuel electrode consisting of CoFe nanoparticles and Ruddlesden-Popper-layered Sr_(3)Fe_(1.25)Mo_(0.75)O_(7)-δ(SFM)from a Sr_(2)Fe_(7/6)Mo_(0.5)Co_(1/3)O_(6)-δ(SFMCo)perovskite oxide after annealing in hydrogen and apply it to reversible CO/CO_(2)conversion in RSOC.The CoFeSFM fuel electrode shows improved catalytic activity by accelerating oxygen diffusion and surface kinetics towards the CO/CO_(2)conversion as demonstrated by the distribution of relaxation time(DRT)study and equivalent circuit model fitting analysis.Furthermore,an electrolyte-supported single cell is evaluated in the 2:1 CO-CO_(2)atmosphere at 800℃,which shows a peak power density of 259 mW cm^(-2)for CO oxidation and a current density of-0.453 A cm^(-2)at 1.3 V for CO_(2)reduction,which correspond to 3.079 and3.155 m L min-1cm^(-2)for the CO and CO_(2)conversion rates,respectively.More importantly,the reversible conversion is successfully demonstrated over 20 cyclic electrolysis and fuel cell switching test modes at 1.3 and 0.6 V.This work provides a useful guideline for designing a fuel electrode through a surface/interface exsolution process for RSOC towards efficient CO-CO_(2)reversible conversion.

Combustion of Hydrogen in an Experimental Trapped Vortex Combustor

Combustion performances of pure hydrogen in an experimental trapped vortex combustor have been tested underdifferent operating conditions. Pressure fluctuations, NOx emissions, OH distributions, and LBO (Lean Blow Out)were measured in the tests. Results indicate that the TVC test rig has successfully realized a double vortex constructionin the cavity zone in a wide range of flow conditions. Hydrogen combustion in the test rig has achievedan excellent LBO performance and relatively low NOx emissions. Through comparison of dynamic pressure data,OH fluctuation images, and NOx emissions, the optimal operating condition has been found out to be Φp=0.4,fuel split=0.4, and primary air/fuel premixed.

Nonlinear analysis of combustion oscillations in a cavity-based supersonic combustor

Combustion oscillations in a supersonic combustor with hydrogen injection upstream of a cavity flameholder are investigated using nonlinear analysis based on experimental measurements.Time series of both flamefront and wall pressure are acquired,and the state space reconstruction approach is adopted to characterize the nonlinear behavior of the combustion oscillations.Three overall equivalence ratios,0.038,0.076 and 0.11,are considered.The existence of a chaotic source in the present combustion system is demonstrated.The correlation dimension and the largest Lyapunov exponent tend to become larger with the increasing equivalence ratio,indicating a more complicated and unstable combustion system.In particular,it is found that the correlation dimension for the highest equivalence ratio is much greater than those of the two lower equivalence ratios.Two possible reasons responsible for the observed nonlinear behaviors are identified.One is the shock-related instabilities and the other is the transition of combustion stabilization mode between the cavity and jet-wake stabilized mode.